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Method for preparing 3D printing wax

A technology of 3D printing and production method, which is applied in wax physical treatment, petroleum wax refining, petroleum industry, etc., and can solve problems such as low product yield, production cycle, difficult separation, and product yield decline

Active Publication Date: 2017-12-26
CHINA PETROLEUM & CHEM CORP +1
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

When the ordinary sweating process produces soap wax and low melting point paraffin wax at 40°C to 60°C, the solid component (wax with a higher melting point) and the liquid component (wax with a lower melting point) in the sweating process are two types of components. They are in two phases of solid and liquid respectively, but it is difficult to completely separate them
In order to make the final product meet the requirements, the method of prolonging the sweating time and increasing the sweating termination temperature is usually adopted, but this will lead to a long production cycle and a decrease in product yield; tests have shown that when the ordinary sweating process produces wax products with a melting point above 70°C, sweating The width of carbon distribution on the wax and the content of n-alkanes in the later stage have nothing to do with the yield, that is, the width of carbon distribution on the wax does not decrease with the decrease of yield, and the content of n-alkanes does not increase with the decrease of yield, so the common sweating separation process does not Suitable for the production of wax products with a melting point of about 70°C
[0019] Compared with the solvent separation method, the sweating process is an intermittent operation, and the product yield is lower and the production cycle is longer. However, the sweating process has the advantages of less equipment investment, simple production process, low operating cost, safe production process, energy saving and no environmental impact. Pollution and other advantages, some manufacturers are still using this method to produce soap wax products
[0020] Over the years, the sweating method has been developed in terms of production equipment and technology, such as CN89214332 (vertical square multi-section sweating tank), CN94223980.6 (dish-type sweating device), CN98233254.8 (paraffin sweating tank), CN200920033500. X (new paraffin sweating tank), CN201210508905.0 (a high-efficiency paraffin sweating device), CN201320127680.4 (tubular paraffin deoiling device), etc., have made improvements in sweating production equipment; CN91206202 (a high-efficiency paraffin sweating tank ) have made improvements in the sweating process, but these methods still cannot produce wax products with a melting point of about 70°C

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0066] This embodiment includes three parts: (A): emulsification, (B): sweating and (C): preparation and silk extrusion.

[0067] (A): emulsification

[0068] This part includes (A1) oil phase material preparation, (A2) water phase material preparation, (A3) emulsion preparation three steps.

[0069] (A1) Oil phase material preparation

[0070] Take No. 64 paraffin wax (PetroChina Fushun Petrochemical Company, melting point 64.40°C, melting range 17.63°C) 80.0Kg, heat to 85°C and melt, add sorbitan monooleate 1.6Kg, diethylene glycol fatty acid ester 0.7Kg , polyoxyethylene fatty acid ester 0.7Kg, stir evenly.

[0071] (A2) Preparation of aqueous phase materials

[0072] 17.0 Kg of water was heated to 95°C.

[0073] (A3) Emulsion preparation

[0074] Stir the oil phase material prepared in (A1) at a speed of 600r / min, and slowly add the water phase material prepared in (A2) into the oil phase material, and continue stirring for 30min to form a water-in-oil emulsion.

[0...

Embodiment 2

[0092] This embodiment includes three parts: (A): emulsification, (B): sweating and (C): preparation and silk extrusion.

[0093] (A): emulsification

[0094] This part includes (A1) oil phase material preparation, (A2) water phase material preparation, (A3) emulsion preparation three steps.

[0095] (A1) Oil phase material preparation

[0096] Take 80.0Kg of No. 64 paraffin (same as Example 1), heat to 85°C and melt, add 2.0Kg of sorbitan monostearate, 0.6Kg of diethylene glycol monolaurate, and 0.4Kg of sodium alkylbenzenesulfonate Kg, stir evenly.

[0097] (A2) Preparation of aqueous phase materials

[0098] 2.0 Kg of KCl was dissolved in 15.0 Kg of water and heated to 95°C.

[0099] (A3) Emulsion preparation

[0100] Stir the oil phase material prepared in (A1) at a speed of 500r / min, and slowly add the water phase material prepared in (A2) into the oil phase material, and continue stirring for 20min to form a water-in-oil emulsion.

[0101] (B): sweating

[0102] W...

Embodiment 3

[0108] This embodiment includes three parts: (A): emulsification, (B): sweating and (C): preparation and silk extrusion.

[0109] (A): emulsification

[0110] This part includes (A1) oil phase material preparation, (A2) water phase material preparation, (A3) emulsion preparation three steps.

[0111] (A1) Oil phase material preparation

[0112] Take 80.0Kg of No. 64 paraffin (same as Example 1), heat to 85°C and melt, add 1.7Kg of sorbitan monooleate, 0.8Kg of tetraethylene glycol monostearate, and 0.5Kg of triacetamide oleate Kg, stir evenly.

[0113] (A2) Preparation of aqueous phase materials

[0114] 1.5Kg of NaCl was dissolved in 15.5Kg of water and heated to 95°C.

[0115] (A3) Emulsion preparation

[0116] Stir the oil phase material prepared in (A1) at a speed of 800r / min, and slowly add the water phase material prepared in (A2) into the oil phase material, and continue stirring for 15min to form a water-in-oil emulsion.

[0117] (B): sweating

[0118] With embo...

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Abstract

The invention discloses a method for preparing 3D printing wax. The method comprises emulsification, sweating and blending and utilizes appropriate paraffin as a raw material. Based on the ordinary sweating method, airflows pass through a wax layer and carry away a liquid component in the sweating process so that a solid component and the liquid component are forcibly separated and preferably, the sweating raw material and water or a salt solution are emulsified so that the liquid component can be fast discharged and thus the sweating method without solvent separation can produce a base material which has a melting point of about 70 DEG C and does not contain a low-melting point component. After blending of the base material, toughened resin, tackifying resin, animal wax and / or plant wax, an antioxidant and a pigment and extrusion filamentation, the 3D printing wax is obtained. The method has the advantages of low equipment investment, simple production process, low operation cost, safety, energy saving and no solvent pollution.

Description

technical field [0001] The invention belongs to the technical field of special wax production, and in particular relates to a production method of wax for 3D printing. Background technique [0002] Precision casting is a general term for precise casting processes obtained by precise molding methods, among which investment casting, also known as lost wax casting, is more commonly used. The products obtained by investment casting are precise and complex, close to the final shape of the parts, and can be used directly without or with little processing. It is an advanced technology near net shape and an excellent technology in the foundry industry. Its application very broad. It is not only suitable for casting of various types and alloys, but also produces castings with higher dimensional accuracy and surface quality than other casting methods, and even complex, high temperature resistant and difficult to process castings that are difficult to cast by other casting methods. C...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C10G73/42C10G73/40C10G73/38B29C47/00
CPCB29C48/05C10G73/38C10G73/40C10G73/42C10G2300/1085
Inventor 孙剑锋王鑫毕文卓张晓晖何凤友王诗语
Owner CHINA PETROLEUM & CHEM CORP
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