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Carbon fiber reinforced thermoplastic composite material and preparation method thereof

A technology of reinforced thermoplastic and composite materials, applied in the field of new energy vehicle materials, can solve the problems of low impact resistance and damage resistance, high fracture toughness, elongation at fracture, poor thermal conductivity, etc., and achieve superior electrical properties and flame retardancy The effect of improving the mechanical properties of materials and improving thermal conductivity

Inactive Publication Date: 2018-07-31
ANHUI XUSHENG NEW CONCEPT MATERIAL CO LTD
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

Due to the shortcomings of thermosetting composite materials in the application process, such as poor heat resistance, low impact resistance and damage resistance, and high manufacturing cost, their application range is limited to a certain extent, and with the development of carbon fiber composite materials, Compared with thermosetting composite materials, carbon fiber composite materials have many advantages, such as: high fracture toughness and high elongation at break; no chemical reaction in the molding process, so the molding speed is fast and the molding cycle is short; prepregs can be stored indefinitely, And there are no special requirements for storage, etc., so carbon fiber thermoplastic composite materials have gradually replaced traditional thermosetting composite materials; especially with the vigorous development of new energy vehicles, carbon fiber thermoplastic composite materials are widely used in the field of new energy vehicles, but the existing carbon fiber thermoplastic composite materials The thermal conductivity of the material is poor. When using these materials to prepare products such as casings and engine covers, it is easy to damage the equipment due to poor heat dissipation performance. Moreover, many manufacturers clearly require that the flame retardant grade of carbon fiber thermoplastic composite materials must reach UL94V-0. Therefore, the current carbon fiber thermoplastic composites need to be further improved in the direction of thermal conductivity and flame retardancy.

Method used

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  • Carbon fiber reinforced thermoplastic composite material and preparation method thereof

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preparation example Construction

[0020] The preparation method of the above-mentioned carbon fiber reinforced thermoplastic composite material adopts the following steps:

[0021] 1) The raw material thermoplastic resin, carbon fiber and inorganic filler are fully dried by a dryer, and the drying time is 4-5 hours, so that the water content of the dried material is less than 0.02wt%.

[0022] 2) Chromium trioxide and boron nitride are mixed and reacted for subsequent use;

[0023] 3) Mixing the thermoplastic resin and the mixed boron nitride, and heating with a heater, the heating time is 1-1.5 hours, and the temperature is 250°C-280°C;

[0024] 4) mixing the thermoplastic resin mixed in step 3 with inorganic fillers, coupling agents, antioxidants, lubricants, and flame retardants in a mixer at high speed, and then adding the mixed materials into the twin-screw extruder hopper, The carbon fiber is added through the fiberizing port of the extruder, extruded and granulated, and the carbon fiber reinforced ther...

Embodiment 1

[0025] Embodiment 1: The thermoplastic resin 56.93, carbon fiber 30 and inorganic filler 8 are fully dried by a dryer, and the drying time is 4 hours, so that the water content of the dried material is less than 0.02wt%, and dichromium trioxide 0.07 and nitriding Boron 1 mixed reaction for standby; mix thermoplastic resin and mixed boron nitride, and heat through heater, heating time is 1 hour, temperature is 250°C; thermoplastic resin mixed in step 3 and inorganic filler 8 , coupling agent 0.5, antioxidant 0.5, lubricant 0.5, and flame retardant 2.5 are mixed at high speed in the mixer, stirred repeatedly for 3 times, each time for 30 minutes, and then the mixed material is added to the hopper of the twin-screw extruder , and carbon fiber 30 is added through the fiber port of the extruder, extruded and granulated, and the carbon fiber reinforced thermoplastic resin composite material is obtained. 180°C, 220°C, 230°C, 240°C, 250°C, 240°C, and the speed of the host is 240-600 r...

Embodiment 2

[0026] Embodiment 2: The thermoplastic resin 52.7, the carbon fiber 32 and the inorganic filler 8.5 are fully dried by a drier, and the drying time is 4 hours, so that the water content of the dried material is less than 0.02wt%, and dichromium trioxide 0.1 is mixed with nitriding Boron 1 mixing reaction for standby; mix thermoplastic resin and mixed boron nitride, and heat through a heater for 1-1.5 hours at a temperature of 260°C; mix thermoplastic resin mixed in step 3 with inorganic Filler 8.5, coupling agent 1.2, antioxidant 0.8, lubricant 1, and flame retardant 2.7 are mixed at high speed in the mixer, and stirred repeatedly for 3 times for 30 minutes each time, and then the mixed material is added to twin-screw extrusion The hopper of the extruder, and carbon fiber 32 is added through the fiber port of the extruder, extruded and granulated, and the carbon fiber reinforced thermoplastic resin composite material is obtained. The settings are 180°C, 220°C, 230°C, 240°C, 25...

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Abstract

The invention relates to the technical field of new energy automobile materials, and in particular relates to a carbon fiber reinforced composite material and a preparation method thereof. The carbonfiber reinforced composite material includes the following raw material components in parts by weight: 45-60 parts of thermoplastic resin, 30-50 parts of carbon fiber, 4.5-10 parts of an inorganic filler, 0.5-2 parts of a coupling agent, 0.5-1.5 parts of an antioxidant, 0.5-2 parts of a lubricant, 2-5 parts of a flame retardant and 1-3 parts of boron nitride, wherein 0.07-0.15 part of a catalyst is added to the boron nitride; the raw materials of the thermoplastic resin, the carbon fiber and the inorganic filler are fully dried by a dryer, chromium oxide and the boron nitride are mixed and reacted for standby use; the thermoplastic resin and the mixed boron nitride are mixed, and heated by a heater for 1 to 1.5 hours at the temperature of 250 DEG C-280 DEG C; the mixed thermoplastic resin,the inorganic filler, the coupling agent, the antioxidant, the lubricant, and the flame retardant are mixed at high speed in a mixer, then the mixed material is added to a hopper of a twin-screw extruder, and the carbon fiber is added through a fiber addition port of the extruder, and the carbon fiber reinforced composite material is obtained by extrusion pelletization.

Description

technical field [0001] The invention relates to the technical field of new energy automobile materials, in particular to a carbon fiber reinforced thermoplastic composite material and a preparation method thereof. Background technique [0002] In the past half century, advanced structural materials used in high-tech fields such as aerospace and new energy vehicles have been dominated by high-performance thermosetting composite materials. Due to the shortcomings of thermosetting composite materials in the application process, such as poor heat resistance, low impact resistance and damage resistance, and high manufacturing cost, their application range is limited to a certain extent, and with the development of carbon fiber composite materials, Compared with thermosetting composite materials, carbon fiber composite materials have many advantages, such as: high fracture toughness and high elongation at break; no chemical reaction in the molding process, so the molding speed is ...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C08L81/02C08L79/08C08L61/16C08K13/04C08K7/06C08K3/38C08K5/3492C08K3/22
CPCC08K3/22C08K3/38C08K5/34928C08K7/06C08K13/04C08K2003/2251C08K2003/385C08K2201/004C08L2201/02C08L2201/22C08L81/02
Inventor 蔡福泉
Owner ANHUI XUSHENG NEW CONCEPT MATERIAL CO LTD
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