Heat Insulation Material And Device Using Same
A technology of heat insulation and carbon materials, applied in heat exchange equipment, lighting and heating equipment, mechanical equipment, etc., can solve the problem of low thermal conductivity, achieve the effect of reducing heat transfer and preventing burning
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Embodiment
[0119] Hereinafter, this embodiment will be described based on examples. However, this embodiment is not limited to the following examples. All reactions were performed under atmospheric conditions.
[0120]
[0121] In addition, in the examples, the heat insulating material 108 in which the carbon material 114 was added and the heat insulating material 110 in which the carbon material 114 was not added were produced, and the following respective measurements were performed.
[0122]
[0123] In the thermal conductivity measurement, a heat flow meter HFM 436Lamda (manufactured by NETZCH) and a TIM tester (manufactured by AnalysysTech) were used.
[0124]
[0125] In addition, a UL94 vertical burning test was performed to evaluate the flame retardancy of the heat insulating material 108 and the heat insulating material 110 . UL refers to the safety standards for electrical equipment developed and approved by UNDERWRITERS LABORATORIES INC. of the United States. It can e...
Embodiment 2
[0158] In water glass aqueous solution (Tosoh Industry Co., Ltd.), add self-dispersing graphene oxide (Sigma-Aldrich, 4mg / ml in H 2 O) and water to prepare raw materials (SiO 2 Concentration 6%, graphene oxide GO concentration 0.5%). Except that the concentration of graphene oxide was increased to 0.5%, a sheet was produced under the same process conditions as in Example 1.
[0159] As a result, heat insulating material 108 having an average thickness of 0.88 mm and a thermal conductivity of 0.020 W / mK was obtained. The filling rate of the silica xerogel 115 at this time was 44.6% by weight. V0 in the UL94 vertical burning test. In addition, as a result of DSC measurement, the thermal decomposition temperature (exothermic peak) of the organic modification group was 550° C. or higher, which was shifted to the high temperature side by 190° C. or higher than when the carbon material 114 was not added. In the cone calorimetry test, in the 20-minute non-combustible material tes...
Embodiment 3
[0161] In aqueous solution of water glass (Tosoh Sangyo Co., Ltd.), add self-dispersing carbon black (Tokai carbon, Aqua black 16219.2wt% in H as carbon material 114 2 O) and water to prepare raw materials (SiO 2 Concentration 6%, carbon black CB concentration 0.1%). To 20.5 g of this dispersion, 3.6 parts by weight (0.74 g) of concentrated hydrochloric acid was added as an acid catalyst, followed by stirring to prepare a sol solution. Sheets were produced under the same process conditions as in Example 1 except that the carbon material was changed to carbon black.
[0162] As a result, heat insulating material 108 having an average thickness of 0.88 mm and a thermal conductivity of 0.019 W / mK was obtained. The filling rate of the silica xerogel 115 at this time was 45.9% by weight. V0 in the UL94 vertical burning test. In addition, as a result of DSC measurement, the thermal decomposition temperature (exothermic peak) of the organic modification group was 550° C. or highe...
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