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A method for preparing a transparent wear-resistant film suitable for watch parts

A wear-resistant film and transparent technology, which is applied in metal material coating process, vacuum evaporation plating, coating, etc., can solve the problems of non-wear resistance, anti-corrosion performance decline, low hardness of stainless steel, etc., and achieve remarkable ductility and combination Good strength and low film brittleness

Active Publication Date: 2019-02-12
TIAN WANG ELECTRONICS (SHENZHEN) CO LTD +1
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0002] Watch parts such as watch bases and straps are generally made of austenitic stainless steel, but the hardness of austenitic stainless steel is not high, and it is prone to defects such as scratches and scratches. Generally, chemical heat treatment is required to improve its hardness, but chemical heat treatment After the structure of the base material changes, the anti-corrosion performance will be significantly reduced; in addition, due to the needs of decoration, some parts of the clock and watch parts need to be coated with various colored coatings (films) after chemical treatment, such as the rose gold layer (main component is gold), these coating (film) layers are not wear-resistant, and are prone to scratches, scratches, discoloration, fading, etc.
The quality requirements for watch parts are: (1) good anti-corrosion performance, and the standard salt spray resistance time is not less than 72 hours; (2) good wear resistance, high surface hardness, which requires more than 700Hv; (3) constant color, no Discoloration is allowed; (4) The coating (film) layer has a certain degree of ductility, and the bonding force with the substrate is better, and can pass the bonding force detection of watch parts; the existing technology cannot meet the above requirements

Method used

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  • A method for preparing a transparent wear-resistant film suitable for watch parts

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Experimental program
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Effect test

Embodiment 1

[0018] Using niobium pentoxide and zirconium dioxide composite coating transparent film technology under high vacuum conditions: the coating target material is niobium pentoxide and zirconium dioxide composite material, wherein the content of niobium pentoxide (weight percentage, the same below) 85%-95%; the content of zirconia is 5%-15%; using intermediate frequency constant voltage coating power supply, coating voltage 400V, frequency 5KHz-15KHz, the positive pole of the power supply is connected to the workpiece, and the negative pole is connected to the target material; Argon gas is used as the The protective gas is used to adjust the vacuum degree in the furnace, and the vacuum degree in the furnace is 5.0-6.0×10 -3 Pa; temperature is 200°C-300°C; coating time is 10-30 minutes.

Embodiment 2

[0020] Adopt niobium pentoxide and zirconium dioxide composite transparent film coating technology under high vacuum conditions: directly apply niobium pentoxide and zirconium dioxide transparent composite film on the infiltrated layer, and the content of niobium pentoxide in the target material is 85% %; the content of zirconia is 15%; the coating voltage is 400V, the frequency is 15KHz, the positive electrode of the power supply is connected to the workpiece, and the negative electrode is connected to the target material; argon is used as a protective gas to adjust the vacuum degree in the furnace. 6.0×10 -3 Pa; the temperature is 300°C; the coating time is 30 minutes, and a transparent film layer with a thickness of about 2 microns can be formed.

Embodiment 3

[0022] Niobium pentoxide and zirconium dioxide composite coating transparent film technology under high vacuum conditions: apply niobium pentoxide and zirconium dioxide transparent composite film on the rose gold plating (film) layer, and the target material is niobium pentoxide The content of zirconium dioxide is 95%; the content of zirconia is 5%; the coating voltage is 400V, the frequency is 5KHz, the positive electrode of the power supply is connected to the workpiece, and the negative electrode is connected to the target material; argon is used as a protective gas to adjust the vacuum in the furnace. The degree is 5.0-6.0×10 -3 Pa; the temperature is 200°C; the coating time is 10 minutes, and a transparent film layer with a thickness of about 0.5 microns can be formed.

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Abstract

The invention discloses a preparation method for a transparent abrasion-resistant film suitable for a clock part. Niobium pentoxide and zirconium dioxide composite plating transparent film technology under the high vacuum condition is adopted, the plating target material is a niobium pentoxide and zirconium dioxide composite, wherein the content of the niobium pentoxide is 85%-95%, and the content of the zirconium dioxide is 5%-15%. An intermediate frequency constant-voltage coating power source is adopted, the voltage is 400 V, the frequency is 5 KHz-15 KHz, a power anode is connected with a workpiece, and a cathode is connected with the target material. Argon serves as protective gas and is used for adjusting the in-furnace vacuum degree, and the in-furnace vacuum degree is 5.0-6.0x10-3 Pa, the temperature is 200 DEG C-300 DEG C, and the coating time is 10-30 minutes. The composite film prepared through the preparation method is transparent, the original appearance impression of the clock is not lowered, abrasion resistance is good, corrosion prevention performance is high, the film layer brittleness is small, the film layer falling phenomenon is avoided, and constancy of the original bottom color can be ensured.

Description

technical field [0001] The invention relates to a preparation method of a transparent film, in particular to a preparation method of a transparent wear-resistant film suitable for watch parts. Background technique [0002] Watch parts such as watch bases and straps are generally made of austenitic stainless steel, but the hardness of austenitic stainless steel is not high, and it is prone to defects such as scratches and scratches. Generally, chemical heat treatment is required to improve its hardness, but chemical heat treatment After the structure of the base material changes, the anti-corrosion performance will be significantly reduced; in addition, due to the needs of decoration, some parts of the clock and watch parts need to be coated with various colored coatings (films) after chemical treatment, such as the rose gold layer (main component It is gold), these coating (film) layers are not wear-resistant, and are prone to scratches, scratches, discoloration, and fading....

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): C23C14/08C23C14/22
CPCC23C14/083C23C14/22
Inventor 张克来林育周罗建东侯庆海
Owner TIAN WANG ELECTRONICS (SHENZHEN) CO LTD
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