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A low-temperature dripping water absorption catalytic denitrification method

A catalytic denitration and absorption technology, applied in the field of flue gas denitrification, can solve the problems of low operating cost, large ozone consumption, low flue gas denitration efficiency, etc., and achieve the effects of wide application range, simple treatment process and stable denitration effect.

Active Publication Date: 2021-02-09
SHANDONG UNIV
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

Ozone oxidation technology is simple, but the consumption of ozone is large, the energy consumption of ozone generation is high, and the operating cost is high
[0005] To sum up, there is still a lack of effective solutions to the problems of low operating cost of flue gas denitrification and low denitrification efficiency of high humidity and low temperature flue gas in the prior art

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0027] A low-temperature drip absorption catalytic denitrification method, comprising the following steps: setting the catalyst layer horizontally, the low-temperature flue gas at 90°C flows through the catalyst layer from bottom to top, and the flue gas space velocity is 8000h -1 , continuously spray water mist to the catalyst layer above the catalyst layer, the ratio of the sprayed water mist flow rate to the flue gas flow rate is 1%:1, so that the catalyst layer is in a wet state, and the NO in the flue gas is oxidized under the catalytic action of the catalyst for NO 2 , the generated NO 2 Absorbed by water mist, nitric acid droplets are generated, and the nitric acid droplets flow down the catalyst wall and are collected at the bottom of the catalyst layer.

[0028] The catalyst comprises activated carbon porous carrier and cobalt oxide and tungsten oxide loaded on the activated carbon porous carrier. The removal efficiency of NO in flue gas is 95%.

Embodiment 2

[0030] A low-temperature drip absorption catalytic denitrification method, comprising the following steps: setting the catalyst layer horizontally, low-temperature flue gas at 150°C flows through the catalyst layer from bottom to top, and the flue gas space velocity is 10000h -1 , continuously spray water mist to the catalyst layer above the catalyst layer, the ratio of the sprayed water mist flow rate to the flue gas flow rate is 0.1%:1, so that the catalyst layer is in a wet state, and the NO in the flue gas is oxidized under the catalytic action of the catalyst for NO 2 , the generated NO 2 Absorbed by water mist, nitric acid droplets are generated, and the nitric acid droplets flow down the catalyst wall and are collected at the bottom of the catalyst layer.

[0031] The catalyst includes active coke porous carrier and nickel oxide loaded on the active coke porous carrier. The catalyst is granular, and the granular catalyst is loaded on the network structure to form a ca...

Embodiment 3

[0033] A low-temperature drip absorption catalytic denitrification method, comprising the following steps: setting the catalyst layer horizontally, low-temperature flue gas at 120°C flows through the catalyst layer from bottom to top, and the flue gas space velocity is 4000h -1 , continuously spray water mist to the catalyst layer above the catalyst layer, the ratio of the sprayed water mist flow rate to the flue gas flow rate is 0.01%:1, so that the catalyst layer is in a wet state, and the NO in the flue gas is oxidized under the catalytic action of the catalyst for NO 2 , the generated NO 2 Absorbed by water mist, nitric acid droplets are generated, and the nitric acid droplets flow down the catalyst wall and are collected at the bottom of the catalyst layer.

[0034] The catalyst comprises activated carbon porous carrier and copper oxide and iron oxide loaded on the activated carbon porous carrier. The catalyst layer is a plate catalyst. The removal efficiency of NO in ...

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PUM

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Abstract

The invention discloses a low-temperature drip absorption catalytic denitrification method, which solves the problems of low operating cost of flue gas denitrification and low denitrification efficiency of high-humidity and low-temperature flue gas in the prior art, and has temperature requirements for flue gas Low, simple treatment process, low operating cost, stable denitrification effect, and less water consumption. The technical solution is: when the low-temperature flue gas flows through the catalyst layer, water mist is continuously sprayed on the catalyst layer to keep the catalyst layer in a wet state, and the NO in the flue gas is oxidized to NO under the catalytic action of the catalyst. 2 , the generated NO 2 Absorbed by water mist.

Description

technical field [0001] The invention belongs to the technical field of flue gas denitrification, and in particular relates to a low-temperature drip absorption type catalytic denitrification method. Background technique [0002] Nitrogen oxides (NO x ) is one of the main air pollutants. The acid rain or acid mist formed combines with hydrocarbons to form photochemical smog, which destroys the ozone layer. Currently, more than 60% of nitrogen oxides come from flue gas from coal combustion. [0003] At present, the most widely used, mature and effective flue gas denitrification technology in the world is NH 3 -SCR technology (selective catalytic reduction of NO with ammonia as reducing agent x ). NH 3 -SCR technology has high denitrification efficiency, is mature and reliable, and has strong adaptability. It is especially suitable for coal-fired units in areas with variable coal quality, frequent unit load changes and sensitive air quality requirements. Since the SCR tec...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): B01D53/86B01D53/56
CPCB01D53/8625B01D2255/2065B01D2255/20707B01D2255/20723B01D2255/2073B01D2255/20738B01D2255/20746B01D2255/20753B01D2255/20761B01D2255/20776B01D2255/20784B01D2255/2092B01D2255/70B01D2255/702B01D2258/0283
Inventor 程星星马春元王志强
Owner SHANDONG UNIV