Water-in-oil association type concentrated thickener for oil displacement and preparation method of water-in-oil association type concentrated thickener

A thickener and associative technology, which is applied in the field of concentrated thickener for water-in-oil associative type oil displacement and its preparation, can solve the problem of increasing the construction platform space, construction cost and construction difficulty, and the use frequency of the dispensing process. It can improve the performance of the system solution, shorten the dissolution time, reduce the difficulty of the process and reduce the production cost.

Inactive Publication Date: 2017-06-13
SICHUAN GUANGYA POLYMER CHEM
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

However, there are still some shortcomings and needs to be improved in the application
On the one hand, the introduction of hydrophobic groups will inevitably have a certain adverse effect on the dissolution of the polymer. In addition, during the preparation process, the polymer dry powder is directly added to water and mixed to obtain a polymer solution, which is easy to form powder particles during the dissolution process. Fish eyes, local agglomeration, insufficient dissolution or longer time to completely dissolve, which not only affects the performance of the solution but also reduces the construction efficiency
On the other hand, when it is necessary to add additives such as surfactants to the polymer solution to form a composite system with a synergistic effect, the on-site process is to prepare the polymer solution and the surfactant solution separately and then mix them, which undoubtedly greatly increases It reduces the construction platform space, construction cost and construction difficulty, especially for platforms with limited space and high frequency of use of dispensing technology.

Method used

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  • Water-in-oil association type concentrated thickener for oil displacement and preparation method of water-in-oil association type concentrated thickener
  • Water-in-oil association type concentrated thickener for oil displacement and preparation method of water-in-oil association type concentrated thickener
  • Water-in-oil association type concentrated thickener for oil displacement and preparation method of water-in-oil association type concentrated thickener

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preparation example Construction

[0074] The present invention also provides a preparation method of the above-mentioned water-in-oil association type oil displacement concentrated thickener, comprising the following steps:

[0075] A) mixing and stirring the dispersion medium, the dispersed phase and the composite emulsifier to obtain a water-in-oil emulsion;

[0076] B) adding a hydrophobic association polymer thickener for oil flooding to the water-in-oil emulsion, mixing and stirring to obtain a concentrated water-in-oil association thickener for oil flooding.

[0077] In the present invention, firstly, the dispersion medium, the dispersion phase and the composite emulsifier are mixed and stirred to obtain the water-in-oil emulsion;

[0078] Wherein, the mixing and stirring temperature is 35-70°C, preferably 40-65°C, more preferably 45-60°C; the mixing and stirring speed is 300-800rmp, preferably 400-700rmp; the mixing and stirring The time is 20 ~ 60min.

[0079] After the water-in-oil emulsion is obtai...

Embodiment 1

[0085] Preparation of concentrated thickener for water-in-oil (W / O) associative flooding (compound emulsifier: tripolyglycerol diisostearate + Pingpinga O O-5)

[0086] (1) A concentrated thickener for W / O association type oil displacement, comprising the following components in mass percentage:

[0087] 0# diesel oil 35.72%, water 35.72%, hydrophobic association polymer oil displacement thickener (hereinafter referred to as "oil displacement thickener") 25%, tripolyglycerol diisostearate 2.85%, Pingpingjia O O-5 0.71%;

[0088] Described oil displacement thickener is acrylamide / sodium acrylate / N-dodecyl substituted acrylamide copolymer, and described composite emulsifier is tripolyglycerol diisostearate and O-5 (ratio 4:1), the preparation steps are as follows:

[0089] At 40°C, control the mass ratio of oil to water to 5:5, mix and emulsify 357.2g diesel, 357.2g water, 28.5g triglyceryl diisostearate, 7.1g O-5, and stir at 600rmp After 30 minutes, a stable water-in-oil em...

Embodiment 2

[0099] Preparation of concentrated thickener for water-in-oil (W / O) associative flooding (compound emulsifier is propylene glycol fatty acid ester PGMS+polyoxyethylene castor oil EL-20)

[0100] (1) A concentrated thickener for W / O association type oil displacement, comprising the following components in mass percentage:

[0101] 0# diesel oil 42.86%, water 28.57%, oil displacement thickener 25%, propylene glycol fatty acid ester PGMS 2.14%, polyoxyethylene castor oil EL-20 1.43%;

[0102] The thickener for oil displacement is acrylamide / sodium acrylate / N-vinylpyrrolidone / stearyl acrylate copolymer, and the composite emulsifier is PGMS and EL-20 (ratio 3:2), The preparation steps are as follows:

[0103] At 50°C, control the mass ratio of oil to water to 6:4, mix 428.6g diesel, 285.7g water, 21.4g PGMS, 14.3g EL-20 to emulsify evenly, stir at 600rmp for 30min to form a stable water-in-oil emulsion , and finally add 250g thickener for oil displacement, and form a uniform and ...

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Abstract

The invention provides a water-in-oil association type concentrated thickener for oil displacement. The water-in-oil association type concentration thickener is prepared from the following components in percentage by mass: 25 weight percent to 50 weight percent of a dispersion medium, 18 weight percent to 45 weight percent of a dispersion phase, 20 weight percent to 40 weight percent of a hydrophobic association polymer thickener for the oil displacement and 2.5 weight percent to 6 weight percent of a compound emulsifier, wherein the dispersion medium is an organic solvent which is not compatible with water; the dispersion phase is water; the compound emulsifier is a compound emulsifier formed by compounding an emulsifier with the HLB (Hydrophile-Lipophile Balance) value of 3 to 7 and an emulsifier with the HLB value of 8 to 10. According to the concentrated thickener provided by the invention, the stabilization time is more than 120d and the dissolution time is less than 5min; performances of a polymer solution prepared from the concentrated thickener provided by the invention are better than performances of a polymer solution which is directly prepared from corresponding thickener powder for the oil displacement.

Description

technical field [0001] The invention belongs to the technical field of oil flooding, and in particular relates to a concentrated thickener for water-in-oil association type oil flooding and a preparation method thereof. Background technique [0002] With the continuous deepening of oilfield exploration and development, it has become impractical to continue to seek new oil resources; at the same time, with the continuous development of existing oilfields, the initial primary and secondary oil recovery methods can no longer achieve good crude oil recovery effects, and seeking new Methods Further improving the oil recovery (tertiary oil recovery) of developed oilfields has become an inevitable trend for stable and increased crude oil production. At present, chemical flooding (that is, injecting chemical agents into the oil layer to change the properties of the displacement phase and the interface properties of the displacement phase and crude oil to improve the recovery of crud...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C09K8/588C09K8/584
CPCC09K8/588C09K8/584
Inventor 郭拥军杨雪杉梁严
Owner SICHUAN GUANGYA POLYMER CHEM
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