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Chitin nanofiber anti-microbial colloid glove and preparation method thereof

A technology of nanofibers and chitin, applied in gloves, clothing, applications, etc., can solve the problems of inability to apply disposable gloves, decline in antibacterial performance, and need for high heat, etc., to achieve retention of molecular structure and antibacterial performance, low cost, and expansion The effect of application range

Inactive Publication Date: 2018-07-20
SHANDONG XINGYU GLOVES
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

Among them, there are some reports on applying chitin to yarn fibers. The specific preparation process is to mix chitin and yarn fibers, make them into a molten state, and then spin them, and finally weave them into antibacterial clothes or gloves. This process can make antibacterial clothes or gloves, but the application range of this method is very narrow, especially it cannot be applied to disposable gloves
In addition, the melt spinning of chitin and yarn fibers will not only destroy the molecular structure of chitin nanofibers due to high temperature, resulting in a significant decline in its antibacterial properties, but also requires a lot of heat and consumes a lot of energy.

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0028] Step S1. Preparation of chitin nanofiber dispersion: 100 parts of purified and modified chitin nanofibers, NNO (dispersant, chemical name is sodium methylene naphthalene sulfonate, methylene naphthalene sulfonate) Sodium, with excellent diffusibility and protective colloid properties) 3 parts and 2,900 parts of water are uniformly mixed to prepare a chitin nanofiber dispersion;

[0029] Step S2. Preparation of chitin nanofiber impregnated mortar: 8 parts of chitin nanofiber dispersion prepared in step S1, 100 parts of pre-vulcanized nitrile latex, 1.5 parts of casein (natural polymer thickened Agent) mixed and homogenized to prepare chitin nanofiber impregnated mortar with a viscosity of 1600mpa.s;

[0030] S3. The chemical fiber knitted glove embryo at a temperature of 55°C is first immersed in 2.5% by mass of calcium nitrate methanol solution coagulant, and after the immersion coagulant is treated, the glove is taken out; then it is immersed in the chitin nanofiber dipping...

Embodiment 2

[0034] Step S1: Preparation of chitin nanofiber dispersion: 120 parts of purified and modified chitin nanofibers, 5 parts of sodium dibutyl naphthalene sulfonate, and 3900 parts of water are uniformly mixed according to mass parts to prepare chitin nanofiber dispersion liquid;

[0035] Step S2: Preparation of chitin nanofiber impregnated mortar: 20 parts of chitin nanofiber dispersion prepared in step S1, 120 parts of pre-vulcanized neoprene latex, 5 parts of gelatin, 1 part of polyols (Such as polyethylene glycol, polypropylene glycol or trimethylolpropane), etc., are mixed and homogenized to prepare chitin nanofiber impregnated mortar;

[0036] S3. Directly immerse the cotton wool glove embryo at a temperature of 45°C into the chitin nanofiber impregnated mortar prepared in step S2 and take it out;

[0037] S4. The gloves processed in step S3 are vulcanized and dried at 60° C. for 45 minutes, and finally at a high-temperature vulcanization temperature of 115 to 120° C. for 90 minu...

Embodiment 3

[0039] Step S1: Preparation of chitin nanofiber dispersion: 90 parts of purified and modified chitin nanofibers, 1 part of NNO, and 800 parts of water are uniformly mixed according to mass parts to prepare a chitin nanofiber dispersion;

[0040] Step S2: Preparation of chitin nanofiber impregnated mortar: 5 parts of chitin nanofiber dispersion prepared in step S1, 90 parts of pre-vulcanized carboxyl styrene butadiene latex, 1 part of starch, 3 parts of aziridine The pyridine crosslinking agent is mixed and homogenized to prepare the chitin nanofiber impregnated mortar;

[0041] S3. The chemical fiber knitted glove embryo at a temperature of 50°C is first immersed in a 2.0% zinc chloride methanol solution coagulant, and then the glove is immersed in the coagulant, and then immersed in the chitin nanofiber impregnated mortar prepared in step S2. Take out

[0042] S4. The gloves treated in step S3 are made into the chitin nanofiber antibacterial rubber gloves at a high-temperature vulc...

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Abstract

The invention relates to a preparation method of a chitin nanofiber anti-microbial colloid glove. The method comprises the following steps: S1, preparing chitin nanofiber dispersion liquid: mixing 90-120 parts of chitin nanofiber, 1-5 parts of a dispersant and 800-3900 parts of water in parts by mass to prepare the chitin nanofiber dispersion liquid; S2, preparing chitin nanofiber dipping adhesivecement: mixing and homogenizing 5-20 parts of the chitin nanofiber dispersion liquid prepared in step S1, 90-120 parts of latex, 0-3 parts of a cross-linking agent and 1-5 parts of a thickening agentin parts by mass to prepare the chitin nanofiber dipping adhesive cement; S3, dipping an unprocessed glove into the chitin nanofiber dipping adhesive cement prepared in step S2; and S4, vulcanizing and drying the glove, which is subjected to treatment in step S3, to obtain the chitin nanofiber anti-microbial colloid glove. According to the preparation method, the chitin nanofiber anti-microbial function can be further applied into disposable colloid anti-microbial gloves, not only does the method not damage the molecular structure of chitin, but also the application range of chitin fiber is extended. The invention further relates to a chitin nanofiber-containing colloid glove.

Description

Technical field [0001] The invention relates to a chitin nanofiber antibacterial rubber glove and a preparation method thereof. Background technique [0002] Chitin (C 8 H 13 O 5 N)n, also known as chitin and chitin, the English name is Chitin. Chitin is the only natural polymer material with its own positive charge in nature. It is a natural alkaline polysaccharide. The chemical structure of Chitin is very similar to that of cellulose. The difference lies in the C-2 hydroxyl group of each glucose unit. Is replaced with acetamido (—NHCOCH 2 ), get chitin. The annual output of chitin in nature can reach 10 tons. It is the second most abundant sugar after cellulose, and the resources are very rich. Chitin is widely used because of its sterilization and disinfection effects. Among them, there are some reports on the application of chitin to yarn fibers. The specific preparation process is to mix chitin and yarn fibers into a molten state, then spin it, and finally spin into antib...

Claims

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Application Information

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IPC IPC(8): C08L9/04C08L11/02C08L9/08C08L7/02C08L75/04C08L5/08C08L89/00C08L89/06C08L3/02C08L29/04A41D19/00
CPCA41D19/0055C08L7/02C08L9/04C08L9/08C08L11/02C08L75/04C08L2205/03C08L2205/16C08L5/08C08L89/00C08L89/06C08L3/02C08L29/04
Inventor 周星余孙永峰
Owner SHANDONG XINGYU GLOVES
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