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Alkali-activated slag cement retarder and preparation method thereof

A technology of alkali slag cement and retarder, applied in the field of building materials, can solve problems such as not being widely used, and achieve the effects of inhibiting the phenomenon of efflorescence, simple use and good retardation effect.

Inactive Publication Date: 2017-09-15
UNIV OF JINAN
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0004] Although alkali slag cement has a series of excellent properties that ordinary Portland cement does not have, such as rapid hardening and early strength, high temperature resistance, corrosion resistance, low-carbon environmental protection, etc., it is still not widely used, mainly because there are technical problems in its construction and use. Difficulty: Fast setting problem

Method used

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  • Alkali-activated slag cement retarder and preparation method thereof
  • Alkali-activated slag cement retarder and preparation method thereof
  • Alkali-activated slag cement retarder and preparation method thereof

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0026] Take by weighing 45kg of industrial-grade boric acid, 25kg of brown sugar, and 30kg of superfine slag powder, and fully mix the raw materials of the above-mentioned quality in a mixer for 10 hours to ensure that they are fully mixed. The mixed material was ground in a ball mill for 5 hours, and its specific surface area was determined to be 480m 2 / kg. attached by figure 1 It can be seen that with the increase of retarder content, the compressive strength of alkali slag cement first increases and then decreases, and the optimum retarder content is 15.0%. The addition of retarder can increase the setting time of alkali slag cement, improve the fluidity of alkali slag cement slurry, and increase the compactness of samples, thereby improving the compressive strength.

Embodiment 2

[0028] Weigh 40kg of industrial-grade boric acid, 20kg of sucrose, and 40kg of superfine slag powder, and fully mix the above-mentioned quality raw materials in a mixer for 10 hours to ensure that they are fully mixed. The mixed material was ground in a ball mill for 6 hours, and its specific surface area was determined to be 500m 2 / kg. attached by figure 2 It can be seen that with the increase of retarder, the initial setting time, final setting time and interval of alkali slag cement increase, and the setting time can be adjusted, which is beneficial to the construction and use of alkali slag cement. attached image 3 It shows that the increase of retarder content can improve the pH value of hardened slurry of alkali slag cement and inhibit the efflorescence of alkali slag cement after hardening.

Embodiment 3

[0030] Weigh 50kg of industrial-grade boric acid, 30kg of brown sugar, and 20kg of superfine slag powder, and fully mix the above-mentioned quality raw materials in a mixer for 10 hours to ensure that they are fully mixed. The mixed material was ground in a ball mill for 7 hours, and its specific surface area was determined to be 545m 2 / kg. attached by Figure 4 It can be seen that the concentration of carbonate ions is the characterization of the degree of efflorescence of alkali slag cement slurry. With the increase of retarder, the concentration of carbonate ions in the leaching solution of hardened slurry of alkali slag cement decreases first and then slightly increases. It fully shows that the retarder can inhibit the efflorescence of alkali slag cement. attached by Figure 5 It is not difficult to see that when the retarder is added at 15.0% mass fraction, the pore size of the hardened slurry of alkali slag cement is greatly reduced, from harmful pores gradually to h...

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Abstract

The invention relates to the technical field of building materials, in particular to a retarder capable of prolonging alkali-activated slag cement setting time and increasing an interval between initial setting time and final setting time, and a preparation method of the retarder. The alkali-activated slag cement retarder is characterized by being prepared from the following raw materials by weight percent: 30-50% of boric acid, 15-35% of brown sugar and 15-55% of superfine slag powder. The alkali-activated slag cement retarder is simple to use; only based on the mass of alkali content of alkali-activated slag cement during preparation, the mixing amount of the retarder is 10-15% of alkali mass, and the proportion of the retarder is 2.0-3.0% of the mass of the alkali-activated slag cement, so that the cost is lower; the retarder has a good retarding effect; according to the different mixing amounts, the initial setting time can be adjusted to 2-15h, the interval between the initial setting time and the final setting time is increased, and the final setting time can be adjusted to 10-25h; the increment and development of early strength and later strength are not influenced; the alkali-activated slag cement retarder can be used for inhibiting the efflorescence phenomenon of the alkali-activated slag cement after construction; the retarder can absorb excessive alkali added into the alkali-activated slag cement by means of a neutralization reaction, and has an inhibiting effect on the efflorescence phenomenon of the building materials after construction.

Description

technical field [0001] The invention relates to the technical field of building materials, in particular to a retarder capable of prolonging the setting time of alkali slag cement and increasing the interval between initial setting time and final setting time and a preparation method thereof. Background technique [0002] Building materials are the most widely used class of materials. At present, the application process of traditional building materials follows the pattern of development-application-abandonment, which leads to the depletion of resources, and causes a large amount of waste materials, pollutant discharge and environmental degradation. For every ton of steel produced, tens of tons of steel slag, slag and other waste slag will be produced. The discharge of solid waste occupies land, pollutes the environment, endangers human health, and also causes a huge waste of resources. How to reduce the consumption of non-renewable resources, make full use of industrial w...

Claims

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Application Information

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IPC IPC(8): C04B24/10C04B103/22
CPCC04B40/0039C04B2103/22C04B22/0013C04B24/10C04B22/0006
Inventor 周宗辉王金邦程新杜鹏
Owner UNIV OF JINAN
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