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Excellent-performance colorful basic paint emulsion and preparation method thereof

A basic paint, colorful technology, applied in the field of basic paint emulsion, can solve the problems of easy breakage, color bleeding emulsion, low glass transition temperature of elastic emulsion, etc., to achieve good water and alkali resistance, weather resistance, strong charge balance stability, anti Excellent bleeding performance

Inactive Publication Date: 2017-09-15
佛山市顺德区巴德富实业有限公司
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

However, most of the colorful base paint emulsions in the market are elastic emulsions and conventional emulsions. First, because the glass transition temperature of elastic emulsions is very low, the water resistance and adhesion of the colored spots are very poor. Second, conventional emulsions have good mechanical properties, but the color dots have high hardness and will be easily broken during the manufacturing process, causing color bleeding and emulsion bleeding. Conventional transportation and storage may easily cause color mixing or blooming, or even paste. It is difficult to meet the performance requirements of multi-color base paint due to quality accidents caused by globalization, and there are very few multi-color base paint emulsions in the true sense.

Method used

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  • Excellent-performance colorful basic paint emulsion and preparation method thereof

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preparation example Construction

[0027] The present invention also provides a method for preparing the above-mentioned multicolor base paint emulsion with excellent performance, comprising the following steps:

[0028] 1) Preparation of base material liquid A: Add 10-30 parts of deionized water and 0.5-1 part of surfactant to the reaction kettle with agitator, condenser and constant flow pump feeding device, and heat up to the temperature in the kettle Reach 80-90°C;

[0029] 2) Preparation of monomer solution B: 5-10 parts of methyl methacrylate, butyl acrylate, styrene, acrylic acid, functional monomer, remaining surfactant, and deionized water in a formula amount under normal temperature and pressure Mix into a uniform solution and stir for 10-30 minutes for later use;

[0030] 3) Preparation of initiator solution C: add the formula amount of persulfate into the remaining deionized water, stir to dissolve;

[0031] 4) When the temperature in the kettle reaches 80-90°C, add 1-5 parts of step 2) to prepare...

Embodiment 1

[0035] A colorful base paint emulsion with excellent performance, including methyl methacrylate, butyl acrylate, styrene, acrylic acid, functional monomer, surfactant, persulfate, water, the contents of the above components are calculated in parts by mass It is: 10 parts of methyl methacrylate, 15 parts of butyl acrylate, 4 parts of styrene, 2 parts of acrylic acid, 1 part of functional monomer, 1 part of surfactant, 0.1 part of persulfate, and 50 parts of water.

[0036] The functional monomer is vinyltrimethoxysilane.

[0037] The surfactant is an anionic emulsifier and a nonionic emulsifier mixed in a mass ratio of 1:1 to form a combined emulsifier.

[0038] The anionic emulsifier adopts C10-C20 alkyl sulfate.

[0039] The nonionic emulsifier adopts alkylphenol polyoxyethylene ether.

[0040] The persulfate is ammonium persulfate.

[0041] 1) Preparation of base liquid A: Add 10 parts of deionized water and 0.5 parts of surfactant to a reaction kettle equipped with a stirr...

Embodiment 2

[0047] A colorful base paint emulsion with excellent performance, including methyl methacrylate, butyl acrylate, styrene, acrylic acid, functional monomer, surfactant, persulfate, water, the contents of the above components are calculated in parts by mass It is: 15 parts of methyl methacrylate, 19 parts of butyl acrylate, 6 parts of styrene, 3 parts of acrylic acid, 2 parts of functional monomer, 2 parts of surfactant, 0.3 part of persulfate, and 50 parts of water.

[0048] The functional monomer is methacryloxypropyltrimethoxysilane.

[0049] The surfactant is an anionic emulsifier and a nonionic emulsifier mixed in a mass ratio of 3:1 to form a combined emulsifier.

[0050] The anionic emulsifier uses 1.5 parts of sodium dialkyl-2-sulfosuccinate.

[0051] The nonionic emulsifier adopts 0.2 parts of polyoxyethylene sorbitan monooleate and 0.3 parts of alkyl alcohol polyoxyethylene ethers.

[0052] The persulfate is potassium persulfate.

[0053] 1) Preparation of base mate...

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Abstract

The invention discloses an excellent-performance colorful basic paint emulsion. The emulsion contains following components in parts by weight: 10-20 parts of methyl methacrylate, 15-25 parts of butyl acrylate, 4-10 parts of styrene, 2-5 parts of acrylic acid, 1-3 parts of functional monomers, 1-3 parts of a surfactant, 0.1-1 part of persulfate and 50 parts of water. The excellent-performance colorful basic paint emulsion has good water tolerance, alkali resistance and weather resistance.

Description

technical field [0001] The invention relates to a base paint emulsion, in particular to a multicolor base paint emulsion with excellent performance and a preparation method thereof. Background technique [0002] Water-in-water colorful paint is composed of incompatible two-phase components, one of which is the continuous phase of the dispersion medium, and the other is the dispersed phase. The dispersed phase is also called the base paint, which is composed of high molecular polymers and inorganic materials. Toning can get rich and colorful colored particles, so that the colorful paint has richer colors and more realistic imitation granite effect than traditional real stone paint. However, most of the colorful base paint emulsions in the market are elastic emulsions and conventional emulsions. First, because the glass transition temperature of elastic emulsions is very low, the water resistance and adhesion of the colored spots are very poor. Second, conventional emulsions ...

Claims

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Application Information

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IPC IPC(8): C09D133/08C09D5/29C08F220/18C08F220/14C08F212/08C08F220/06C08F230/08C08F2/26C08F2/30
CPCC08F2/26C08F2/30C08F220/18C08F220/1804C09D5/29C09D133/08C08F220/14C08F212/08C08F220/06C08F230/08
Inventor 谢彪李师雄罗云
Owner 佛山市顺德区巴德富实业有限公司