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Resin lens with ultraviolet photocuring refractive index of 1.56 and production method thereof

A technology of resin lenses and ultraviolet rays, applied in optics, optical components, optical components, etc., can solve problems such as long polymerization time, large internal stress, and general optical performance

Active Publication Date: 2017-05-24
SHANGHAI WEIXING OPTICAL
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

Optical resins are divided into thermoplastic resins and thermosetting resins. Thermoplastic resins such as polycarbonate (PC) are mainly used for sun lenses and partial corrective lenses. The advantages are fast molding and low molding cost. The disadvantage is relatively large internal stress. , general optical performance
Thermosetting resins such as polymethyl methacrylate (PMAA), polyurethane (PU) and polydiallyl diglycol carbonate (CR-39) have the advantages of good optical properties and small stress, but molding requires 20 - Molding time ranging from 40 hours, the polymerization time is relatively long
In order to solve the problem of comparison of curing time in the above-mentioned thermosetting resin manufacturing process, the manufacturing method of ultraviolet light curing resin with a refractive index of 1.56 and its resin lens manufacturing method were developed

Method used

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  • Resin lens with ultraviolet photocuring refractive index of 1.56 and production method thereof
  • Resin lens with ultraviolet photocuring refractive index of 1.56 and production method thereof
  • Resin lens with ultraviolet photocuring refractive index of 1.56 and production method thereof

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0036] Methyl styrene: 180g;

[0037] Polypropylene glycol diacrylate: 220g;

[0038] Trimethylolpropane trimethacrylate: 300g;

[0039] Polypentyl glycol dimethacrylate: 300g;

[0040] 2'-(2'-hydroxy-3'-tert-butyl-5'-methylphenyl)-5-chlorobenzotriazole: 0.01g;

[0041] 2-(2'-hydroxy-5'-tert-octylphenyl)benzotriazole: 0.02g;

[0042] 2-hydroxy-4-methoxybenzophenone: 0.02g;

[0043] 2,2'-Dimethyl-4-methylaminobenzophenone 2'-(2'-hydroxy-3'-tert-butyl-5'-methylphenyl)-5-chlorobenzene

[0044] Triazole: 0.03g;

[0045] Pigment: Pigment blue: 0.5g; Pigment green: 0.2g.

[0046] Photocuring initiator: 1.2 g of acylphosphine oxide.

[0047] The mixture obtained according to the above formula was sheared for 2 hours at a stirring speed of 2000 rpm, and then vacuumed at a degree of vacuum of 1.0*10 -2 Vacuum degassing under Pascal vacuum. Then filter with a filter element of 1 μm, pour into the glass mold prepared in advance after filtering, and put the glass mold into an ult...

Embodiment 2

[0051] Methyl styrene: 180g;

[0052] Polypropylene glycol diacrylate: 220g;

[0053] Trimethylolpropane trimethacrylate: 300g;

[0054] Polypentyl glycol dimethacrylate: 300g;

[0055] 2'-(2'-hydroxy-3'-tert-butyl-5'-methylphenyl)-5-chlorobenzotriazole: 0.03g;

[0056] 2-(2'-hydroxy-5'-tert-octylphenyl)benzotriazole: 0.03g;

[0057] 2-hydroxy-4-methoxybenzophenone: 0.05g;

[0058] 2,2'-Dimethyl-4-methylaminobenzophenone 2'-(2'-hydroxy-3'-tert-butyl-5'-methylphenyl)-5-chlorobenzene

[0059] Triazole: 0.06g;

[0060] Pigment: Pigment blue: 0.5g; Pigment green: 0.2g.

[0061] Photocuring initiator: 1.5 g of acylphosphine oxide.

[0062] The mixture obtained according to the above formula was sheared for 2 hours at a stirring speed of 2500 rpm, and then vacuumed at a degree of vacuum of 1.0*10 -2 Vacuum degassing under Pascal vacuum. Then filter with a filter element of 0.5 μm, pour it into a prepared glass mold after filtering, put the glass mold into an ultraviolet curin...

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Abstract

The invention relates to a resin lens with ultraviolet photocuring refractive index of 1.56, and the resin lens comprises the following raw material components by mass: 15%-20% of methyl styrene, 35%-60% of poly(propyleneglycol)dimethacrylate, 20%-40% of tri methylol propane tri methacrylate, 15%-30% of poly pentyl glycol dimethacrylate, 0.002 to 0.05% of an UV agent, 0.01-0.04% of a pigment and 0.06-0.1% of a light curing initiator. The invention provides a method for manufacturing the resin lens with the ultraviolet photocuring refractive index of 1.56, and the method is a new and efficient method for producing the resin lenses that can be cured by ultraviolet ray.

Description

【Technical field】 [0001] The invention relates to the technical field of resin lenses, in particular to a resin lens with a refractive index of 1.56 cured by ultraviolet light and a production method thereof. 【Background technique】 [0002] Before the 1930s, the main material in the optical field was optical glass, with nearly 240 types and a refractive index ranging from 1.4 to 2.8, with a wide range of choices. As a wearing product, spectacle lenses have relatively high requirements on specific gravity and impact resistance. However, most optical glass has a large specific gravity and is easily broken. Compared with optical glass, optical resin has the advantages of light weight, impact resistance and easy processing and molding. Once launched, it quickly replaced optical glass and became the mainstream product of spectacle lenses. The development and research of optical resin abroad began in the 1920s, and dozens of optical resins with different specifications have been...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C08F290/06C08F212/12C08F222/14C08F2/48C08L51/08C08K5/3475C08K5/132C08K5/17G02C7/02B29D11/00
Inventor 汪山献松陈国贵
Owner SHANGHAI WEIXING OPTICAL
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