A wine residue-based composite material and a process for preparing wires for 3D printing using the composite material
A 3D printing, lees-based technology, used in additive processing and other directions, can solve the problems of severe global warming, reduce unpleasant odors, reduce costs, and promote conversion rates.
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Embodiment 1
[0041]A preparation method of wine residue-based composite material, comprising the following steps:
[0042] (1) Preparation of distiller's residue recycling raw materials:
[0043] Collect and clean the discarded wine lees after fermentation of Daqu Baijiu in the brewery. After cleaning, expose them to the sun for 10 hours, then dry them in an oven at 185°C for 4 hours, grind them, and sieve them to 105-75 microns (about 150-200 mesh).
[0044] (2) Preparation of wine residue-based composites
[0045] Put the prepared Daqu distiller's residue powder into the extruder with PHA and PBAT in different proportions of 20%, 40%, and 60%, respectively, and add in addition 1wt% compatibilizer (silane coupling agent), 1wt% lubricant (paraffin wax), and 0.4wt% antioxidant (triaryl phosphite), co-extruded with PHA, PBAT composition by twin-screw Blending by machine, the processing temperature is 145-165°C, after kneading processing and extrusion, it is granulated in a supercooled wat...
Embodiment 2
[0051] A preparation method of wine residue-based composite material, comprising the following steps:
[0052] (1) Preparation of distiller's residue recycling raw materials:
[0053] After collecting the discarded distiller's residue after fermentation of Xiaoqu Baijiu in the brewery, clean it, expose it to the sun for 12 hours, then dry it in an oven at 185°C for 4 hours, then crush it, grind it, and sieve it to 20 -25 microns (about 500-625 mesh).
[0054] (2) Preparation of wine residue-based composites
[0055] To investigate the strength of composite materials prepared by adding different proportions of distiller's residue powder, ABS was first dried in a dehumidification oven for 4 hours, and the temperature of the dehumidification oven was 90°C to make the moisture content less than 0.1%. Afterwards, the ABS plastic composition after drying is added in the extruder, and the prepared wine residue powder (20%, 40%, 60%) is mixed with the ABS after dehydration, and the ...
Embodiment 3
[0060] A method for preparing a high-strength biodegradable wine residue-based composite material, comprising the following steps:
[0061] (1) Preparation of distiller's residue raw material:
[0062] Collect the waste lees from the brewery after making Daqu Baijiu, clean them, expose them to the sun for 48 hours, then dry them in an oven at 195°C for 10 hours, then grind them and sieve them to 15- 25 microns (about 500-900 mesh).
[0063] (2) High-strength biodegradable wine residue-based composites
[0064] The PLA was dried in a dehumidification oven for 4 hours, the temperature of the dehumidification oven was 85°C, and the dew point temperature was -40°C. The prepared distiller's residue raw material is mixed with PLA after dehydration with different proportions of distiller's residue (10%, 20%, 40%, 60%), and an additional mass percentage of the substance (the total mass of PLA and distiller's residue) is added 1.5% by weight compatibilizer (glycidyl methacrylate), 3...
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