Preparation method of high-performance nylon nanocomposite

A nano-composite material and high-performance technology, applied in the field of preparation of high-performance nylon nano-composite materials, can solve the problems of high cost of industrialized materials, high price of nano-modifier POSS, limited improvement of mechanical properties of nano-materials, etc.

A nano-composite material and high-performance technology, applied in the field of preparation of high-performance nylon nano-composite materials, can solve the problems of high cost of industrialized materials, high price of nano-modifier POSS, limited improvement of mechanical properties of nano-materials, etc.

CN108329686AActive Publication Date: 2018-07-27QINGDAO UNIV OF SCI & TECH

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  • Preparation method of high-performance nylon nanocomposite

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0036] A nylon composite material is prepared by drying nylon 6 and silica grafted polyamino acid nanoparticles at 80℃-90℃ for 8-10 hours; according to the weight ratio, 100 parts have been dried Nylon 6, 3 parts of silica grafted polyamino acid nanoparticles (NCA monomer and aminated SiO 2 -NH 2 The ratio is 0.5:1), 0.8 parts of antioxidant, 0.5 parts of processing aid ethylene bis-stearamide (EBS), fully stirred to obtain the compound, and the above-mentioned ingredients are passed through the extruder at 250-270℃ Next, the nano particles and nylon 6 are blended and granulated to obtain a high-performance nylon 6 nanocomposite material.

Embodiment 2

[0038] A nylon composite material is prepared by drying nylon 6 and silica grafted polyamino acid nanoparticles at 80℃-90℃ for 8-10 hours; according to the weight ratio, 100 parts have been dried Nylon 6, 3 parts of silica grafted polyamino acid nanoparticles (NCA monomer and aminated SiO 2 -NH 2 The ratio is 1:1), 0.8 parts of antioxidant, 0.5 parts of processing aid ethylene bisstearamide (EBS), fully stirred to obtain the compound, and the above-mentioned ingredients are passed through the extruder at 250-270℃ Next, the nano particles and nylon 6 are blended and granulated to obtain a high-performance nylon 6 nanocomposite material.

Embodiment 3

[0040] A nylon composite material is prepared by drying nylon 6 and silica grafted polyamino acid nanoparticles at 80℃-90℃ for 8-10 hours; according to the weight ratio, 100 parts have been dried Nylon 6, 3 parts of silica grafted polyamino acid nanoparticles (NCA monomer and aminated SiO 2 -NH 2 The ratio is 2:1), 0.8 parts of antioxidant, 0.5 parts of processing aid ethylene bis-stearamide (EBS), fully stirred to obtain the compound, and the above-mentioned ingredients are passed through the extruder at 250-270℃ Next, the nano particles and nylon 6 are blended and granulated to obtain a high-performance nylon 6 nanocomposite material.

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Abstract

The invention discloses a preparation method of a high-performance nylon nanocomposite. The method comprises the steps as follows: self-made nano SiO2 is used as filler, firstly, the nano SiO2 spheresurface is grafted with a polyamino acid molecular chain with chemical structure characteristics similar to nylon through macromolecular design, and the dual network structure function of a particle physical network and a grafting molecular chain and matrix molecular chain entanglement network is expected to be played, so that uniform dispersion of nanoparticles in a polymer matrix and the good interface interaction between the nanoparticles and the matrix material are realized. Then, macromolecular modified SiO2 is added to nylon for melt blending, and a novel high-performance nylon nanocomposite with wide application prospects is developed.

Description

Technical field [0001] The invention belongs to the technical field of polymer materials, and specifically relates to a method for preparing a high-performance nylon nano composite material. Background technique [0002] Nanomaterials are used in polymers, which can perfectly combine the rigidity, dimensional stability and thermal stability of inorganic substances with the toughness, processability and dielectric properties of polymers to obtain composite materials with excellent performance. Although nanomaterials can comprehensively improve the comprehensive properties of polymers, they can also give them unique physical and chemical properties. However, due to the small particle size and high surface energy of nanoparticles, they are easy to agglomerate to form secondary particles, resulting in poor dispersion of nanoparticles in polymers and unable to show the favored surface area effect, volume effect, and quantum size effect. Seriously affect its use effect. In actual pro...

Claims

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Application Information

Patent Timeline
27 Jul 2018
Publication
CN108329686A
IPC
C08L77/02; C08L87/00; C08G83/00
CPC
C08G83/001; C08L77/02; C08L2201/08; C08L87/00
Inventors
阚泽; 董文杰