Ink-receptive layer coating solution for high-glossiness water-resistant photographic paper and preparation method thereof

An ink-absorbing layer and high-gloss technology, which is applied to the ink-absorbing layer coating liquid of high-gloss water-resistant photo paper and its preparation field, can solve the problems of slow printing drying speed, affecting the display and preservation of printed colors, poor water resistance, etc. Speed ​​improvement, increase the ink absorption drying rate and printing resolution, the effect of fast ink absorption drying rate

Inactive Publication Date: 2017-05-31
JIANGSU GEMEIGAO DEV CO LTD
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0004] Coated paper photo paper has the advantages of good water resistance, high flatness, complete hydrophobicity on the back of the paper, vivid and bright output colors, and is suitable for long-term storage. However, its surface gloss is relatively low, the printing drying speed is slow, and the surface is prone to scratches And leave fingerprints, which will affect the printing color display and preservation
[0005] Cast-coated photo paper has high gloss, fast printing and drying speed, high surface hardness, and vivid and bright colors. However, because it uses paper as the base material, it has relatively poor water resistance and is easy to curl, which affects long-term storage applications.

Method used

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Examples

Experimental program
Comparison scheme
Effect test

specific Embodiment 1

[0026] An ink-absorbing layer coating solution for high-gloss water-resistant photographic paper, the ink-absorbing layer coating solution is composed of the following components in parts by weight:

[0027] 50 parts of water;

[0028] 3 parts of color fixing agent;

[0029] 0.1 part of defoamer;

[0030] Brightener 0.1 part;

[0031] 5 parts of polyvinyl alcohol solution (15%);

[0032] Microporous silica 12 parts;

[0033] 10 parts of polymer emulsion.

[0034] The color fixing agent is a quaternary ammonium salt formaldehyde-free color fixing agent.

[0035] The defoamer is a polyether defoamer: tributyl phosphate.

[0036] The whitening agent is a stilbene derivative, which is a sodium disulfonic acid salt.

[0037] The polyvinyl alcohol solution (15%) is polyvinyl alcohol 1799.

[0038] The particle size of the microporous silica is 9 microns, and the pore volume is 1.4ml / g.

[0039] The polymer emulsion is a nonionic vinyl acetate-ethylene copolymer emulsion.

...

specific Embodiment 2

[0042] An ink-absorbing layer coating solution for high-gloss water-resistant photographic paper, the ink-absorbing layer coating solution is composed of the following components in parts by weight:

[0043] 70 parts of water;

[0044] Fixing agent 7 parts;

[0045] 0.5 part of defoamer;

[0046] 0.5 parts of whitening agent;

[0047] 10 parts of polyvinyl alcohol solution (15%);

[0048] Microporous silica 18 parts;

[0049] 15 parts of polymer emulsion.

[0050] The color fixing agent is a quaternized reactive color fixing agent.

[0051] The defoamer is a polyether defoamer: polydimethylsiloxane.

[0052] The whitening agent is a stilbene derivative, which is sodium tetrasulfonate.

[0053] The polyvinyl alcohol solution (15%) is polyvinyl alcohol 1788.

[0054] The particle size of the microporous silica is 15 microns, and the pore volume is 2.0ml / g.

[0055] The polymer emulsion is a nonionic vinyl acetate-ethylene copolymer emulsion.

[0056] A method for prepa...

specific Embodiment 3

[0058] An ink-absorbing layer coating solution for high-gloss water-resistant photographic paper, the ink-absorbing layer coating solution is composed of the following components in parts by weight:

[0059] 60 parts of water;

[0060] Fixing agent 5 parts;

[0061] 0.3 part of defoamer;

[0062] 0.4 parts of whitening agent;

[0063] 8 parts of polyvinyl alcohol solution (15%);

[0064] Microporous silica 15 parts;

[0065] 13 parts of polymer emulsion.

[0066] The color fixing agent is a quaternized high polymer formaldehyde-free color fixing agent.

[0067] The defoamer is polyether defoamer: polysiloxane defoamer.

[0068] The whitening agent is a stilbene derivative, which is sodium hexasulfonic acid.

[0069] The polyvinyl alcohol solution (15%) is Kuraray FJS-1000 from Japan.

[0070] The particle size of the microporous silica is 13 microns, and the pore volume is 1.8ml / g.

[0071] The polymer emulsion is a nonionic vinyl acetate-ethylene copolymer emulsion. ...

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Abstract

The invention discloses an ink-receptive layer coating solution for high-glossiness water-resistant photographic paper. The ink-receptive layer coating solution is composed of the following components in parts by weight: 50-70 parts of water, 3-7 parts of color fixative, 0.1-0.5 part of defoaming agent, 0.1-0.5 part of whitener, 5-10 parts of polyvinyl alcohol solution (15%), 12-18 parts of microporous silicon dioxide and 10-15 parts of polymer emulsion. The preparation method comprises the following steps: respectively adding the color fixative, defoaming agent, whitener and polyvinyl alcohol solution into the water according to the formula technique proportion, stirring uniformly, adding the silicon dioxide, stirring at high speed for 30-90 minutes, adding a polymer emulsion, stirring at high speed for 20-60 minutes, and filtering to form the ink-receptive layer coating solution for high-glossiness water-resistant photographic paper. The ink-receptive layer coating solution adopts the microporous silicon dioxide as the ink-receptive medium, thereby enhancing the ink-receptive drying rate and printing resolution of the product.

Description

technical field [0001] The technical field of the present invention is the technical field of new materials, and the application field is the field of image output, in particular to an ink-absorbing layer coating solution of high-gloss water-resistant photographic paper and a preparation method thereof. Background technique [0002] In September 2012, my country Lucky Film Group, a giant film manufacturer in China, closed the last color film production line in Nanjing, marking that my country's digital inkjet printing technology has basically replaced the traditional silver salt output technology in the image output industry. [0003] Inkjet printing photo paper is the printing medium material in digital inkjet printing technology, which is made by coating the coating liquid on the surface of the substrate. At present, the types of photo paper on the market mainly include coated paper photo paper and cast-coated photo paper. Among them, the coated paper photo paper is coated...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): D21H19/40D21H19/60D21H19/46D21H19/48B41M5/52
CPCB41M5/52D21H19/40D21H19/46D21H19/48D21H19/60
Inventor 陆建辉王玉丰
Owner JIANGSU GEMEIGAO DEV CO LTD
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