Phosphomolybdic acid copper antiflaming smoke-suppression PVC (polyvinyl chloride) rigid foamed sheet and preparation method thereof

A technology of copper phosphomolybdate and foamed sheet is applied in the field of copper phosphomolybdate flame retardant and smoke-suppressing PVC rigid foam sheet and its preparation, which can solve the problems of the flame retardant performance of PVC material decreasing and the magnitude of decrease being large, etc. Achieve the effect of improving oxygen index, eliminating decomposition and simple production process

Inactive Publication Date: 2018-07-06
HUBEI UNIV OF TECH
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

Although rigid PVC itself has excellent flame retardant properties, foaming will cause a decrease in the flame retardant properties of PVC materials, and the lower the density, the greater the decrease, especially when it is forced to burn in the air, it will emit a lot of black smoke, while Black smoke is the deadliest factor in fires

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0021] Each component is weighed according to parts by weight, respectively 100 parts by weight of SG-7 resin, 3 parts by weight of calcium-zinc composite heat stabilizer, 0.3 parts by weight of polyethylene wax, 0.2 parts by weight of stearic acid, and 2 parts by weight of processing aid ACR , 1.2 parts by mass of sodium bicarbonate, 0.5 parts by mass of azodicarbonamide, 11 parts by mass of 1250 mesh calcium carbonate, and 4 parts by mass of copper phosphomolybdate.

Embodiment 2

[0023] Each component is weighed according to parts by weight, respectively, 100 parts by mass of SG-7 resin, 5 parts by mass of calcium-zinc composite heat stabilizer, 0.4 parts by mass of polyethylene wax, 0.5 parts by mass of stearic acid, and 3 parts by mass of processing aid ACR , 1.6 parts by mass of sodium bicarbonate, 0.6 parts by mass of azodicarbonamide, 8 parts by mass of 1250 mesh calcium carbonate, and 5 parts by mass of copper phosphomolybdate.

Embodiment 3

[0025] Each component is weighed according to parts by weight, respectively, 100 parts by weight of SG-7 resin, 6 parts by weight of calcium-zinc composite heat stabilizer, 0.3 parts by weight of polyethylene wax, 0.5 parts by weight of stearic acid, and 2 parts by weight of processing aid ACR , 1.3 parts by mass of sodium bicarbonate, 0.4 parts by mass of azodicarbonamide, 25 parts by mass of 1250 mesh calcium carbonate, and 6 parts by mass of copper phosphomolybdate.

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Abstract

The invention belongs to the field of application of high polymer materials, and relates to a phosphomolybdic acid copper antiflaming smoke-suppression PVC (polyvinyl chloride) rigid foamed sheet anda preparation method thereof. The phosphomolybdic acid copper antiflaming smoke-suppression PVC rigid foamed sheet is prepared from the following ingredients in parts by weight: 100 parts by weight ofPVC resin powder, 3-6 parts by weight of stabilizer, 0.5-2 parts by weight of lubricating agent, 1-3 parts by weight of processing aid, 1-4 parts by weight of foaming agent, 8-25 parts by weight of filler and 3-6 parts by weight of antiflaming smoke-suppression agent. The phosphomolybdic acid copper antiflaming smoke-suppression PVC rigid foamed sheet takes phosphomolybdic acid and basic zinc carbonate as raw materials, the phosphomolybdic acid copper prepared under a water bath condition is adopted as the antiflaming smoke-suppression agent and is combined with other auxiliary agents, the mixture is added into the production of the PVC rigid foamed sheet, a technology is simple, yield is high, and an antiflaming smoke-suppression effect is obvious.

Description

technical field [0001] The invention belongs to the application field of polymer materials, and relates to a copper phosphomolybdate flame-retardant and smoke-suppressing PVC rigid foam board and a preparation method thereof. Background technique [0002] The main chemical composition of PVC foam board is polyvinyl chloride (Polyvinyl chloride), so it is also called foamed polyvinyl chloride board. It is widely used in various fields such as industry, agriculture, transportation, construction, communication, medical care and health, such as industrial spare parts, tarpaulins, water pipes, plastic doors and windows, cable protective sleeves, medical products, etc. Although rigid PVC itself has excellent flame retardant properties, foaming will cause a decrease in the flame retardant properties of PVC materials, and the lower the density, the greater the decrease, especially when it is forced to burn in the air, it will emit a lot of black smoke, while Black smoke is the dead...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C08L27/06C08L23/06C08L33/04C08K5/098C08K3/26C08K5/09C08K3/32C08K13/02C08J9/08C08J9/10
CPCC08J9/08C08J9/103C08J2203/02C08J2203/04C08J2203/18C08J2327/06C08J2433/04C08K3/32C08K5/09C08K5/098C08K13/02C08K2003/265
Inventor 陈绪煌
Owner HUBEI UNIV OF TECH
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