Glue liquid used for aluminum base board of high-heat-conductive copper-clad board and preparation method of same
A technology for copper clad laminates and aluminum substrates, which is applied in the field of glue and preparation of high thermal conductivity copper clad laminate aluminum substrates, can solve the problems of poor processing performance, potential safety hazards, unstable thermal conductivity, etc., and achieves increased heat resistance and thermal stability. Effects of thermal conductivity, increased crosslinking density, and increased heat resistance temperature
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Embodiment 1
[0011] A glue solution for high thermal conductivity copper-clad aluminum substrates, including the following raw materials: low-bromine A80 epoxy resin (Br content 18%) 70±2Kg, zinc oxide modified bisphenol A epoxy resin 30±2 Kg, DICY (dicyandiamide) 1.5±0.01Kg, DDS (4,4 diaminodiphenylsulfone) 11±0.01Kg, 2MI (2-methylimidazole) 0.2±0.001Kg, DMF (dimethylformamide) 75±1Kg, coupling agent 5.4±0.01Kg, high-purity alumina (4um) 245±1Kg, high-purity alumina (1um) 105±1Kg.
[0012] The preparation method of the above-mentioned glue solution for high thermal conductivity type copper clad laminate aluminum substrate includes the following steps: (1) mix the curing agent DICY, 4,4 diaminodiphenyl sulfone and the curing accelerator 2MI evenly and put them into the glue mixing tank, Then add the solvent into it, and keep stirring for 2 hours to make it completely dissolve; (2) Add the formula amount of coupling agent in three times in the glue mixing tank, stir for 20 minutes after eac...
Embodiment 2
[0017] A glue solution for high thermal conductivity copper-clad aluminum substrates, including the following raw materials: low-bromine A80 epoxy resin (Br content 18%) 70±2Kg, zinc oxide modified bisphenol A epoxy resin 30±2 Kg, DICY (dicyandiamide) 1.5±0.01Kg, DDS (4,4 diaminodiphenylsulfone) 11±0.01Kg, 2MI (2-methylimidazole) 0.2±0.001Kg, DMF (dimethylformamide) 75±1Kg, coupling agent 5.4±0.01Kg, high-purity alumina (4um) 245±1Kg, high-purity alumina (1um) 75±1Kg, high-purity aluminum nitride (1um) 30±1Kg.
[0018] The preparation method is the same as in Example 1. It can be used to prepare flame-retardant products with high withstand voltage and high thermal conductivity.
[0019] The glue solution of the common formula and the glue solution of the formula of this embodiment were used to prepare the product respectively, and relevant data detection was carried out, and the results are shown in Table 2:
[0020] .
Embodiment 3
[0022] A glue solution for high thermal conductivity copper-clad aluminum substrates, including the following raw materials: phosphorus-containing halogen-free A80 epoxy resin (P content 3.5%) 70±2Kg, zinc oxide modified bisphenol A epoxy resin 30± 2 (Kg), DICY (dicyandiamide) 1.5±0.01Kg, DDS (4,4 diaminodiphenyl sulfone) 11±0.01Kg, 2MI (2-methylimidazole) 0.2±0.001Kg, DMF (dimethyl Formamide) 75±1Kg, coupling agent 5.4±0.01Kg, high-purity alumina (4um) 245±1Kg, high-purity alumina (1um) 105±1Kg.
[0023] The preparation method is the same as in Example 1. It can be used to prepare flame retardant, halogen-free, high withstand voltage and high thermal conductivity products.
[0024] The glue solution of the common formula and the glue solution of the formula of this embodiment were used to prepare the product respectively, and relevant data detection was carried out, and the results are shown in Table 3:
[0025] .
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