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A kind of high-toughness environment-friendly peelable glue and preparation method thereof

An environmentally friendly, high-toughness technology, used in epoxy resin adhesives, adhesives, adhesive types, etc., can solve the problems of poor impact resistance and vibration resistance, difficult to degrade, easy to crack, etc., to achieve a wide range of applications, film forming. Good strength and small elongation at break

Active Publication Date: 2018-12-11
荆门博创光电科技有限公司
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0002] The application of high-toughness and environment-friendly peelable adhesives is very common, and has been widely used in aerospace, aviation, machinery, electronics, medical and other fields, but in use, there are problems such as poor toughness, high brittleness of cured products, poor impact resistance and vibration resistance. , easy to crack and other defects, as a structural adhesive, it must be modified and toughened to meet its special technical requirements
At present, the peelable glue on the market has the following disadvantages: (1) The peelable glue on the existing market contains volatile solvents, which will affect the performance of the scraper, the working environment, and the length of curing time, the process is complicated, and it will affect the touch screen sensor function. The base material on the block is corroded; (2) It will remain when peeling off, and there will be residual glue, which needs to be wiped with a solvent, which is mainly due to its poor toughness; (3) The peelable glue is more toxic, not only the solvent is volatilized, In addition, the used peelable rubber waste cannot be degraded and becomes a pollutant
Invention application "A Protective Elastic Peelable Blue Glue and Its Preparation Method" (Application No.: 201510438687.1) The product prepared uses a plasticizer, which is difficult to degrade and is not environmentally friendly

Method used

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  • A kind of high-toughness environment-friendly peelable glue and preparation method thereof
  • A kind of high-toughness environment-friendly peelable glue and preparation method thereof
  • A kind of high-toughness environment-friendly peelable glue and preparation method thereof

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0028] A high-toughness environment-friendly peelable rubber, which is prepared from the following raw materials (measured per 100kg of peelable rubber produced):

[0029] raw material

Dosage(kg)

Waterborne Polyacrylic Resin

40

water

48.4

calcium carbonate

10

Polyether type defoamer

0.3

Polyacrylic leveling agent

0.1

Carboxylated nitrile rubber

1

rheological agent

0.1

Phthalocyanine blue

0.1

[0030] The sources of raw materials used are as follows: the water-soluble resin is Korean Hanwha water-based polyacrylic acid solid resin, the model is Soluryl-160; the defoamer is the polyether defoamer of Wancheng Group, the model is XWC-753N; It is the product of Shanghai Dapan Chemical Co., Ltd., the model is DP-260; the carboxylated nitrile rubber is the product of Saikede Rubber and Plastic Company, the model is LR-899; the rheological agent is silica, Cabot silica TS- 720.

[0031] ...

Embodiment 2

[0036] A high-toughness environment-friendly peelable rubber, which is prepared from the following raw materials (measured per 100kg of peelable rubber produced):

[0037]

[0038]

[0039] The sources of the raw materials used are as follows: the water-based epoxy resin is the product of Guangzhou Hongyu Trading Co., Ltd., the model is HY-100; the silicone defoamer is the product of Guangzhou Yuheng Chemical Materials Co., Ltd., the model is Y-698 / 699; The acrylic leveling agent is the product of Shanghai Dapan Chemical Co., Ltd., the model is DP-260; the carboxylated nitrile rubber is the product of Saikede Rubber and Plastic Company, the model is LR-899; the rheological agent is white carbon black, Cabot Silica TS-720.

[0040] The preparation method of the above-mentioned high-toughness environment-friendly peelable adhesive comprises the following steps:

[0041] (1) Take each component in proportion,

[0042] (2) Water-based epoxy resin is dissolved in part of wa...

Embodiment 3

[0045] A high-toughness environment-friendly peelable rubber, which is prepared from the following raw materials (measured per 100kg of peelable rubber produced):

[0046] raw material

Dosage kg

Waterborne polyurethane resin

55

water

7

Barium sulfate

20

Polyether type defoamer

1

Polyacrylic leveling agent

1

polyvinyl alcohol

10

rheological agent

5

Phthalocyanine blue

1

[0047] The sources of raw materials used are as follows: water-based polyurethane resin is the product of Dongguan Mirenzhan Chemical Co., Ltd., model is MR-701; polyether type defoamer is the product of Weifang Dadong Chemical Co., Ltd., model is DEFOAMER NXZ; The leveling agent is the product of Shanghai Dapan Chemical Co., Ltd., the model is DP-260; the polyvinyl alcohol is the product of Beijing Guohao Chemical Company, the model is GH-JY; the rheological agent is white carbon black, Cabot White Carbon Black TS...

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PUM

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Abstract

The invention discloses a high-toughness environment-friendly peelable adhesive and a preparation method thereof. The high-toughness environment-friendly peelable adhesive is prepared from water-soluble resin, water, filler, an anti-foaming agent, a levelling agent, a toughening agent, a rheological agent and a pigment in certain proportions. The preparation method comprises the following steps: A, weighing various components in proportions; B, dissolving water-based resin in part water, adding the toughening agent, and stirring for 1.5 to 2.5 hours; C, adding the filler and the pigment into a mixed liquid, stirring uniformly, grinding 2 to 5 times by using a three-roller grinding machine, adding the rest water into the ground material, stirring 0.5 to 2 hours at 90 to 110 DEG C, adding the anti-foaming agent for performing anti-foaming treatment after the materials are stirred uniformly, and finally, adding the levelling agent and the rheological agent. The peelable adhesive provided by the invention has the characteristics of high film forming strength, high temperature resistance, low breaking elongation, environment-friendliness and the like; the use range is wide; the peelable adhesive is particularly suitable for protecting processes, such as cutting, carving, printing and film coating, in a touch screen process.

Description

technical field [0001] The invention belongs to the technical field of high molecular polymers, and in particular relates to a high-toughness and environment-friendly peelable glue, and also relates to a preparation method of the high-toughness and environment-friendly peelable glue. Background technique [0002] The application of high-toughness and environment-friendly peelable adhesives is very common, and has been widely used in aerospace, aviation, machinery, electronics, medical and other fields, but in use, there are problems such as poor toughness, high brittleness of cured products, poor impact resistance and vibration resistance. , easy to crack and other defects, as a structural adhesive, it must be modified and toughened to meet its special technical requirements. At present, the peelable glue on the market has the following disadvantages: (1) The peelable glue on the existing market contains volatile solvents, which will affect the performance of the scraper, th...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): C09J133/00C09J163/00C09J175/04C09J127/06C09J11/08C09J11/04
CPCC08L2201/08C08L2205/03C08L2205/035C09J11/04C09J11/08C09J127/06C09J133/00C09J163/00C09J175/04C08L13/00C08K2003/265C08K3/34C08L29/04C08K2003/3045C08K3/36
Inventor 陈勇谭晓明杨希雄熊航行刘明李立威熊泽云王洪林
Owner 荆门博创光电科技有限公司
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