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A kind of preparation method of cobalt colored mica pearlescent pigment

A pearlescent pigment, mica technology, applied in inorganic pigment processing, chemical instruments and methods, fibrous fillers, etc., can solve the problems of poor pigment saturation and gloss, achieve enhanced reflection effect, loose finished products, high polarizability Effect

Active Publication Date: 2020-09-18
上海毅旺新材料有限公司
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0005] The technical problem to be solved by the present invention is to provide a preparation method of cobalt-colored mica pearlescent pigments for the problem of poor pigment saturation and glossiness of the discoloration effect of commercially available mica pigments

Method used

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Examples

Experimental program
Comparison scheme
Effect test

example 1

[0024] Take 0.12g europium trioxide, 0.10g cerium oxide, 0.10g neodymium oxide, add 50g mass fraction of 1% nitric acid solution, stir at 300r / min for 30min, get rare earth salt solution, take 0.5g cobalt nitrate, 1.0g nitric acid Aluminum, add 50mL of deionized water, stir at 300r / min for 20min, then add rare earth salt solution, continue to stir for 20min to obtain a coloring solution, take 5g of glass flakes, 5g of flaky alumina, 5g of flaky mica powder, add 300mL of deionized In water, stir at 300r / min for 20h in a constant temperature water bath at 40°C, adjust the pH to 9.0 with a 5% sodium carbonate solution by mass fraction, then raise the temperature to 80°C, add the coloring solution dropwise at 1g / min, and drop the mass fraction at the same time Use 10% ammonia water to keep the pH constant, let it stand for 30 minutes after the dropwise addition, filter to obtain the filter residue, wash the filter residue twice with deionized water, place it in a drying oven, and d...

example 2

[0026]Take 0.13g europium trioxide, 0.11g cerium oxide, 0.11g neodymium oxide, add 80g mass fraction to 1% nitric acid solution, stir at 350r / min for 35min, get rare earth salt solution, take 0.8g cobalt nitrate, 1.5g nitric acid Aluminum, add 80mL of deionized water, stir at 350r / min for 25min, then add rare earth salt solution, continue stirring for 25min to obtain a coloring solution, take 8g of glass flakes, 8g of flaky alumina, 8g of flaky mica powder, add 450mL of deionized In water, stir at 350r / min for 22h in a constant temperature water bath at 45°C, and adjust the pH to 9.2 with a 5% sodium carbonate solution by mass fraction, then raise the temperature to 85°C, add the coloring solution dropwise at 1g / min, and add the mass fraction at the same time 10% ammonia water was used to keep the pH constant. After the dropwise addition, let stand for 40 minutes, filter the filter residue, wash the filter residue twice with deionized water, put it in a drying oven, and dry it ...

example 3

[0028] Take 0.15g europium trioxide, 0.12g cerium oxide, 0.12g neodymium oxide, add 100g mass fraction of 1% nitric acid solution, stir at 400r / min for 40min, get rare earth salt solution, take 1.0g cobalt nitrate, 2.0g nitric acid Aluminum, add 100mL deionized water, stir at 400r / min for 30min, then add rare earth salt solution, continue stirring for 30min to obtain a coloring solution, take 10g glass flakes, 10g flaky alumina, 10g flaky mica powder, add 600mL deionized In water, stir at 400r / min for 24 hours in a constant temperature water bath at 50°C, and adjust the pH to 9.5 with a 5% sodium carbonate solution by mass fraction, then raise the temperature to 90°C, add the coloring solution dropwise at 2g / min, and add the mass fraction at the same time 10% ammonia water was used to keep the pH constant. After the dropwise addition, let it stand for 50 minutes, filter the filter residue, wash the filter residue 3 times with deionized water, place it in a drying oven, and dry ...

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PUM

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Abstract

The invention relates to a preparation method of a cobalt coloring mica pearlescent pigment, and belongs to the technical field of pigment preparation. By means of a special 4f electron layer structure of a rare earth element, the rear earth element has rich visible light region spectrum lines and serves as a chromophoric group to be applied in the pigment, the rear earth element serves as a doping agent to enter other compound crystal lattices, crystal phase structure or crystal lattice parameters can be changed, and then the pigment generates a special hue, the effects of changing color, stabilizing color and assisting color are achieved, rear earth ion polarizability is high, rear earth ions enter host crystals, the refractive index of the crystals can be increased, the reflection effect to the light is enhanced, the paint color can look brighter, the degree of saturation of the paint color is improved, hydrated titanium dioxide flakes generated through titanium salt hydrolysis areuniformly and compactly deposited on the surface of the flake pigment, and a TiO2 H2O film high in refractive index and good in transparency is formed. The mica pearlescent pigment film is uniform, compact and excellent in pearly-lustre effect, and has the function of shielding ultraviolet light, microwaves and infrared rays.

Description

technical field [0001] The invention relates to a preparation method of a cobalt-colored mica pearlescent pigment, which belongs to the technical field of pigment preparation. Background technique [0002] The research, development and utilization of mica pearlescent pigments in my country started relatively late. There are more than 50 units engaged in the research, development and production of this new product in my country, with an annual total output of more than several thousand tons. However, the quality of mica pearlescent pigments in my country and Compared with foreign products, there are great differences in performance, such as silver-white pearlescent pigments: low gloss and low whiteness; colored pearlescent pigments: the color is not pure and bright, and the wettability and dispersibility of the pigments are not ideal. In addition, due to the lack of complete and advanced characterization means in our country, the application field is narrow, and it is far from...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): C09C1/40C09C3/04C09C3/06
CPCC09C1/0015C09C1/0021C09C3/006C09C3/041C09C3/043C09C3/063
Inventor 苗霞明张桂芳朱华
Owner 上海毅旺新材料有限公司