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Fabric fluoride-free waterproof agent and preparation method thereof

A fluorine-free water repellent and textile technology, applied in textiles and papermaking, improved hand-feeling fibers, fiber types, etc., can solve the problems of insufficient fluorine-based products, insufficient oil repellency and waterproof and washing resistance, and limit development and application and other problems, to achieve a good effect of water and oil repellency

Inactive Publication Date: 2018-08-31
佛山慧创正元新材料科技有限公司
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

With the further improvement of people's requirements for the safety of textiles and chemicals, environmentally friendly fluorine-free waterproofing agents will become more and more popular, but the disadvantages of the existing fluorine-free environmentally friendly waterproofing agents are oil-proof performance and waterproof and washing resistance. Insufficient, far from reaching the effect of fluorine-based products, thus limiting its development and application in the textile field to a certain extent

Method used

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  • Fabric fluoride-free waterproof agent and preparation method thereof

Examples

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Comparison scheme
Effect test

Embodiment 1

[0016] Embodiment 1: A fluorine-free waterproofing agent for textiles, which is composed of the following raw materials in parts by weight: 25 parts of n-butyl acrylate, 2 parts of fumed titanium dioxide, 12 parts of higher fatty alcohol acrylate, 2 parts of polyethylene wax, two parts 3 parts of sodium butylnaphthalene sulfonate, 4 parts of alkyl glyceryl ether sulfonate, 3 parts of polyether silicone oil, 2 parts of stearic acid, 0.7 part of zinc nitrate hexahydrate, 0.3 part of catalyst, 120 parts of water; the catalyst For n-butyllithium.

[0017] A kind of preparation method of described fluorine-free waterproofing agent for textiles, it comprises the following steps:

[0018] (1) Prepare raw materials according to the parts by weight;

[0019] (2) Put fumed titanium dioxide, zinc nitrate hexahydrate and polyether silicone oil in a container and stir for 75 minutes to obtain a homogeneous material;

[0020] (3) n-butyl acrylate, higher fatty alcohol acrylate, polyethyle...

Embodiment 2

[0023] Embodiment 2: A fluorine-free waterproofing agent for textiles, which consists of the following raw materials in parts by weight: 20 parts of n-butyl acrylate, 1 part of fumed titanium dioxide, 10 parts of higher fatty alcohol acrylate, 1 part of polyethylene wax, two 1 part of sodium butylnaphthalene sulfonate, 2 parts of alkyl glyceryl ether sulfonate, 2 parts of polyether silicone oil, 1.5 parts of stearic acid, 0.5 part of zinc nitrate hexahydrate, 0.2 part of catalyst n-butyllithium, and 100 parts of water.

[0024] A kind of preparation method of described fluorine-free waterproofing agent for textiles, it comprises the following steps:

[0025] (1) Prepare raw materials according to the parts by weight;

[0026] (2) Put gas-phase titanium dioxide, zinc nitrate hexahydrate and polyether silicone oil in a container and stir for 1 hour to obtain a homogeneous material;

[0027] (3) Mix n-butyl acrylate, higher fatty alcohol acrylate, polyethylene wax, sodium dibuty...

Embodiment 3

[0030] Embodiment 3: A fluorine-free waterproofing agent for textiles, which is composed of the following raw materials in parts by weight: 30 parts of n-butyl acrylate, 3 parts of fumed titanium dioxide, 15 parts of higher fatty alcohol acrylate, 3 parts of polyethylene wax, two 4 parts of sodium butylnaphthalene sulfonate, 5 parts of alkyl glyceryl ether sulfonate, 4 parts of polyether silicone oil, 3 parts of stearic acid, 1 part of zinc nitrate hexahydrate, 0.5 part of catalyst n-butyllithium, and 140 parts of water.

[0031] A kind of preparation method of described fluorine-free waterproofing agent for textiles, it comprises the following steps:

[0032] (1) Prepare raw materials according to the parts by weight;

[0033] (2) Put gas-phase titanium dioxide, zinc nitrate hexahydrate and polyether silicone oil in a container and stir for 1.5 hours to obtain a homogeneous material;

[0034] (3) Mix n-butyl acrylate, higher fatty alcohol acrylate, polyethylene wax, sodium d...

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Abstract

The invention discloses a fabric fluoride-free waterproof agent which consists of the following raw materials in parts by weight: 20-30 parts of n-butyl acrylate, 1-3 parts of gas-phase titanium dioxide, 10-15 parts of high-class higher aliphatic alcohol acrylate, 1-3 parts of polyethylene wax, 1-4 parts of naphthalene sulfonicacid dibutyl-sodium salt, 2-5 parts of alkyl glyceryl ether sulfonate,2-4 parts of polyether silicon oil, 1.5-3 parts of stearic acid, 0.5-1 part of zinc nitrate hexahydrate, 0.2-0.5 part of a catalyst and 100-140 parts of water. By adopting the fabric fluoride-free waterproof agent disclosed by the invention, the n-butyl acrylate and the high-class higher aliphatic alcohol acrylate are creatively reacted under the function of the catalyst, and are subjected to commixing reactions with the gas-phase titanium dioxide, the polyethylene wax, the naphthalene sulfonicacid dibutyl-sodium salt, the alkyl glyceryl ether sulfonate, the polyether silicon oil, the stearicacid and the zinc nitrate hexahydrate, then a good waterproof and anti-oil effect can be achieved, and meanwhile an environmental-friendly fluoride-free waterproof finishing agent which is good in washing resistance for fabrics can be prepared.

Description

technical field [0001] The invention relates to the field of textile processing materials and preparation, in particular to a fluorine-free waterproofing agent for textiles and a preparation method thereof. Background technique [0002] In order to meet people's continuous requirements for textiles, more and more textiles are endowed with functionality, and waterproof function is one of the important branches. Water and oil repellent fabric is a functional and intelligent fabric. Textiles treated with water and oil repellency can resist rainwater and oil stains, and can discharge sweat and sweat from the human body in a timely manner, so as to keep the human body dry and warm, and are water and oil repellent in decoration and industrial fields. Functional tablecloths, car protective covers, etc. are also popular. [0003] At present, the best waterproof finishing agents are still fluorine-containing organic polymers. Of course, most of these waterproof finishing agents co...

Claims

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Application Information

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IPC IPC(8): D06M11/46D06M15/263D06M15/227D06M13/256D06M13/188D06M15/647D06M11/65C08F220/18C08F220/10D06M101/32
CPCC08F220/18C08F220/1804D06M11/46D06M11/65D06M13/188D06M13/256D06M15/227D06M15/263D06M15/647D06M2101/32D06M2200/11D06M2200/12D06M2200/50C08F220/10
Inventor 胡玲
Owner 佛山慧创正元新材料科技有限公司
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