A kind of preparation method of flame-retardant nonwoven fabric
A technology of non-woven fabrics and liquid crystal polymers, applied in the direction of non-woven fabrics, textiles and papermaking, feeding solutions to spinnerets, etc., can solve the problems of poor flame retardant effect, high cost, complicated process, etc. Effects of viscosity, improved filtration, and excellent flame retardancy
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[0021] A preparation method of flame-retardant nonwoven fabric, the steps are as follows:
[0022] (1) Blend the slices of liquid crystal polymer and polymer evenly according to the ratio of 1: (1-19), and after vacuum drying for 8-24 hours, carry out melt extrusion granulation in the granulator to prepare composite polymer slice;
[0023] (2) Send the composite polymer chips prepared in step (1) into a twin-screw extruder, and use meltblown technology or spunbond method to complete the preparation of flame-retardant nonwoven fabrics.
[0024] In the step (1), the liquid crystal polymer is a phosphorus-containing liquid crystal polymer, and the phosphorus-containing liquid crystal polymer has the following structural units:
[0025]
[0026] Among them, R 1 The structure is
[0027] R 2 Any of the following structures: Wherein n is an integer of 4-10;
[0028] R 3 Any of the following structures:
[0029] The melting point of the phosphorus-containing liquid ...
Embodiment 1
[0037] Phosphorus-containing liquid crystal polymer A and PA-66 are uniformly blended at a mass ratio of 3:17, dried at 110°C and vacuum degree of 20Pa for 12 hours, and then melted and extruded in a granulator for granulation to obtain a phosphorus-containing composite polymer The material is sliced, and the melting temperature is 270°C. After vacuum drying, the chips are sent to a twin-screw extruder with an aspect ratio of 45. After preheating, melting, filtering and metering, they are sent to the spinneret die to extrude a thin stream of melt through the spinneret. . The temperatures of the feed section, compression section and metering section of the screw are 180°C, 280°C, and 310°C respectively, and the screw speed is 25 rpm. The melt-blown technology is used, that is, after the fine flow of the melt is stretched and refined by hot air, it is condensed into a web on the receiving device, and the fiber web is trimmed and wound to obtain a flame-retardant melt-blown PA-6...
Embodiment 2
[0040] Phosphorus-containing liquid crystal polymer B and PET are uniformly blended at a mass ratio of 1:4, dried at 110°C and vacuum degree of 50Pa for 18 hours, and then melted and extruded in a granulator for granulation to obtain phosphorus-containing composite polymer chips , and the melt extrusion temperature was 280°C. After vacuum drying, the chips are sent to a twin-screw extruder with an aspect ratio of 40. After preheating, melting, filtering and metering, they are sent to the spinneret die to extrude a thin stream of melt through the spinneret. . The temperatures of the feed section, compression section and metering section of the screw are 170°C, 280°C, and 300°C, respectively, and the screw speed is 25 rpm. The melt-blown technology is used, that is, after the fine flow of the melt is stretched and refined by hot air, it is condensed into a web on the receiving device, and the fiber web is trimmed and wound to obtain a flame-retardant melt-blown PET nonwoven fab...
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