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Method for preparing conductive wool fabric by using mercaptoacetic acid solution

A technology of thioglycolic acid and wool, which is applied in the field of preparation of functional fabrics, can solve the problems of difficult control, reduction of wool fiber skin affinity, long process, etc., and achieve the effect of reducing damage

Inactive Publication Date: 2017-12-08
SOUTHWEST UNIVERSITY
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

However, the adsorption method mainly uses the intermolecular van der Waals force and ionic bond force to make the nanoparticles adsorb to the surface of the wool fiber, and the washing fastness is low; the process of the sol-gel method and the layer-by-layer assembly method is long and difficult to control; The coating method is to use adhesives to bond nanoparticles to the surface of wool fibers, which reduces the skin affinity of wool fibers to the human body

Method used

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0013] (1) Preparation of solution: Add 30g of mercaptoacetic acid, 2g of lithium chloride and 3g of sodium lauryl sulfate into 100ml of water to form a mixed solution, adjust the pH value to 9-10 with sodium hydroxide, and then add Add 0.3g nano-graphite powder in, obtain the dissolving solution that is dispersed with nano-graphite powder under ultrasonic vibration;

[0014] (2) padding the woolen fabric in the solution solution obtained in step (1) several times, and the excess rate is 70%;

[0015] (3) Steam the wool fabric after padding at 120°C for 10 minutes;

[0016] (4) Soak the steamed wool fabric in an aqueous solution of polyvinyl alcohol (12% by mass) to solidify for 10 minutes, then wash and dry.

Embodiment 2

[0018] (1) Preparation of solution: Add 40g of mercaptoacetic acid, 2g of lithium chloride and 3g of sodium lauryl sulfate into 100ml of water to form a mixed solution, adjust the pH value to 9-10 with sodium hydroxide, and then add Add 0.6g nanometer carboxylated graphene in, obtain the dissolving solution that is dispersed with nanometer carboxylated graphene under ultrasonic vibration;

[0019] (2) padding the woolen fabric in the solution solution obtained in step (1) several times, and the excess rate is 100%;

[0020] (3) Steam the padded wool fabric at 120°C for 8 minutes;

[0021] (4) Soak the steamed wool fabric in an aqueous solution of polyvinyl alcohol (14% by mass) to solidify for 10 minutes, then wash and dry.

Embodiment 3

[0023] (1) Preparation of solution: Add 45g of mercaptoacetic acid, 3g of lithium chloride and 4g of sodium lauryl sulfate into 100ml of water to form a mixed solution, adjust the pH value to 9-10 with sodium hydroxide, and then add Add 0.8g of carbon nanotubes to the solution, and obtain a solution in which carbon nanotubes are dispersed under ultrasonic vibration;

[0024] (2) padding the woolen fabric in the solution obtained in step (1) several times, and the excess rate is 110%;

[0025] (3) Steam the padded wool fabric at 110°C for 25 minutes;

[0026] (4) Soak the steamed wool fabric in an aqueous solution of polyvinyl alcohol (18% by mass) to solidify for 10 minutes, then wash and dry.

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
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PUM

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Abstract

The present invention provides a method for preparing conductive wool fabric using thioglycolic acid solution, the method comprising the following steps: (1) Preparation of solution: adding thioglycolic acid, lithium chloride and sodium lauryl sulfate into water to form Mix the solution, adjust the pH value to 9-10 with sodium hydroxide, adjust the pH value to 9-10 with sodium hydroxide, then add conductive nano particles to the solution, and obtain a solution dispersed with conductive nano particles under ultrasonic vibration; ( 2) Padding the woolen fabric in the solution obtained in step (1) multiple times; (3) steaming the padded woolen fabric; (4) soaking the steamed woolen fabric in an aqueous solution of polyvinyl alcohol solidified in the middle, then washed and dried. The preparation technology is simple and easy, with low cost, little damage to the strength of the wool fabric, does not change the surface properties of the wool fiber, and the nano-conductive particles have good fastness on the wool fabric; no adhesive is used in the preparation process, and no Poison is harmless.

Description

technical field [0001] The invention relates to a method for preparing functional fabrics, in particular to a method for preparing conductive wool fabrics using thioglycolic acid solution. Background technique [0002] Functional fiber materials can be prepared by introducing nanoparticles into textile fibers. At present, there are many preparation methods for introducing nanoparticles into wool fibers, such as: adsorption method, sol-gel method, layer-by-layer assembly method, coating method and so on. However, the adsorption method mainly uses the intermolecular van der Waals force and ionic bond force to make the nanoparticles adsorb to the surface of the wool fiber, and the washing fastness is low; the process of the sol-gel method and the layer-by-layer assembly method is long and difficult to control; The coating method is to use adhesives to bond nanoparticles to the surface of wool fibers, which reduces the skin affinity of wool fibers to the human body. [0003] T...

Claims

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): D06M13/252D06M11/13D06M13/262D06M11/74D06M15/333D06M10/08D06M10/06D06M101/12
CPCD06M13/252D06M10/06D06M10/08D06M11/13D06M11/74D06M13/262D06M15/333D06M2101/12
Inventor 卢明刘一萍
Owner SOUTHWEST UNIVERSITY
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