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Thermal conductive and insulating polyphenylene sulfide composite material and preparation method thereof

A technology of composite materials and polyphenylene sulfide, which is applied in the field of conductive insulating materials, can solve the problems of large thermal conductivity, poor mechanical properties, and low thermal conductivity, and achieve the effects of increased thermal conductivity, increased mechanical properties, and excellent mechanical properties

Inactive Publication Date: 2018-05-29
CHENGDU SHANSHUI TIANXIA TECH CO LTD
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0006] The purpose of the present invention is to overcome the defects of low thermal conductivity and poor mechanical properties of existing polyphenylene sulfide composite materials, and provide a thermally conductive and insulating polyphenylene sulfide composite material and its preparation method; And the organic-inorganic hybrid principle makes it have the advantages of large thermal conductivity and good mechanical properties, which promotes the application of thermally conductive insulating materials in electronic devices that require rapid heat dissipation

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0031] (1) Disperse 3 parts by weight of alumina, 5 parts by weight of basalt fiber, and 4 parts by weight of copper oxide in 10 parts by weight of ethanethiol to form a solution;

[0032] (2) Esterify and couple the solution obtained in step 1 with 3 parts by weight of carbolic acid and 2 parts by weight of a silane coupling agent at 120°C for 5 hours to obtain a mixture;

[0033] (3) Mix the mixture obtained in step 2 with 20 parts by weight of polyphenylene sulfide resin with a degree of polymerization of 200, 5 parts by weight of polyether ether ketone with a degree of polymerization of 40, and 2 parts by weight of a cross-linking agent, and then mix it at 255 The cross-linking reaction was carried out at a temperature of ℃ for 3 hours to obtain a thermally conductive and insulating polyphenylene sulfide composite material.

Embodiment 2

[0035] (1) Disperse 2 parts by weight of alumina, 3 parts by weight of basalt fiber, and 6 parts by weight of copper oxide in 5 parts by weight of ethanethiol to form a solution;

[0036] (2) Esterify and couple the solution obtained in step 1 with 2 parts by weight of carbolic acid and 1 part by weight of a coupling agent at a temperature of 150° C. for 2 hours to obtain a mixture;

[0037] (3) Mix the mixture obtained in step 2 with 15 parts by weight of polyphenylene sulfide resin with a degree of polymerization of 500, 10 parts by weight of polyether ether ketone with a degree of polymerization of 80, and 3 parts by weight of a cross-linking agent, and then mix them at 250 The crosslinking reaction was carried out at a temperature of ℃ for 1 hour to obtain a thermally conductive and insulating polyphenylene sulfide composite material.

Embodiment 3

[0039] (1) Disperse 2 parts by weight of alumina, 3 parts by weight of basalt fiber, and 5 parts by weight of copper oxide in 5 parts by weight of ethanethiol to form a solution;

[0040] (2) Esterifying and coupling the solution obtained in step 1 with 5 parts by weight of carbolic acid and 1 part by weight of a coupling agent to obtain a mixture;

[0041](3) Mix the mixture obtained in step 2 with 30 parts by weight of polyphenylene sulfide resin, 10 parts by weight of polyether ether ketone, and 1 part by weight of a crosslinking agent, and then carry out crosslinking reaction to obtain thermally conductive insulating polyphenylene sulfide composite material.

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PUM

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Abstract

The invention discloses a thermal conductive and insulating polyphenylene sulfide composite material and a preparation method thereof. The composite material is prepared from the following raw materials by weight: 30-60 parts of polyphenylene sulfide resin, 5-10 parts of ethanethiol, 10-25 parts of polyether-ether-ketone, 2-5 parts of carbolic acid, 2-5 parts of aluminum oxide, 3-6 parts of basaltfiber, 2-5 parts of copper oxide, 1-3 parts of a coupling agent, and 1-5 parts of a cross-linking agent. The composite material has the advantages of high thermal conductive constant and high mechanical properties, and promotes the application of polyphenylene sulfide composite material in electronic devices needing fast heat dissipation.

Description

technical field [0001] The invention relates to the field of conductive insulating materials, in particular to a thermally conductive and insulating polyphenylene sulfide composite material and a preparation method thereof. Background technique [0002] With the development of electronic technology, the miniaturization and intensification of products have become a trend. Especially in the fields of communications, microwave, aerospace, smart phones, etc., the operating frequency of the system is gradually increasing, and the processing capability of the chip is gradually increasing. How to improve the signal sensitivity, reliability and heat dissipation of the electronic system has become a hot spot. Electronic and electrical equipment will generate a lot of heat. If the heat cannot be discharged in time, it will inevitably cause damage to the components of electronic and electrical appliances and the equipment itself if it accumulates to a certain extent. Therefore, the ex...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C08L81/02C08L61/16C08K13/06C08K9/06C08K9/04C08K3/22C08K7/10C08J3/24
CPCC08L81/02C08J3/246C08J2381/02C08J2461/16C08L2203/20C08L2312/00C08L61/16C08K13/06C08K9/06C08K9/04C08K2003/2227C08K2003/2248C08K7/10
Inventor 王鸥
Owner CHENGDU SHANSHUI TIANXIA TECH CO LTD
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