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Preparation method of fiber-aerogel composite material in composite core material for vacuum insulation board

A technology of vacuum insulation panels and composite materials, applied in heat exchange equipment, chemical characteristics of fibers, single-component synthetic polymer rayon, etc., can solve the problems of high brittle resistance, low thermal conductivity, etc. The effect of reducing thermal conductivity and density and improving thermal insulation performance

Inactive Publication Date: 2018-04-20
NINGBO XIAYUAN TECH
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0007] In order to solve the problems existing in vacuum insulation panels in the prior art, the invention discloses a composite core material for vacuum insulation panels with low thermal conductivity and high anti-brittleness ability and its preparation method

Method used

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  • Preparation method of fiber-aerogel composite material in composite core material for vacuum insulation board
  • Preparation method of fiber-aerogel composite material in composite core material for vacuum insulation board

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0030] A kind of composite core body material for vacuum insulation board, is made of nano Bi 2 Te 3 Modified melamine formal fiber, nanoporous zeolite modified polycarbonate foam insulation material and fiber-aerogel composite material are filled into a film bag with an opening on one side according to the weight ratio of 5:3:2. The film bag is sealed and placed in the mold of the molding machine, so that the filling material is evenly distributed in the film bag, and the filling material is pressurized and molded under a molding pressure of 50MPa, and finally the mold pressure is unloaded and demolded to obtain the formed core material.

[0031] Among them, the nano-Bi 2 Te 3 Modified melamine formal fiber is prepared by the following method:

[0032](1) Dissolve bismuth chloride, tellurium powder, potassium hydroxide, and sodium borohydride in N-N-dimethylformamide, and conduct a hydrothermal reaction at 110°C for 28 hours with the resulting solution, and cool naturally ...

Embodiment 2

[0043] A kind of composite core body material for vacuum insulation board, is made of nano Bi 2 Te 3 Modified melamine formal fiber, nanoporous zeolite modified polycarbonate foam insulation material and fiber-aerogel composite material are filled into a film bag with an opening on one side according to the weight ratio of 11:5:4. The film bag is sealed and placed in the mold of the molding machine, so that the filling material is evenly distributed in the film bag, and the filling material is pressurized and molded under a molding pressure of 52MPa, and finally the mold pressure is unloaded and demolded to obtain the formed core material.

[0044] Among them, the nano-Bi 2 Te 3 Modified melamine formal fiber is prepared by the following method:

[0045] (1) Dissolve bismuth chloride, tellurium powder, potassium hydroxide, and sodium borohydride in N-N-dimethylformamide, and conduct a hydrothermal reaction at 130°C for 26 hours with the resulting solution, and cool naturall...

Embodiment 3

[0056] A kind of composite core body material for vacuum insulation panel, is made of nano Bi 2 Te 3Modified melamine formal fiber, nanoporous zeolite modified polycarbonate foam insulation material and fiber-aerogel composite material are filled into a film bag with an opening on one side according to the weight ratio of 11:6:3. The film bag is sealed and placed in the mold of the forming machine, so that the filling material is evenly distributed in the film bag, and the filling material is pressurized and molded under the molding pressure of 48MPa, and finally the mold pressure is unloaded and demolded to obtain the formed core material.

[0057] Among them, the nano-Bi 2 Te 3 Modified melamine formal fiber is prepared by the following method:

[0058] (1) Dissolve bismuth chloride, tellurium powder, potassium hydroxide, and sodium borohydride in N-N-dimethylformamide, and conduct a hydrothermal reaction at 140° C. for 24 hours with the resulting solution, and cool natur...

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Abstract

The invention discloses a preparation method of a fiber-aerogel composite material in a composite core material for a vacuum insulation board. The composite core material is obtained by compounding nano Bi2Te3 modified melamine formaldehyde fiber, nano porous zeolite modified polycarbonate foaming heat insulation material and fiber-aerogel composite material according to a weight ratio of (10-12):(5-6):(2-4). According to the preparation method provided by the invention, an inorganic nano-particle modified organic fiber flexible heat insulation material is screened, and the brittleness resistance of the core material is improved; by effectively combining the heat insulation material with an inorganic-organic composite foaming material, the thermal conductivity and density of the core material are further reduced, and the composite core material is ensured to have better heat insulation performance.

Description

[0001] This application is a divisional application, the original patent number is: 201610290809.1, the application date is April 27, 2016, and the title of the invention is: a composite core material for vacuum insulation panels and its preparation method. technical field [0002] The invention relates to the field of vacuum insulation panels, in particular to a composite core material for vacuum insulation panels and a preparation method thereof, which are suitable for use as insulation materials for refrigerators and freezers. Background technique [0003] With the gradual enhancement of people's awareness of energy saving and emission reduction, new requirements have been put forward for the development and application of new energy, new technology and new materials. At present, in the insulation box of a refrigerator, in addition to foam insulation materials, vacuum insulation materials with high insulation performance are more and more widely used as insulation material...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C08L61/28C08L69/00C08K13/06C08K9/06C08K7/26C08K3/30C08K3/36C08J9/12C08G12/32F16L59/065
CPCC08G12/32C08J9/0061C08J9/0066C08J9/0071C08J9/008C08J9/009C08J9/0095C08J9/122C08J9/30C08J2203/06C08J2361/28C08J2369/00C08J2469/00C08K3/30C08K3/36C08K7/26C08K9/06C08K13/06C08K2201/011C08L61/28C08L2203/14C08L2205/035D01F1/10D01F6/94F16L59/065C08L69/00
Inventor 魏亮
Owner NINGBO XIAYUAN TECH