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Special plating aid for aluminum-containing zinc plating solution

A technology of fluxing agent and galvanizing solution, which is applied in hot dip plating process, coating, metal material coating process, etc. The effect of generating, improving current efficiency, and excellent film-forming properties

Active Publication Date: 2017-11-03
平湖瑞星金属工艺有限公司
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0004] The technical problem to be solved by the present invention is: in the process of hot-dip plating, the traditional plating flux and the aluminum in the aluminum-containing galvanizing solution generate aluminum chloride which is easy to sublimate at a relatively low temperature, resulting in a large amount of harmful smog being produced on the production site. Problems that affect workers' operation and the surrounding environment provide a special flux for aluminum-containing galvanizing baths

Method used

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Examples

Experimental program
Comparison scheme
Effect test

example 1

[0022]First weigh 500g of plant ash, pour it into a beaker filled with 1000mL of hydrochloric acid with a mass fraction of 10%, then move the beaker into a digital speed measuring constant temperature magnetic stirrer, and stir and mix at a constant temperature at a temperature of 85°C and a speed of 500r / min. 40min, then filter the material in the beaker to obtain the filtrate, and transfer the obtained filtrate to a rotary evaporator, and at a temperature of 85°C and a pressure of 0.08MPa, condense by rotary evaporation for 45min to obtain a concentrated solution; transfer the obtained concentrated solution to In the refrigerator, refrigerate at a temperature of 4°C for 5 hours, then filter the refrigerated concentrated solution to obtain a filter residue, and transfer the obtained filter residue to an oven, and dry at a temperature of 110°C to constant weight to obtain plant ash extract filter residue; then weigh 300g of polyester fibers with a diameter of 1.4mm, cut them in...

example 2

[0024] First weigh 300g of plant ash, pour it into a beaker filled with 800mL of hydrochloric acid with a mass fraction of 8%, then move the beaker into a digital speed measuring constant temperature magnetic stirrer, and stir and mix at a constant temperature at a temperature of 75°C and a speed of 300r / min. 20min, then filter the material in the beaker to obtain the filtrate, and transfer the obtained filtrate to a rotary evaporator, and at a temperature of 80°C and a pressure of 0.06MPa, condense by rotary evaporation for 30min to obtain a concentrated solution; transfer the obtained concentrated solution to In the refrigerator, refrigerate at a temperature of 2°C for 3 hours, then filter the refrigerated concentrate to obtain a filter residue, transfer the obtained filter residue to an oven, and dry at a temperature of 105°C to constant weight to obtain plant ash extract filter residue; then weigh 200g of polyester fibers with a diameter of 1.0mm, cut them into lengths of 2...

example 3

[0026] First weigh 400g of plant ash, pour it into a beaker filled with 900mL hydrochloric acid with a mass fraction of 9%, and then move the beaker into a digital speed measuring constant temperature magnetic stirrer, and stir and mix at a constant temperature at a temperature of 80°C and a speed of 400r / min. 30min, then filter the material in the beaker to obtain the filtrate, and transfer the obtained filtrate to a rotary evaporator, and at a temperature of 82°C and a pressure of 0.07MPa, condense by rotary evaporation for 35min to obtain a concentrated solution; transfer the obtained concentrated solution to In the refrigerator, refrigerate at a temperature of 3°C for 4 hours, then filter the refrigerated concentrate to obtain a filter residue, transfer the obtained filter residue to an oven, and dry at a temperature of 107°C to constant weight to obtain plant ash extract filter residue; then weigh 250g of polyester fibers with a diameter of 1.2mm, cut them into lengths of ...

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Abstract

The invention relates to a special plating aid for aluminum-containing zinc plating solution, and belongs to the technical field of steel material surface plating technology. At first, hydrochloric acid is used to dissolve acid-soluble components in plant ash, rotary evaporation and concentration are carried out on filtrate after filtering, and dried filter residue is obtained after cooling and crystallizing; then, polyester staple fibers are soaked with sodium hydroxide solution, the polyester staple fibers are soaked with self-made liquid culture medium to modify the fibers; next, citric acid is consumed by using yeast aerobic respiration to release complexing cerium ions; in the meantime, carbon dioxide generated by the aerobic respiration is dissolved in water, the concentration of carbonate ions around the fibers is made to increase, and the carbonate ions are combined with the cerium ions to generate precipitates. The polyester fiber is removed and cerium carbonate is decomposed to obtain calcined material through calcination. Finally, the calcined material is mixed with the self-made drying filter residue and the like. According to the special plating aid, the excellent film-forming performance of dopamine is matched with the self-made calcined material to improve the current efficiency of the electroplating solution in the using process, the generation of aluminum chloride can be inhibited, and the problem that harmful smog is easily generated in the using process is avoided.

Description

technical field [0001] The invention relates to a special plating flux for an aluminum-containing galvanizing solution, which belongs to the technical field of surface coating technology of iron and steel materials. Background technique [0002] Flux plating is the process of immersing the pickled steel parts in a zinc ammonium chloride flux with a certain composition to form a thin layer of zinc ammonium chloride salt film on the surface of the parts. The fluxing process cleans the surface of steel parts, removes the iron salts or oxides left on the surface of the parts after pickling and cleaning, and makes the steel parts have greater surface activity when they enter the zinc bath. Depositing a layer of salt film on the surface of steel parts can prevent the steel parts from rusting in the air during the period from the fluxing pool to the zinc pot. When the iron and steel parts that have been treated by the plating treatment are immersed in the zinc solution, the ammoni...

Claims

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Application Information

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IPC IPC(8): C23C2/02C23C2/06
CPCC23C2/02C23C2/06
Inventor 张晶薛洋许丽君
Owner 平湖瑞星金属工艺有限公司
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