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Nanowire p-n heterojunction and preparation method thereof

A nanowire and heterojunction technology, applied in nanotechnology, nanotechnology, chemical instruments and methods, etc., can solve problems such as expensive equipment, difficulty in obtaining templates, and difficulty in preparing high-purity samples, achieving rapid preparation and overcoming difficulties in obtaining , Preparation of economical and efficient effect

Inactive Publication Date: 2018-01-23
JINAN UNIVERSITY
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  • Abstract
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Problems solved by technology

The main disadvantage of chemical vapor deposition is expensive equipment and high cost; the disadvantage of solid-phase reaction combination is that it needs ultra-high vacuum to avoid the volatilization of reactants; the disadvantage of pulsed laser deposition is that pulsed laser equipment is required, and it is difficult to prepare high-purity samples; template The steps of auxiliary synthesis are: evaporation of gold film on the side of alumina template, electrodeposition of organic polymer materials, electrodeposition of inorganic semiconductor materials, dissolution of alumina templates, the presence of templates is difficult to obtain, and the diameter, length and number of micropores are difficult to control , the disadvantage of complex process
In summary, the existing methods for preparing nanowire p-n heterojunctions have the problems of high production cost and complicated process flow.

Method used

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  • Nanowire p-n heterojunction and preparation method thereof
  • Nanowire p-n heterojunction and preparation method thereof
  • Nanowire p-n heterojunction and preparation method thereof

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preparation example Construction

[0026] The invention provides a method for preparing a nanowire p-n heterojunction, comprising the following steps:

[0027] Mixing p-type quantum dots with conductive polymers and benzene organic solvents to obtain a mixed solution doped with p-type quantum dots;

[0028] Mixing n-type quantum dots with conductive polymers and benzene organic solvents to obtain a mixed solution doped with n-type quantum dots;

[0029] Pulling the mixed solution doped with p-type quantum dots to obtain p-type nanowires;

[0030] Pulling the mixed solution doped with n-type quantum dots to obtain n-type nanowires;

[0031] Under an optical microscope, the p-type nanowire and the n-type nanowire are micro-manipulated to obtain a cross structure, which is a nanowire p-n heterojunction.

[0032] The invention mixes p-type quantum dots with conductive polymers and benzene organic solvents to obtain a mixed solution doped with p-type quantum dots. In the present invention, the p-type quantum dots...

Embodiment 1

[0052] Dissolve 880mg of polyaniline in 1mL of xylene solvent to form a homogeneous polyaniline xylene solution.

[0053] Add 450 μL of p-type / n-type CdSe-ZnS core-shell quantum dot xylene solution (concentration: 2 μmol / L) into 1 mL of prepared polyaniline xylene solution, stir at room temperature for 2 hours, and then sonicate for 40 minutes , to obtain a mixed solution doped with p or n type quantum dots.

[0054] Immerse the glass fiber optic cone (tip diameter 10 microns) in the mixed solution of p or n-type quantum dots for 1 second, and pull the glass fiber optic cone at 0.1m / s, so that the polyaniline between the light cone tip and the solution can be obtained. Nanowires (doped with quantum dots). With the rapid evaporation of the xylene solution, a quantum dot-doped polyaniline nanowire is pulled out to obtain p-type nanowires and n-type nanowires.

[0055] Under an optical microscope (magnification 50, numerical aperture 0.7), firstly fix a p-type nanowire, and the...

Embodiment 2

[0059] Dissolve 620mg of polyaniline in 0.7mL of xylene solvent to form a homogeneous polyaniline xylene solution.

[0060] Add 250 μL p-type / n-type CdSe-ZnS core-shell quantum dot xylene solution (concentration: 4 μmol / L) into 0.7 mL polyaniline xylene solution, stir at room temperature for 2 hours, and then sonicate for 40 Minutes, a mixed solution doped with p or n type quantum dots is obtained.

[0061] Immerse the glass fiber cone (30 microns in tip diameter) in the mixed solution of p or n-type quantum dots for 4 seconds, and pull the glass fiber cone at 3m / s, so that the polyaniline nanometer between the tip of the light cone and the solution can be obtained. wire (with quantum dots doped in it). With the rapid evaporation of the xylene solution, a quantum dot-doped polyaniline nanowire is pulled out to obtain p-type nanowires and n-type nanowires.

[0062] Under an optical microscope (magnification 50, numerical aperture 0.7), first fix an n-type nanowire, and then u...

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Abstract

The invention provides a preparation method of nanowire p-n heterojunction, and belongs to the field of heterojunction material preparation. A p type quantum dot or n type quantum dot is mixed with aconducting polymer and a benzene type organic solvent to obtain a p type or n type quantum dot doped mixed solution; the p type or n type quantum dot doped mixed solution is subjected to drawing to obtain a p type or n type nanowire; finally, under the optical microscope, the p type and the n type nanowire are subjected to micro operation to obtain a crossed structure, i.e., the nanowire p-n heterojunction is obtained. A direct drawing technology and a micro operation and control technology are combined for realizing fast preparation of the nanowire p-n heterojunction; the method does not needthe complicated technological process; the difficult problem that a template is difficult to obtain is solved, so that the preparation of the nanowire p-n heterojunction is economic and efficient.

Description

technical field [0001] The invention relates to the field of preparation of heterojunction materials, in particular to a nanowire p-n heterojunction and a preparation method thereof. Background technique [0002] Nanowire p-n heterojunctions have attracted extensive attention from researchers due to their excellent light emission, photoconductivity, photovoltaic and rectification properties. The excellent properties exhibited by nanowire p-n heterojunctions are not only the simple superposition of individual material properties, but also the synergistic contribution of the heterointerface formed between individual materials, which can produce the effect of one plus one greater than two. [0003] In the prior art, the preparation methods of nanowire p-n heterojunction mainly include: chemical vapor deposition, solid phase reaction combination, pulsed laser deposition and template-assisted synthesis. The main disadvantage of chemical vapor deposition is expensive equipment an...

Claims

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Application Information

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IPC IPC(8): C01B19/00C01G9/08B82Y30/00B82Y40/00
Inventor 李宝军杨先光张垚李宇超
Owner JINAN UNIVERSITY
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