Preparation method and application of thermosetting powder coating for outdoor coating
A thermosetting powder and coating technology, applied in powder coatings, polyester coatings, coatings, etc., can solve the problems of reduced service life and discounted use effects, and achieve the effects of improved performance, strong adhesion, and high impact strength
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Embodiment 1
[0023] (1) 40 parts of hydroxyl polyester resin, 8 parts of 1,2-propanediol, 3 parts of guanidine sulfamate, 2 parts of polyethylene glycol octylphenyl ether, 0.5 parts of tetrafluorowax, 3 parts of coloring material, two Add 1 part of aminodiphenyl sulfone and 1 part of benzoin to the planetary ball mill together, add zirconia grinding balls according to the ratio of ball to material ratio of 8:1, and then add ethylene glycol, the amount of ethylene glycol is the mass of the grinding balls 65% of the mixture was ball milled at a rate of 150 rpm for 4 hours, and after the ball milling was completed, it was placed in a drying oven at 120°C for 6 hours to obtain a dry mixed powder;
[0024] (2) Send the dry mixed powder obtained in step (1) into a twin-screw extruder, set the aspect ratio of the twin-screw extruder to 20:1, the speed to 350 rpm, and the temperature in the first zone to 90-100 ℃, the temperature in the second zone is 100~110℃, the temperature in the third zone is...
Embodiment 2
[0030] (1) 45 parts of hydroxyl polyester resin, 9 parts of 1,2-propanediol, 4 parts of guanidine sulfamate, 3 parts of polyethylene glycol octylphenyl ether, 1 part of tetrafluorowax, 4 parts of colorant, three 2 parts of boron fluoride complex and 2 parts of benzoin are jointly added to the planetary ball mill, zirconia grinding balls are added according to the ratio of ball to material ratio of 9:1, and then ethylene glycol is added. The amount of ethylene glycol is Grinding 70% of the ball mass, ball milling at a rate of 175 rpm for 5 hours, after the ball milling is completed, place it in a drying oven at 125°C for 7 hours to obtain a dry mixed powder;
[0031] (2) Send the dry mixed powder obtained in step (1) into a twin-screw extruder, set the aspect ratio of the twin-screw extruder to 20:1, the speed to 350 rpm, and the temperature in the first zone to 90-100 ℃, the temperature in the second zone is 100~110℃, the temperature in the third zone is 105~115℃, the temperat...
Embodiment 3
[0037](1) 50 parts of hydroxyl polyester resin, 10 parts of 1,2-propanediol, 5 parts of guanidine sulfamate, 4 parts of polyethylene glycol octylphenyl ether, 1.5 parts of tetrafluorowax, 5 parts of coloring material, two Add 3 parts of carboxylic acid dihydrazide and 3 parts of stearic acid into the planetary ball mill together, add zirconia grinding balls according to the ratio of ball to material ratio of 10:1, and then add ethylene glycol, the amount of ethylene glycol is grinding 75% of the mass of the ball was ball milled at a rate of 200 rpm for 6 hours, and after the ball milling was completed, it was placed in a drying oven at 130°C for 8 hours to obtain a dry mixed powder;
[0038] (2) Send the dry mixed powder obtained in step (1) into a twin-screw extruder, set the aspect ratio of the twin-screw extruder to 20:1, the speed to 350 rpm, and the temperature in the first zone to 90-100 ℃, the temperature in the second zone is 100~110℃, the temperature in the third zone...
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