Novel active printing dye for digital printing and preparation method of novel active printing dye
A technology of reactive printing and digital printing, which is applied in the fields of dyeing, organic dyes, textiles and papermaking, etc. It can solve problems such as printing nozzle clogging, and achieve the effects of improved anti-permeability, easy storage, and increased consistency
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Embodiment 1
[0028] (1) In parts by volume, mix 1 part of epoxy resin with 5 parts of aniline, heat and stir at 100°C for 5 hours, cool to room temperature, take out and place in a solution of 3 parts of chloroform and 1 part of methanol , vacuum-dried to obtain an epoxy resin precursor.
[0029] (2) In parts by volume, dissolve 1 part of vinylsulfone sulfate in 30 parts of alkaline aqueous solution with a pH value of 8, stir until completely dissolved, then add 8 parts of sodium nitrate, mix well, and then drop Add to 5 parts of acetic acid solution at 0°C and stir evenly to obtain vinyl sulfone sulfate diazonium salt.
[0030] (3) In parts by volume, dissolve the epoxy resin precursor prepared by 0.5 parts of step (1) in a solvent, place in an ice-water bath, slowly add 2 parts of vinyl sulfone sulfate prepared by step (2) dropwise The diazonium salt is reacted with stirring, and the modified vinyl sulfone type reactive dye is obtained after precipitation, filtration, washing and drying...
Embodiment 2
[0033] (1) In parts by volume, mix 1 part of epoxy resin with 10 parts of aniline, heat and stir at 120°C for 6 hours, cool to room temperature, take out the solution placed in 5 parts of chloroform and 2 parts of methanol In vacuum drying, the epoxy resin precursor was obtained.
[0034] (2) In parts by volume, dissolve 1 part of vinylsulfone sulfate in 50 parts of alkaline aqueous solution with a pH value of 10, stir until completely dissolved, then add 16 parts of sodium nitrate, mix well, and then drop Add to 20 parts of acetic acid solution at 0°C and stir evenly to obtain vinyl sulfone sulfate diazonium salt.
[0035] (3) In parts by volume, dissolve the epoxy resin precursor prepared by 1 part of step (1) in a solvent, place in an ice-water bath, slowly add 4 parts of vinylsulfone sulfate prepared by step (2) dropwise The diazonium salt is reacted with stirring, and the modified vinyl sulfone type reactive dye is obtained after precipitation, filtration, washing and dr...
Embodiment 3
[0038] (1) In parts by volume, mix 1 part of epoxy resin with 7 parts of aniline, heat and stir at 110°C for 5.5 hours, cool to room temperature, take out the solution placed in 4 parts of chloroform and 1.5 parts of methanol In vacuum drying, the epoxy resin precursor was obtained.
[0039](2) In parts by volume, dissolve 1 part of vinylsulfone sulfate in 40 parts of alkaline aqueous solution with a pH value of 9, stir until completely dissolved, then add 15 parts of sodium nitrate, mix well, and then drop Add to 15 parts of acetic acid solution at 0°C and stir evenly to obtain vinyl sulfone sulfate diazonium salt.
[0040] (3) In parts by volume, dissolve the epoxy resin precursor prepared by 0.7 parts of step (1) in a solvent, place in an ice-water bath, slowly add 3 parts of vinyl sulfone sulfate prepared by step (2) dropwise The diazonium salt is reacted with stirring, and the modified vinyl sulfone type reactive dye is obtained after precipitation, filtration, washing a...
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