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Production method for microwave catalytic pyrolysis of Eupatorium adenophorum

A technology of Eupatorium adenophorum and its production method, which is applied in the field of comprehensive resource utilization, can solve the problems of inability to apply dye wastewater adsorbent, ignore the comprehensive utilization of biomass oil, and reduce the utilization rate of resources, so as to achieve circular economy and product added value High, product cleaning effect

Inactive Publication Date: 2017-07-25
KUNMING UNIV OF SCI & TECH
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

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Problems solved by technology

However, this invention only considers the utilization of biomass gas products, but ignores the comprehensive utilization of biomass oil and biomass carbon, and the utilization rate of resources is greatly reduced
[0009] The patent application number is 201410547885.7, and the name is a method for directional production of biomass charcoal, biomass oil and biomass gas by using microwave catalytic pyrolysis of biomass. It discloses a method of uniformly mixing biomass with metal salts or metal oxide catalysts. , and then pyrolyzed to obtain gas products and solid products, the gas products are rapidly condensed, the condensable part is directly condensed into liquid high-quality biomass oil, and the non-condensable gas is a high calorific value gas fuel; the solid product is taken out after cooling to room temperature with the furnace to obtain High-yield biochar, the high-yield biochar is directly used as a raw material or fuel for the production of activated carbon, but the specific surface area of ​​activated carbon is only 300-400m 2 / g, when adsorbing dye wastewater, the adsorption capacity is small, so it cannot be used as an adsorbent in dye wastewater

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0028] The microwave catalyzed pyrolysis method for producing Eupatorium adenophorum, its specific steps are as follows:

[0029] (1) First put Eupatorium adenophorum in 0.5mol / LFeSO according to the liquid-solid ratio of 3:1g / ml 4 In the solution, soak for 90 minutes under ultrasonic conditions (ultrasonic power is 150W), then filter and dry to obtain Eupatorium adenophorum after soaking;

[0030] (2) Put the Eupatorium adenophorum obtained in step (1) in a microwave oven under a carbon dioxide atmosphere (the amount of carbon dioxide introduced is 150ml / min), and pyrolyze it at 700°C for 90 minutes to obtain gas products and solid products;

[0031] (3) The gas product obtained in step (2) is rapidly condensed at -2°C, and the condensable part is directly condensed into a liquid-phase high-quality biomass oil, which is further processed to obtain a bio-oil fuel, and the non-condensable part is a gas fuel. After treatment, it can be used instead of fuel; the solid product ob...

Embodiment 2

[0034] The microwave catalyzed pyrolysis method for producing Eupatorium adenophorum, its specific steps are as follows:

[0035] (1) First put Eupatorium adenophorum in 0.3mol / LFeSO according to the liquid-solid ratio of 5:1g / ml 4 In the solution, soak for 30 minutes under ultrasonic conditions (ultrasonic power is 50W), then filter and dry to obtain Eupatorium adenophorum after soaking;

[0036] (2) Put the Eupatorium adenophorum obtained in step (1) in a microwave oven under a carbon dioxide atmosphere (the amount of carbon dioxide introduced is 350ml / min), and pyrolyze it at a temperature of 900°C for 30 minutes to obtain gas products and solid products;

[0037] (3) The gas product obtained in step (2) is rapidly condensed at -2°C, and the condensable part is directly condensed into a liquid-phase high-quality biomass oil, which is further processed to obtain a bio-oil fuel, and the non-condensable part is a gas fuel. After treatment, it can be used instead of fuel; the so...

Embodiment 3

[0040] The microwave catalyzed pyrolysis method for producing Eupatorium adenophorum, its specific steps are as follows:

[0041] (1) First put Eupatorium adenophorum in 0.4mol / LFeSO according to the liquid-solid ratio of 4:1g / ml 4 In the solution, immerse under ultrasonic conditions for 60min (ultrasonic power is 100W), then filter and dry to obtain Eupatorium adenophorum after immersion;

[0042] (2) Put the Eupatorium adenophorum obtained in step (1) in a microwave oven under a carbon dioxide atmosphere (the amount of carbon dioxide introduced is 200ml / min), and pyrolyze it at 800°C for 60 minutes to obtain gas products and solid products;

[0043] (3) The gas product obtained in step (2) is rapidly condensed at -2°C, and the condensable part is directly condensed into a liquid-phase high-quality biomass oil, which is further processed to obtain a bio-oil fuel, and the non-condensable part is a gas fuel. After treatment, it can be used instead of fuel; the solid product ob...

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Abstract

The invention relates to a production method for microwave catalytic pyrolysis of Eupatorium adenophorum, and belongs to the technical field of comprehensive utilization of resources. The method comprises the following steps: placing Eupatorium adenophorum in a FeSO4 solution, impregnating the Eupatorium adenophorum under an ultrasonic condition, and carrying out filtering and drying to obtain impregnated Eupatorium adenophorum; placing the Eupatorium adenophorum in carbon dioxide atmosphere in a microwave oven, and pyrolyzing the Eupatorium adenophorum at 700-900 DEG C for 30-90 min to obtain a gas product and a solid product; rapidly condensing the gas product at -2 DEG C to directly condense a condensable part into a liquid-phase high quality bio-oil, further processing the bio-oil to obtain a bio-oil fuel, and processing a non-condensable part to form a fuel substitute; and cooling the solid product to room temperature in order to obtain magnetic active carbon. The method allows the high-added value products bio-mass carbon, gas and oil to be prepared through the microwave catalytic pyrolysis of a raw material Eupatorium adenophorum by using FeSO4 as a catalyst, and so the comprehensive utilization of the Eupatorium adenophorum is realized.

Description

technical field [0001] The invention relates to a microwave catalytic pyrolysis production method of Eupatorium adenophorum, belonging to the technical field of comprehensive utilization of resources. Background technique [0002] With the depletion of fossil energy, human beings have to face the increasingly serious energy crisis and chemical resource crisis. Searching for clean and renewable energy and green chemicals has become the focus of research in various countries. Biomass resources as a cheap [0003] Renewable resources that are easy to obtain and come from a wide range of sources have great potential for development and application. Researchers from all over the world have conducted active exploration and experimental research on the utilization of biomass resources, and have achieved certain research results. However, these studies often focus on a certain aspect of the utilization of biomass resources, which belongs to the way of "separate efforts" and does no...

Claims

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Application Information

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IPC IPC(8): C10G1/00C10B53/02C01B32/318
CPCC10B53/02C10G1/00C10G2300/1014Y02E50/10
Inventor 夏洪应程松张利波彭金辉舒建华李春阳
Owner KUNMING UNIV OF SCI & TECH