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Glue liquid used for aluminum base board of high-heat-conductive copper-clad board and preparation method of same

A technology for copper clad laminates and aluminum substrates, which is applied in the field of glue and preparation of high thermal conductivity copper clad laminate aluminum substrates, can solve the problems of poor processing performance, potential safety hazards, unstable thermal conductivity, etc., and achieves increased heat resistance and thermal stability. Effects of thermal conductivity, increased crosslinking density, and increased heat resistance temperature

Inactive Publication Date: 2017-12-22
NANTONG RODA ELECTRON
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

Due to the different process formulas and production conditions of the heat conduction plates currently on the market, the quality of heat conduction copper clad laminates is uneven, which affects some customers' trust in this type of product to a certain extent, and thus has a negative impact on the development of this type of product. It has a certain degree of negative impact, which is mainly reflected in the following aspects: 1. The formula of the product is unreasonable, resulting in a short shelf life and poor processing performance in the later stage; Stable; 3. Unreasonable selection of fillers leads to unstable thermal conductivity and potential safety hazards

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0011] A glue solution for high thermal conductivity copper-clad aluminum substrates, including the following raw materials: low-bromine A80 epoxy resin (Br content 18%) 70±2Kg, zinc oxide modified bisphenol A epoxy resin 30±2 Kg, DICY (dicyandiamide) 1.5±0.01Kg, DDS (4,4 diaminodiphenylsulfone) 11±0.01Kg, 2MI (2-methylimidazole) 0.2±0.001Kg, DMF (dimethylformamide) 75±1Kg, coupling agent 5.4±0.01Kg, high-purity alumina (4um) 245±1Kg, high-purity alumina (1um) 105±1Kg.

[0012] The preparation method of the above-mentioned glue solution for high thermal conductivity type copper clad laminate aluminum substrate includes the following steps: (1) mix the curing agent DICY, 4,4 diaminodiphenyl sulfone and the curing accelerator 2MI evenly and put them into the glue mixing tank, Then add the solvent into it, and keep stirring for 2 hours to make it completely dissolve; (2) Add the formula amount of coupling agent in three times in the glue mixing tank, stir for 20 minutes after eac...

Embodiment 2

[0017] A glue solution for high thermal conductivity copper-clad aluminum substrates, including the following raw materials: low-bromine A80 epoxy resin (Br content 18%) 70±2Kg, zinc oxide modified bisphenol A epoxy resin 30±2 Kg, DICY (dicyandiamide) 1.5±0.01Kg, DDS (4,4 diaminodiphenylsulfone) 11±0.01Kg, 2MI (2-methylimidazole) 0.2±0.001Kg, DMF (dimethylformamide) 75±1Kg, coupling agent 5.4±0.01Kg, high-purity alumina (4um) 245±1Kg, high-purity alumina (1um) 75±1Kg, high-purity aluminum nitride (1um) 30±1Kg.

[0018] The preparation method is the same as in Example 1. It can be used to prepare flame-retardant products with high withstand voltage and high thermal conductivity.

[0019] The glue solution of the common formula and the glue solution of the formula of this embodiment were used to prepare the product respectively, and relevant data detection was carried out, and the results are shown in Table 2:

[0020] .

Embodiment 3

[0022] A glue solution for high thermal conductivity copper-clad aluminum substrates, including the following raw materials: phosphorus-containing halogen-free A80 epoxy resin (P content 3.5%) 70±2Kg, zinc oxide modified bisphenol A epoxy resin 30± 2 (Kg), DICY (dicyandiamide) 1.5±0.01Kg, DDS (4,4 diaminodiphenyl sulfone) 11±0.01Kg, 2MI (2-methylimidazole) 0.2±0.001Kg, DMF (dimethyl Formamide) 75±1Kg, coupling agent 5.4±0.01Kg, high-purity alumina (4um) 245±1Kg, high-purity alumina (1um) 105±1Kg.

[0023] The preparation method is the same as in Example 1. It can be used to prepare flame retardant, halogen-free, high withstand voltage and high thermal conductivity products.

[0024] The glue solution of the common formula and the glue solution of the formula of this embodiment were used to prepare the product respectively, and relevant data detection was carried out, and the results are shown in Table 3:

[0025] .

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PUM

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Abstract

The invention discloses a glue liquid used for an aluminum base board of a high-heat-conductive copper-clad board. The glue liquid includes, by weight, 100 + / - 2 parts of epoxy resin, 12.5 + / - 0.1 parts of an amine curing agent, 0.2 + / - 0.001 parts of a curing accelerator, 75 + / - 1 parts of a solvent, 5.4 + / - 0.1 parts of a coupling agent, and 350 + / - 2 parts of inorganic filler, wherein the epoxy resin includes 70 + / - 2 parts of phosphorus-containing halogen-free epoxy resin or bisphenol A type low-bromine epoxy resin and 30 + / - 2 parts of zinc oxide modified bisphenol A type epoxy resin. The preparation method includes the following steps: 1) uniformly mixing the amine curing agent and the curing accelerator, adding the mixture to the solvent, continuously stirring the liquid for 2 h to dissolve the mixture completely; 2) adding the coupling agent, in three times, into a glue blending tank, wherein when one batch of the coupling agent is added, the coupling is stirred for 20 min, and then the next batch is added; 3) after the coupling agent is completely added, adding all of the inorganic filler, and uniformly stirring the mixture for 30 min completely; and 4) adding the epoxy resin to the glue blending tank, and then high-speed-stirring the mixture for 4-6 h until the glue liquid is completely aged. The glue liquid has high heat resistance and heat conductivity.

Description

technical field [0001] The invention relates to a glue solution for a high thermal conductivity copper-clad aluminum substrate and a preparation method thereof. Background technique [0002] With the development of the economy, the quality of life of people in various countries has been significantly improved, and the safety requirements for various products are becoming more and more stringent. Under such conditions, high thermal conductivity copper-clad laminates and aluminum substrates have emerged in due course, and have gradually become the trend of market development. Due to the different process formulas and production conditions of the heat conduction plates currently on the market, the quality of heat conduction copper clad laminates is uneven, which affects some customers' trust in this type of product to a certain extent, and thus has a negative impact on the development of this type of product. It has a certain degree of negative impact, which is mainly reflecte...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C09J163/00C09J11/04C08G59/50
CPCC08G59/50C08G59/504C08K2003/2227C08K2003/2296C08K2003/282C08K2201/014C08L2201/08C08L2205/025C08L2312/00C09J11/04C09J163/00C08L63/00C08K13/02C08K3/22
Inventor 包晓剑奚辉顾鑫
Owner NANTONG RODA ELECTRON
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