Clothianidin Controlled-release Embedded Granules and Its Preparation and Application
A technology of clothianidin and granules, which is applied in the agricultural field and can solve the problems of no sustained-release performance and conventional granules that do not have sustained-release performance.
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Embodiment 1
[0026] Pour 8g of polycaprolactone polyol (melting point about 60°C) into a 25mL beaker, heat to a molten state, then add 4g of polyethylene glycol 4000, and heat on a heating magnetic stirrer until completely dissolved and transparent. After it is completely transparent, add 4g of clothianidin technical substance 97% into it and continue to heat and stir until clear and transparent, then add 4g of beeswax (melting point 62-67° C.) and continue to stir until translucent. Then cool, stirring continuously during the cooling process, after the temperature drops, pour it on the pre-prepared ziplock bag and spread it. After the cooling is complete, pulverize with a small universal pulverizer, collect powders smaller than 100 mesh, and obtain clothianidin controlled-release embedding granules.
[0027] After content detection, the drug loading capacity is 17.8%, and the embedding rate is 92%. The release simulation experiment was carried out in the medium (2.5% methanol pH7.0 buffe...
Embodiment 2
[0029] Example 2: Preparation of 19.4% Clothianidin Controlled-release Embedded Granules
[0030] Pour 7g of polycaprolactone polyol (melting point about 60°C) into a 25mL beaker, heat to a molten state, then add 4g of polyethylene glycol 4000, and heat on a heating magnetic stirrer until completely dissolved and transparent. After it is completely transparent, add 4g of clothianidin technical substance 97% to it and continue to heat and stir until it is clear and transparent, then add 5g of beeswax and continue to stir until it is translucent. Then cool, stirring continuously during the cooling process, after the temperature drops, pour it on the pre-prepared ziplock bag and spread it. After the cooling is complete, use a small universal pulverizer to pulverize and collect powder less than 100 mesh. Clothianidin controlled-release embedded granules were obtained.
[0031] After content detection, the drug loading capacity was 19.4%, and the embedding rate was 100%. The rel...
Embodiment 3
[0032] Example 3: Preparation of 17.9% Clothianidin Controlled Release Embedded Granules
[0033] Pour 4g of polyethylene glycol 4000 into a 25mL beaker, heat to a molten state, then add 12g of carnauba wax (melting point 80-86°C), and heat on a heating magnetic stirrer until completely dissolved and transparent. After being completely transparent, 4 g of clothianidin 97% technical substance was added therein and continued heating and stirring until clear and transparent. Then cool, stirring continuously during the cooling process, after the temperature drops, pour it on the pre-prepared ziplock bag and spread it. After the cooling is complete, use a small universal pulverizer to pulverize and collect powder less than 100 mesh. Clothianidin controlled-release embedded granules were obtained.
[0034] After content detection, the drug loading capacity was 17.9%, and the embedding rate was 92.3%. The release simulation experiment was carried out in the medium (2.5% methanol p...
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