Light-free formaldehyde removal catalyst, formaldehyde removal system containing catalyst and purpose thereof

A catalyst and system technology, applied in the environmental field, can solve the problems of product toxicity, pollution hazards, etc., and achieve the effect of solving the problem of aldehyde removal

Active Publication Date: 2017-09-22
ZHEJIANG SCI-TECH UNIV
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0005] The third category: Spraying aldehyde-dissolving enzymes, aldehyde-dissolving enzymes can oxidize aldehydes into acids or reduce them to alcohols, but the toxicity of the products still exists, and spraying high-concentration scavengers in the air will harm people. Create new pollution hazards
[0006] The fourth category: the application of air purifiers. In the case of indoor air pollution, the use of air purifiers can reduce the degree of pollution to a certain extent, but air purifiers can only play an auxiliary and remedial role, and do not mean Can fundamentally eliminate air pollution
At present, there is no technology that can effectively decompose aldehydes once they are released in the absence of light.

Method used

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  • Light-free formaldehyde removal catalyst, formaldehyde removal system containing catalyst and purpose thereof
  • Light-free formaldehyde removal catalyst, formaldehyde removal system containing catalyst and purpose thereof
  • Light-free formaldehyde removal catalyst, formaldehyde removal system containing catalyst and purpose thereof

Examples

Experimental program
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Effect test

Embodiment 1

[0075] In this example, an Ag / MgO catalyst is prepared by taking the transition metal as Ag and the basic carrier as MgO as an example to illustrate the non-light aldehyde removal catalyst involved in the present invention. The preparation method of the catalyst is as follows: add 11 mg of silver nitrate to 15 ml of oleylamine solution, stir at 90 degrees for 1 hour, add 120 mg of tert-butylboramine borane as a reducing agent, and adjust the reaction temperature to 120 degrees , reacted for 3 hours, cooled to room temperature, added absolute ethanol to precipitate and washed, centrifuged and dried to obtain Ag nanoparticles. Then the prepared Ag nanoparticles were dissolved in chloroform to form a 1mol / L solution, and then the MgO solid powder was added into the chloroform solution, and stirred and adsorbed at room temperature for 2-5 hours. When the adsorption equilibrium is reached, the stirring is stopped and the solution is allowed to stand still for about 10 minutes, then...

Embodiment 2

[0080] Add 20 mg of chloroplatinic acid into 10 ml of oleylamine solution, stir at 100 degrees for 1 hour, add 220 mg of tert-butylboramine borane as a reducing agent, adjust the reaction temperature to 120 degrees, react for 4 hours and then cool to room temperature, add absolute ethanol to precipitate and wash, and obtain Pt nanoparticles after centrifugation and drying. Then the prepared Pt nanoparticles are dissolved in chloroform to form a 1mol / L solution, and then the MgO solid powder is added into the chloroform solution, and stirred and adsorbed at room temperature for 2-5 hours. When the adsorption equilibrium is reached, the stirring is stopped and the solution is left to stand for about 20 minutes, then the above-mentioned adsorbed precipitate is vacuum-dried, and finally calcined at 500° C., and the size distribution of the obtained Pt nanoparticles is 5-50 nm.

[0081] The above-prepared Pt / MgO catalyst was placed in a solution of DMPO trapping agent containing fo...

Embodiment 3

[0083] 20 milligrams of chloroplatinic acid and 10 milligrams of silver nitrate were added to 20 milliliters of oleylamine solution, and after stirring at 100 degrees for 1 hour, 340 milligrams of tert-butylboramine borane was added as a reducing agent, and the reaction temperature was adjusted to 120 degrees. After reacting for 4 hours, cool to room temperature, add absolute ethanol to precipitate and wash, and obtain PtAg nano-alloy particles after centrifuging and drying, with a particle size of about 10 nm. Then the prepared PtAg nano-alloy particles are dissolved in chloroform to form a 1mol / L solution, and then the MgO solid powder is added into the above-mentioned chloroform solution, and stirred and adsorbed at room temperature for 2-5 hours. When the adsorption equilibrium is reached, the stirring is stopped and the solution is left to stand for about 20 minutes, then the above-mentioned adsorbed precipitate is vacuum-dried, and finally calcined at 500° C., and the siz...

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Abstract

The invention relates to a light-free formaldehyde removal catalyst, which can effectively decompose formaldehyde substances in light-free environment and can effectively decompose formaldehyde substances under the condition of no need of external energy. The light-free formaldehyde removal catalyst is prepared from transition metal particles and alkaline carriers; the transition metal particles are loaded onto the surface of the alkaline carriers; after the transition metal particles and the alkaline carriers are in contact with air and / or aldehyde substances, active oxygen species are generated in the interface positions of the transition metal particles and the alkaline carriers; an alkaline carrier-transition metal-active oxygen species structure is formed; the active oxygen species comprise superoxide free radicals, peroxy free radicals and hydroxyl free radicals; the alkaline carrier-transition metal-active oxygen species structure comprises alkaline carrier-transition metal-superoxide free radicals, alkaline carrier-transition metal-hydroperoxide free radicals and / or alkaline carrier-transition metal-hydroxyl radicals. The light-free formaldehyde removal catalyst provided by the invention has the advantages that the formaldehyde removal efficiency is very high; the cost is low; the formaldehyde removal efficiency can reach 99.9 percent to the highest degree.

Description

technical field [0001] The invention relates to the field of environment, in particular to a non-light aldehyde removal catalyst, an aldehyde removal system containing the catalyst and its application. Background technique [0002] In modern society, aldehydes generally exceed the standard after decoration of new houses. Aldehyde is a gas with a strong pungent smell, not only pungent, but also harmful to the human body and has a long incubation period. It is called "the first killer of indoor pollution"; The main cause of leukemia, memory and intelligence decline of teenagers, has been identified as "carcinogenic and teratogenic substances" by the World Health Organization. Therefore, there are various methods for removing aldehydes on the market. Generally speaking, they can be divided into the following categories: [0003] The first category: physical adsorption of porous materials, such as activated carbon, bamboo charcoal and diatomaceous earth, etc., but this method ...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): B01J23/66B01J23/58B01J23/30B01J23/28B01J23/78B01J27/22B01J29/44B01J29/03B01J37/08B01J37/16B01D53/86B01D53/72D06M11/83D06M11/44D06M13/342D06M15/03D06M101/06D06M101/10D06M101/32
CPCB01D53/8668D06M11/44D06M11/83D06M13/342D06M15/03C01B3/042C01B3/326B01J23/28B01J23/30B01J23/58B01J23/66B01J23/78B01J27/22B01J29/0325B01J29/44B01J35/008B01J37/088B01J37/16D06M2101/10D06M2101/06D06M2101/32C01B2203/0277C01B2203/1082C01B2203/107C01B2203/1094C01B2203/1041C01B2203/1058C01B2203/1064C01B2203/1052B01D2256/22B01D2256/16B01D2259/4508Y02E60/36
Inventor 李仁宏闫晓庆吴碧灵祝晓辉
Owner ZHEJIANG SCI-TECH UNIV
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