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TiO2 giant electrorheological fluid and application thereof

A giant electrorheological fluid and solution technology, applied in the petroleum industry, lubricating compositions, etc., can solve the problems of difficult practical industrial application, narrow operating temperature range, complicated preparation process, etc., and achieves low leakage current, low leakage current density, Simple preparation process

Active Publication Date: 2017-12-15
SUN YAT SEN UNIV
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0004] The purpose of the present invention is to overcome TiO in the prior art 2 Electrorheological fluid preparation process is complicated, the operating temperature range is narrow, the durability is weak, and the actual industrial application is difficult, providing a TiO 2 giant electrorheological fluid

Method used

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  • TiO2 giant electrorheological fluid and application thereof
  • TiO2 giant electrorheological fluid and application thereof
  • TiO2 giant electrorheological fluid and application thereof

Examples

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Embodiment 1~2

[0025] Example 1~2 TiO 2 giant electrorheological fluid

[0026] The TiO that present embodiment 1 provides 2 Giant electrorheological fluid was obtained by the following preparation method: 6 mL of deionized water was dissolved in 200 mL of absolute ethanol, and it was fully mixed under the action of a magnetic stirrer to prepare A solution; 30 mL of butyl titanate was dissolved in 300 mL of In water and ethanol, make it fully mixed under the action of a magnetic stirrer to prepare B solution; slowly drop B solution into A solution in a stirring state with a dropping funnel, fully react, and then centrifuge the generated white product, Repeated washing with deionized water and absolute ethanol, all the above operations were carried out at room temperature, and finally air-dried at 70°C for 2 hours to obtain TiO 2 particles; the TiO 2 The particles were heat-treated at 200°C for 2h to obtain a powder sample. TiO 2 Mix the powder and silicone oil in proportion to obtain Ti...

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Abstract

The invention relates to a TiO2 giant electrorheological fluid and application thereof. The preparation method of the TiO2 giant electrorheological fluid comprises the steps of: S1: mixing deionized water and anhydrous ethanol in a volume ratio of 3:100, and performing stirring to obtain a solution A, mixing butyl titanate and anhydrous ethanol in a volume ratio of 10:100, and performing stirring to obtain a solution B; S2: adding the solution B into the solution A under stirring, carrying out full reaction, and then conducitng centrifugation, washing and drying to obtain TiO2 particles, wherein the deionized water and butyl titanate are in a volume ratio of 1:5; S3: subjecting the TiO2 particles obtained by S2 to heat treatment at 120-200DEG C for 2h; and S4: mixing the TiO2 particles obtained in S3 with silicone oil to obtain TiO2 giant electrorheological fluid, which has a TiO2 particle solid content of not less than 1.0g / mL. The TiO2 giant electrorheological fluid provided by the invention has the advantages of simple preparation process, high electrorheological efficiency and small leakage current density, and can be used in a wide temperature range. Under optimal conditions, the electrorheological efficiency is up to 2000 times and the leakage current density is less than 20microA / cm<2>, therefore the TiO2 giant electrorheological fluid is suitable for industrial application.

Description

technical field [0001] The invention belongs to the field of new intelligent materials, more specifically, relates to a TiO 2 Giant electrorheological fluid and its application. Background technique [0002] metal oxide TiO 2 With a high dielectric constant, it is a typical electrorheological fluid raw material with great research and development potential. But pure TiO 2 The yield strength of electrorheological fluid is very small, which cannot meet the requirements of industrialization. People focus on its modification. Common modification methods include doping, polar molecule coating, and changing specific surface area. These modification methods have achieved good results, so that the yield strength can reach more than 100kPa at a lower electric field strength, and the leakage current is also controlled within a reasonable range, but the preparation of TiO by modification 2 The preparation process of electrorheological fluid is complicated, and there are many experi...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C10M169/04C10M171/00C10M177/00C10N40/16
CPCC10M169/04C10M171/001C10M177/00C10M2201/062C10M2229/0405C10N2040/16
Inventor 熊小敏邱昭辉
Owner SUN YAT SEN UNIV
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