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A short-cycle hot-press inorganic adhesive and its preparation method and application

An inorganic adhesive, short-cycle technology, applied in the direction of inorganic adhesives, adhesives, adhesive additives, etc., can solve the problems of poor water resistance and fire resistance, water loss, long hot pressing cycle, etc., to achieve bonding performance and waterproof performance Excellent, increased toughness and flexural strength, shortened hot pressing time

Active Publication Date: 2020-12-29
CENTRAL SOUTH UNIVERSITY OF FORESTRY AND TECHNOLOGY
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0003] At present, aldehyde adhesives are mainly used in the production of wood-based panels in my country. Wood-based panels have technical bottlenecks such as high release of free formaldehyde, poor water resistance and fire resistance.
Although the wood-based panels produced with inorganic adhesives have the advantages of no free formaldehyde release, good waterproof and fireproof performance, but when inorganic adhesives are used in the cold-pressing production process of wood-based panels, a large number of clamping frames and backing plates are required. Large investment, long pressurized maintenance time and low production efficiency
In addition, when inorganic adhesives are used in the hot-pressing production process of wood-based panels, the hot-pressing cycle is long, and water loss is serious during the hot-pressing process, which will adversely affect the strength of wood-based panels.

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0030] A short-cycle hot-pressing inorganic adhesive prepared from the following components by weight: 30 parts of tap water, 50 parts of aluminum tripolyphosphate, 60 parts of sodium silicate, 10 parts of phosphoric acid, 8 parts of boric acid, and 5 parts of protein soil 7 parts, 7 parts of natural betaine, 7 parts of rosin powder, 7 parts of nylon powder, 15 parts of bisphenol A cyanate resin. The above-mentioned boric acid, natural betaine, nylon powder, rosin powder and bisphenol A cyanate resin are all products passed through a 200-mesh sieve.

[0031] The preparation method of above-mentioned inorganic adhesive agent, comprises the following steps:

[0032] (1) Fully mix aluminum tripolyphosphate, tap water and sodium silicate into a closed container, heat at 200°C for 1 hour, grind and sieve after cooling to obtain a 300-mesh mixed powder;

[0033] (2) Fully mix boric acid and tap water, stir well, then add the mixed powder obtained in step (1), and stir for 10 minute...

Embodiment 2

[0049] A short-cycle hot-pressing inorganic adhesive prepared from the following components by weight: 40 parts of tap water, 40 parts of aluminum tripolyphosphate, 70 parts of sodium silicate, 13 parts of phosphoric acid, 7 parts of boric acid, and 7 parts of protein soil 6 parts of natural betaine, 4 parts of rosin powder, 6 parts of nylon powder, 18 parts of bisphenol A cyanate resin. The above-mentioned boric acid, natural betaine, nylon powder, rosin powder and bisphenol A cyanate resin are all products passed through a 200-mesh sieve.

[0050] The preparation method of the above-mentioned inorganic adhesive is the same as in Example 1.

[0051] This embodiment also provides an application of the above-mentioned inorganic adhesive, that is, using the inorganic adhesive to prepare a wood-based panel, and the wood-based panel is prepared from the above-mentioned inorganic adhesive and wood processing residue fibers. The specific preparation method is as follows:

[0052] ...

Embodiment 3

[0058] A short-cycle hot-pressing inorganic adhesive prepared from the following components by weight: 50 parts of tap water, 50 parts of aluminum tripolyphosphate, 70 parts of sodium silicate, 15 parts of phosphoric acid, 5 parts of boric acid, and 10 parts of protein soil 8 parts, 8 parts of natural betaine, 3 parts of rosin powder, 8 parts of nylon powder, 20 parts of bisphenol A type cyanate resin. The above-mentioned boric acid, natural betaine, nylon powder, rosin powder and bisphenol A cyanate resin are all products passed through a 200-mesh sieve.

[0059] The preparation method of the above-mentioned inorganic adhesive is the same as in Example 1.

[0060] This embodiment also provides an application of the above-mentioned inorganic adhesive, that is, using the inorganic adhesive to prepare a wood-based panel, and the wood-based panel is prepared from the above-mentioned inorganic adhesive and bamboo processing residue fibers. The specific preparation method is as fo...

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Abstract

The invention discloses a short cycle hot press inorganic adhesive, which comprises the following components by weight: 40-60 parts of aluminum tripolyphosphate, 60-80 parts of sodium silicate, 10-15parts of phosphoric acid, 3-8 parts of a wetting agent, 6-8 parts of a toughening agent, 5-8 parts of rosin powder, 10-20 parts of bisphenol A cyanate ester resin, and 20-50 parts of water. The invention also provides a preparation method and application of the short cycle hot press inorganic adhesive. The inorganic adhesive contains the pre-locking agent bisphenol A cyanate ester resin and the initial adhesive rosin. When the inorganic adhesive is used for artificial boards, the hot press time is shorter, and the hot press time can be shortened by 50% or more. In addition, the artificial boards prepared with the inorganic adhesive have no emission of free formaldehyde or other toxic gases.

Description

technical field [0001] The invention belongs to the field of adhesives, and in particular relates to an inorganic adhesive used for wood-based panels, a preparation method and application thereof. Background technique [0002] my country produces more than 1.5 billion tons of agricultural and forestry processing residues every year, including about 900 million tons of agricultural straw. Most of the agricultural straw is burned or used as fuel, with low added value. It also aggravates smog and brings environmental pollution problems. my country's annual wood consumption is about 600 million cubic meters, while the annual supply is about 300 million cubic meters, and the dependence on foreign countries exceeds 50%. The use of agricultural and forestry processing residues to expand the production scale of wood-based panels can effectively alleviate the shortage of wood resources in my country. [0003] At present, aldehyde adhesives are mainly used in the production of wood-b...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): C09J1/02C09J11/04C09J11/06C09J11/08
CPCC09J1/02C09J11/04C09J11/06C09J11/08
Inventor 李新功郑霞杨凯张晓风夏琪琪李佩琦林云飞陈东山谢向荣
Owner CENTRAL SOUTH UNIVERSITY OF FORESTRY AND TECHNOLOGY
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