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Method for improving silicon dioxide aerogel water phase dispersibility thorugh atomization absorption

A technology for silica and aerogel water, which is applied in chemical instruments and methods, climate sustainability, dyeing low molecular organic compound treatment, etc. and process complexity, to achieve the effect of strong continuous operability, improved dispersion stability, and shortened modification time.

Active Publication Date: 2017-06-20
ECONANO TECH LTD BEIJING
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

Silica aerogels are gradually being used in building envelope structures, coatings and concrete. However, due to the strong hydrophobicity of the airgel surface, the water contact angle is 140-150°, and the density is very small, about 0.02-0.25g / mL, it is difficult to achieve uniform dispersion in aqueous phase materials
However, in commonly used construction materials, such as the doping and use process of airgel in water-based paint, composite materials or chemical methods will increase the production cost and complexity of the process, and even destroy the inherent structure and characteristics of the airgel itself , and the introduction of organic moieties will reduce the combustion performance of airgel materials and increase their fire hazards

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0025] A kind of atomization adsorption that the present invention proposes improves the method for silica airgel aqueous phase dispersibility, comprises the following steps:

[0026] S1, refine the silica airgel powder, and obtain the refined airgel after sieving;

[0027] S2. Atomize the organic solvent with a density greater than water, and then transport it from the top of the closed container into the closed container to form a coating reagent, and then evenly disperse the refined airgel in the closed container to form a powder mist, so that the powder mist Adsorbing the coating reagent to obtain a coated airgel; wherein, the bottom of the closed container is equipped with an aqueous dispersant solution, and is provided with a stirring device and an air blowing device;

[0028] S3. The airgel to be coated sinks to the surface of the dispersant aqueous solution, and the coated airgel with a density greater than or equal to water is stirred and dispersed in the aqueous solu...

Embodiment 2

[0030] A kind of atomization adsorption that the present invention proposes improves the method for silica airgel aqueous phase dispersibility, comprises the following steps:

[0031] S1. Put the silica airgel powder into the ball mill tank, add four kinds of agate balls with particle diameters of 8mm, 11mm, 14mm, and 20mm respectively, set the speed at 100r / min, and mill for 4h for refinement. Obtain fine airgel after sieving;

[0032] S2. Use a pressurized delivery pump to atomize 25mL of dichloromethane, and then add it from the top to the airtight container to disperse to form a coating reagent; use a powder delivery pump to transport 1g of refined airgel and evenly disperse it in the airtight container Forming a powder mist, so that the powder mist absorbs the coating reagent to obtain a coated airgel; wherein, the bottom of the airtight container is equipped with an aqueous solution of polyoxyethylene sorbitan monolaurate, and is provided with a stirring device, and on t...

Embodiment 3

[0036] A kind of atomization adsorption that the present invention proposes improves the method for silica airgel aqueous phase dispersibility, comprises the following steps:

[0037] S1. Put the silica airgel powder into the ball mill tank, add four kinds of balls with particle diameters of 8mm, 11mm, 14mm, and 20mm respectively, set the speed at 300r / min, mill for 2 hours to refine, and sieve Finally, a refined airgel is obtained;

[0038]S2. Use a pressurized delivery pump to atomize 15mL of carbon disulfide, then add it from the top into a closed container to disperse to form a coating reagent; use a powder delivery pump to transport 1g of refined airgel and evenly disperse it in a closed container to form a powder Body mist, so that the powder mist absorbs the coating reagent to obtain the coated aerogel; wherein, the bottom of the airtight container is equipped with a sodium stearate aqueous solution, and is provided with a stirring device and an air blowing device;

[...

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Abstract

The invention discloses a method for improving silicon dioxide aerogel water phase dispersibility through atomization absorption. The method comprises the following steps of fining and sieving silicon dioxide aerogel powder to obtain refined aerogel; atomizing organic solvents with the density being greater than the density of the water; forming a film coating reagent in a sealed container; uniformly dispersing the refined aerogel into a sealed container to form powder fog; adsorbing the film coating reagent by the powder fog to obtain coated aerogel; charging dispersing agent water solution into the bottom of a sealed container, wherein the sealed container is provided with a stirring device and an air blowing device; after the coated aerogel sinks down to the surface of the dispersing agent water solution, stirring and dispersing the coated aerogel with the density being greater than or equal to the density of the water into the water solution; blowing up the coated aerogel with the density being smaller than the density of water so that the coated aerogel is in contact with the film coating reagent again for adsorption. The method for improving silicon dioxide aerogel water phase dispersibility through atomization absorption provided by the invention has the advantages that the inherent structure and characteristics of the silicon dioxide aerogel are remained; the stable dispersion of the silicon dioxide aerogel in the water phase is realized; the work procedures are simple; the cost is low.

Description

technical field [0001] The invention relates to the technical field of hydrophobic silica aerogels, in particular to a method for improving the dispersibility of the silica airgel by atomization adsorption. Background technique [0002] Silica airgel has good thermal insulation properties. Compared with traditional inorganic thermal insulation materials and organic thermal insulation materials in the field of building energy-saving thermal insulation, airgel has more obvious advantages in civil thermal insulation materials, especially external wall thermal insulation. Silica airgel has a nanoporous and three-dimensional network skeleton structure, and has the advantages of low density, small pore size, high porosity, large specific surface area, and low thermal conductivity. Moreover, cheap water glass, rice husk ash, etc. can be used as raw materials for preparation, and the preparation cost is low. Silica aerogels are gradually being used in building envelopes, coatings a...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C04B18/14C04B14/06C04B20/10
CPCC09C1/28C09C3/006C09C3/04C09C3/08Y02W30/91
Inventor 马丽艳刘忠
Owner ECONANO TECH LTD BEIJING
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