Fabric fluoride-free waterproof agent and preparation method thereof
A fluorine-free water repellent and textile technology, applied in textiles and papermaking, improved hand-feeling fibers, fiber types, etc., can solve the problems of insufficient fluorine-based products, insufficient oil repellency and waterproof and washing resistance, and limit development and application and other problems, to achieve a good effect of water and oil repellency
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Embodiment 1
[0016] Embodiment 1: A fluorine-free waterproofing agent for textiles, which is composed of the following raw materials in parts by weight: 25 parts of n-butyl acrylate, 2 parts of fumed titanium dioxide, 12 parts of higher fatty alcohol acrylate, 2 parts of polyethylene wax, two parts 3 parts of sodium butylnaphthalene sulfonate, 4 parts of alkyl glyceryl ether sulfonate, 3 parts of polyether silicone oil, 2 parts of stearic acid, 0.7 part of zinc nitrate hexahydrate, 0.3 part of catalyst, 120 parts of water; the catalyst For n-butyllithium.
[0017] A kind of preparation method of described fluorine-free waterproofing agent for textiles, it comprises the following steps:
[0018] (1) Prepare raw materials according to the parts by weight;
[0019] (2) Put fumed titanium dioxide, zinc nitrate hexahydrate and polyether silicone oil in a container and stir for 75 minutes to obtain a homogeneous material;
[0020] (3) n-butyl acrylate, higher fatty alcohol acrylate, polyethyle...
Embodiment 2
[0023] Embodiment 2: A fluorine-free waterproofing agent for textiles, which consists of the following raw materials in parts by weight: 20 parts of n-butyl acrylate, 1 part of fumed titanium dioxide, 10 parts of higher fatty alcohol acrylate, 1 part of polyethylene wax, two 1 part of sodium butylnaphthalene sulfonate, 2 parts of alkyl glyceryl ether sulfonate, 2 parts of polyether silicone oil, 1.5 parts of stearic acid, 0.5 part of zinc nitrate hexahydrate, 0.2 part of catalyst n-butyllithium, and 100 parts of water.
[0024] A kind of preparation method of described fluorine-free waterproofing agent for textiles, it comprises the following steps:
[0025] (1) Prepare raw materials according to the parts by weight;
[0026] (2) Put gas-phase titanium dioxide, zinc nitrate hexahydrate and polyether silicone oil in a container and stir for 1 hour to obtain a homogeneous material;
[0027] (3) Mix n-butyl acrylate, higher fatty alcohol acrylate, polyethylene wax, sodium dibuty...
Embodiment 3
[0030] Embodiment 3: A fluorine-free waterproofing agent for textiles, which is composed of the following raw materials in parts by weight: 30 parts of n-butyl acrylate, 3 parts of fumed titanium dioxide, 15 parts of higher fatty alcohol acrylate, 3 parts of polyethylene wax, two 4 parts of sodium butylnaphthalene sulfonate, 5 parts of alkyl glyceryl ether sulfonate, 4 parts of polyether silicone oil, 3 parts of stearic acid, 1 part of zinc nitrate hexahydrate, 0.5 part of catalyst n-butyllithium, and 140 parts of water.
[0031] A kind of preparation method of described fluorine-free waterproofing agent for textiles, it comprises the following steps:
[0032] (1) Prepare raw materials according to the parts by weight;
[0033] (2) Put gas-phase titanium dioxide, zinc nitrate hexahydrate and polyether silicone oil in a container and stir for 1.5 hours to obtain a homogeneous material;
[0034] (3) Mix n-butyl acrylate, higher fatty alcohol acrylate, polyethylene wax, sodium d...
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