A gel breaker for recoverable fracturing fluid in oil and gas wells and using method
A technology of fracturing fluid and gel breaker, which is applied in the direction of chemical instruments and methods, drilling compositions, etc., and can solve the problems of poor gel breaking effect of fracturing fluid, complex water quality of flowback fluid, and slow reaction speed, etc. Achieve the effects of improving incomplete gel breaking, controllable gel breaking time, and easy use
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Embodiment 1
[0024] This embodiment provides a gel breaker for recyclable fracturing fluid of oil and gas wells, including mixture A and mixture B, and the mass ratio of mixture A to mixture B is 1:0.01-1;
[0025] The mixture A includes the following components: by mass percentage, 0.01%-10.0% aluminum salt, 30%-80% iron salt, 0.5-5.0% carbonate, and the balance is solvent;
[0026] Said mixture B is any two or three of ammonium persulfate, glucoside bond-specific enzyme of guanidine, and hydrolase specific for starch glycoside bond. Both the guar gum glycoside bond-specific enzyme and the starch glycoside bond-specific hydrolase are existing products and are available on the market.
[0027] When the gel breaker is in use, it is added to the prepared fracturing fluid. The amount added to the fracturing fluid is 0.02% to 0.30% of the total volume of the fracturing fluid. The mixture A is added in the replacement stage , the mixture B is added from the pre-fluid stage to the sand-carrying...
Embodiment 2
[0031] On the basis of Example 1, this example provides a gel breaker for recoverable fracturing fluid of oil and gas wells, wherein the aluminum salt in the mixture A is one of aluminum trichloride and aluminum sulfate.
[0032] The iron salt is one or more of ferric sulfate, ferric chloride, ferrous sulfate, dicyclopentadienyl iron, and ferrous acetate.
[0033] The carbonate is one or more of sodium carbonate, calcium carbonate, and reservoir rock powder with a carbonate content greater than 0.2%.
[0034] The solvent is one or more of ether, methanol, hydrochloric acid, and water.
[0035] The ammonium persulfate capsules, the glucoside bond-specific enzymes of guar gum, and the specific hydrolase enzymes of starch glycoside bonds in the mixture B can also be their capsule coatings. Both the guar gum glycoside bond-specific enzyme capsule coating and the starch glycoside bond-specific hydrolase capsule coating are available on the market.
[0036] The mixture in the gel ...
Embodiment 3
[0039] This embodiment provides a gel breaker for recoverable fracturing fluid of oil and gas wells, which includes 1 part of mixture A and 0.3 part of mixture B in parts by mass;
[0040] Wherein, mixture A comprises the aluminum sulfate that mass percentage is 4%, the ferric chloride of 24%, the ferrous sulfate of 16%, 1% sodium carbonate, all the other are water;
[0041] Mixture B is composed of 50% guaridine glycoside-bond-specific enzyme and 50% ammonium persulfate by mass percentage; the guaridine glycoside-bond-specific enzyme was purchased from Su Kehan Bioengineering Co., Ltd.
[0042] At 80°C, add 0.2% of the above-mentioned breaker to the total volume of the fracturing fluid, add mixture A in the displacement stage, add mixture B in the pre-fluid stage to the sand-carrying fluid stage, and stir evenly to reduce the viscosity of the fracturing fluid. Make the viscosity of the fracturing fluid lower than 5mPa·s within 120 minutes.
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