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Method for rapidly pyrolyzing food and drink waste oil saponated substances

A technology of catering waste oil and saponification, which is applied in the preparation of liquid hydrocarbon mixtures, petroleum industry, biological raw materials, etc., can solve the problems of slow heating rate, small microwave absorption factor, low dielectric constant, etc., and achieve the improvement of biofuel quality, reduce side reactions, and promote the effect of tar decomposition

Active Publication Date: 2018-02-09
NANCHANG UNIV
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  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0004] It is worth noting that although MACFP technology can uniformly heat materials and promote the generation of hydrocarbons, there are still a series of outstanding problems in the heat transfer effect and catalyst of this technology, including: (1) In terms of heat transfer effect: waste oil and Catalysts have disadvantages such as low microwave absorption factor, low dielectric constant, and slow heating rate. At the same time, it is difficult to control the pyrolysis temperature and catalytic temperature separately in the traditional microwave pyrolysis process.
(2) Catalyst: At present, microwave-assisted catalytic fast pyrolysis technology is mostly in-situ catalysis, and the catalyst has defects such as easy passivation and deactivation, and difficult separation.

Method used

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  • Method for rapidly pyrolyzing food and drink waste oil saponated substances

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Experimental program
Comparison scheme
Effect test

Embodiment 1

[0024] Such as figure 1 As shown, the target pyrolysis temperature is set to 550 °C, the target catalytic temperature is 300 °C through the control system, the microwave power is adjusted to 6000 W, the feeding speed is 20 kg / h, and the stirring speed is 60 r / min. At the target temperature, the waste catering oil saponification is continuously added into the microwave reaction chamber through the screw feeder, and the stirrer is pulled up and down to stir, and the saponification of the waste catering oil is rapidly heated and pyrolyzed, and the resulting residue is discharged through the orifice into the residue storage. , the ash-proof partition is set under the orifice to prevent the residue from entering the gas outlet, and the pyrolysis steam enters the upper gas outlet of the slag storage through the high-temperature spherical silicon carbide bed under the negative pressure of the air pump, and then enters the catalyst filling tube for catalytic reforming , and finally th...

Embodiment 2

[0026] Such as figure 1 As shown, the target pyrolysis temperature is set to 650 °C, the target catalytic temperature is 250 °C through the control system, the microwave power is adjusted to 8000 W, the feed rate is 30 kg / h, and the stirring speed is 60 r / min. At the target temperature, the waste catering oil saponification is continuously added into the microwave reaction chamber through the screw feeder, and the stirrer is pulled up and down to stir, and the saponification of the waste catering oil is rapidly heated and pyrolyzed, and the resulting residue is discharged through the orifice into the residue storage. , the ash-proof partition is set under the orifice to prevent the residue from entering the gas outlet, and the pyrolysis steam enters the upper gas outlet of the slag storage through the high-temperature spherical silicon carbide bed under the negative pressure of the air pump, and then enters the catalyst filling tube for catalytic reforming , and finally throug...

Embodiment 3

[0028] Such as figure 1 As shown, the target pyrolysis temperature is set to 750 °C and the target catalytic temperature is 350 °C through the control system, the microwave power is adjusted to 6000 W, the feed rate is 20 kg / h, and the stirring speed is 60 r / min. At the target temperature, the waste catering oil saponification is continuously added into the microwave reaction chamber through the screw feeder, and the stirrer is pulled up and down to stir, and the saponification of the waste catering oil is rapidly heated and pyrolyzed, and the resulting residue is discharged through the orifice into the residue storage. , the ash-proof partition is set under the orifice to prevent the residue from entering the gas outlet, and the pyrolysis steam enters the upper gas outlet of the slag storage through the high-temperature spherical silicon carbide bed under the negative pressure of the air pump, and then enters the catalyst filling tube for catalytic reforming , and finally thr...

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Abstract

A method for rapidly pyrolyzing food and drink waste oil saponated substances is disclosed, and the method is as follows: controlling a down-draft rapid microwave pyrolysis reaction device to set target pyrolysis temperature to 500 to 750 DEG C and target catalytic temperature to 200 to 500 DEG C and adjust microwave power to 1000 to 9000 W, feeding speed to 5-50kg / h and stirring speed to 20-120r / min; when pyrolysis temperature and catalytic temperature reach the set target value, continuously adding the food and drink waste oil saponated substances into a microwave reaction cavity via a screw feeder, and stirring with a stirrer in an up-and-down lifting manner; discharging pyrolysis residue into a residue storage device; performing catalytic reforming on pyrolysis steam, collecting biological fuel oil with a liquid collector, and collecting biological fuel gas with a gas collector. The method has the advantages of being continuable in operation, suitable for industrialized production, short in reaction time and few in side reactions, effective catalytic reforming of the pyrolysis steam can be performed, and the quality of the biological fuel gas can be improved.

Description

technical field [0001] The invention relates to a method for rapid microwave pyrolysis conversion of waste catering oil saponification into high value-added fuel oil. Background technique [0002] With the rapid consumption of fossil fuels and the deterioration of the environment, the rapid pyrolysis of waste oils (mainly composed of triglycerides and free fatty acids) into high-quality hydrocarbon fuels has attracted more and more attention from relevant researchers. Triglycerides from vegetable oil sources are considered to be one of the best raw materials for converting renewable fuels. my country is rich in energy tree species. At the same time, the food industry and catering industry produce a large amount of waste oils every year, but the renewable oils obtained through thermal cracking and transesterification Fuels have high oxygen content, low calorific value, high viscosity, high acidity, strong corrosion, and poor stability. These shortcomings seriously restrict the...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C10G3/00
CPCC10G3/42C10G2300/1007Y02P30/20
Inventor 王允圃刘玉环戴磊磊段邓乐吴秋浩曾子鸿余桢婷姜林张淑梅
Owner NANCHANG UNIV