Chitin nanofiber anti-microbial colloid glove and preparation method thereof
A technology of nanofibers and chitin, applied in gloves, clothing, applications, etc., can solve the problems of inability to apply disposable gloves, decline in antibacterial performance, and need for high heat, etc., to achieve retention of molecular structure and antibacterial performance, low cost, and expansion The effect of application range
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Embodiment 1
[0028] Step S1. Preparation of chitin nanofiber dispersion: 100 parts of purified and modified chitin nanofibers, NNO (dispersant, chemical name is sodium methylene naphthalene sulfonate, methylene naphthalene sulfonate) Sodium, with excellent diffusibility and protective colloid properties) 3 parts and 2,900 parts of water are uniformly mixed to prepare a chitin nanofiber dispersion;
[0029] Step S2. Preparation of chitin nanofiber impregnated mortar: 8 parts of chitin nanofiber dispersion prepared in step S1, 100 parts of pre-vulcanized nitrile latex, 1.5 parts of casein (natural polymer thickened Agent) mixed and homogenized to prepare chitin nanofiber impregnated mortar with a viscosity of 1600mpa.s;
[0030] S3. The chemical fiber knitted glove embryo at a temperature of 55°C is first immersed in 2.5% by mass of calcium nitrate methanol solution coagulant, and after the immersion coagulant is treated, the glove is taken out; then it is immersed in the chitin nanofiber dipping...
Embodiment 2
[0034] Step S1: Preparation of chitin nanofiber dispersion: 120 parts of purified and modified chitin nanofibers, 5 parts of sodium dibutyl naphthalene sulfonate, and 3900 parts of water are uniformly mixed according to mass parts to prepare chitin nanofiber dispersion liquid;
[0035] Step S2: Preparation of chitin nanofiber impregnated mortar: 20 parts of chitin nanofiber dispersion prepared in step S1, 120 parts of pre-vulcanized neoprene latex, 5 parts of gelatin, 1 part of polyols (Such as polyethylene glycol, polypropylene glycol or trimethylolpropane), etc., are mixed and homogenized to prepare chitin nanofiber impregnated mortar;
[0036] S3. Directly immerse the cotton wool glove embryo at a temperature of 45°C into the chitin nanofiber impregnated mortar prepared in step S2 and take it out;
[0037] S4. The gloves processed in step S3 are vulcanized and dried at 60° C. for 45 minutes, and finally at a high-temperature vulcanization temperature of 115 to 120° C. for 90 minu...
Embodiment 3
[0039] Step S1: Preparation of chitin nanofiber dispersion: 90 parts of purified and modified chitin nanofibers, 1 part of NNO, and 800 parts of water are uniformly mixed according to mass parts to prepare a chitin nanofiber dispersion;
[0040] Step S2: Preparation of chitin nanofiber impregnated mortar: 5 parts of chitin nanofiber dispersion prepared in step S1, 90 parts of pre-vulcanized carboxyl styrene butadiene latex, 1 part of starch, 3 parts of aziridine The pyridine crosslinking agent is mixed and homogenized to prepare the chitin nanofiber impregnated mortar;
[0041] S3. The chemical fiber knitted glove embryo at a temperature of 50°C is first immersed in a 2.0% zinc chloride methanol solution coagulant, and then the glove is immersed in the coagulant, and then immersed in the chitin nanofiber impregnated mortar prepared in step S2. Take out
[0042] S4. The gloves treated in step S3 are made into the chitin nanofiber antibacterial rubber gloves at a high-temperature vulc...
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