A kind of degradable slow-release multifunctional agricultural film and its preparation method
An agricultural film and multi-functional technology, applied in the field of degradable slow-release multi-functional agricultural film and its preparation, to achieve the effects of performance improvement, excellent slow release, and reduced usage
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Embodiment 1
[0024] A kind of degradable slow-release multifunctional agricultural film, its preparation method comprises the following steps:
[0025] (1), take by weighing 100 parts of agricultural straw (wheat straw), 27 parts of hydrofluoric acid (mass concentration is 40%), 33 parts of oxalic acid (anhydrous), 0.4 part of ferric fluoride, 85 parts of water, 28 parts of hydrochloric acid ( The mass concentration is 30%), 3 parts of dilute nitric acid (mass concentration is 8%), and 21 parts of ethanol are added in the reactor, the stirring speed is 105r / min, and the reaction is 0.6h under the condition of maintaining the system temperature at 93°C. After 1mol / L Sodium hydroxide solution is neutralized to pH to 7.0, centrifuged in 10000r / min centrifuge for 10min, sediment is washed 3 times through 500mL (each washing consumption, other examples have the same meaning) water, 500mL (each washing consumption, other The meaning of the embodiment is the same) washing with ethanol for 3 times...
Embodiment 2
[0030] A kind of degradable slow-release multifunctional agricultural film, its preparation method comprises the following steps:
[0031](1), weigh 100 parts of agricultural straw (wheat straw), 19 parts of hydrofluoric acid (mass concentration is 40%), 26 parts of oxalic acid, 0.1 part of ferric fluoride, 79 parts of water, 20 parts of 30% (wt.% ) of hydrochloric acid, 1 part of dilute nitric acid (mass concentration is 8%), and 15 parts of ethanol are added in the reactor, and the stirring speed is 90r / min, and the reaction is 0.5h under the condition of maintaining the system temperature at 85°C, and after 1mol / L sodium hydroxide solution Neutralize until the pH reaches 7.0, centrifuge in a centrifuge at 10000r / min for 10min, wash the sediment three times with 500mL of water and three times with 500mL of ethanol, and dry it in vacuum at 65°C and -0.08MPa for 1h to obtain nanocellulose;
[0032] (2), Weigh 100 parts of Abutilon, 18 parts of water, 9 parts of ethanol, 3 part...
Embodiment 3
[0036] A kind of degradable slow-release multifunctional agricultural film, its preparation method comprises the following steps:
[0037] (1), weigh 100 parts of agricultural straw (wheat straw), 38 parts of hydrofluoric acid (mass concentration is 40%), 40 parts of oxalic acid, 0.9 part of ferric fluoride, 115 parts of water, 33 parts of 30% (wt.% ) hydrochloric acid, 9 parts of dilute nitric acid (mass concentration is 8%), and 32 parts of ethanol are added in the reactor, and the stirring speed is 130r / min, and the temperature of the system is maintained at 100°C for 2 hours. and until the pH reaches 7.0, centrifuge in a centrifuge at 10000r / min for 10min, wash the sediment three times with 500mL of water and three times with 500mL of ethanol, and dry it in vacuum at 65°C and -0.08MPa for 1h to obtain nanocellulose;
[0038] (2), Weigh 100 parts of Abutilon, 29 parts of water, 14 parts of ethanol, 9 parts of ethylene glycol, and 16 parts of betaine and add them to the free...
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