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Amorphous alloy polishing solution and amorphous alloy polishing method

A technology of amorphous alloy and polishing fluid, applied in the field of amorphous alloy polishing, can solve the problems of chemical residue, difficult cleaning, high free electron content, etc., and achieve the effect of low current density, guaranteed polishing quality, and low atomic momentum

Pending Publication Date: 2018-10-16
GUANGDONG UNIV OF TECH
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

The high elasticity and high hardness of amorphous alloys make traditional mechanical polishing methods have problems such as poor effect and low efficiency; electrochemical polishing is also limited by the high resistivity of amorphous materials, and the electrolytic polishing electrolyte is often a highly corrosive chemical substance. Such as sulfuric acid, hydrofluoric acid, etc., it is difficult to clean after throwing away, and there are chemical residues, which leads to the inability of the treated surgical instruments to achieve the ideal medical performance
[0003] In the existing amorphous alloy polishing method, when the current is passed through the amorphous alloy, the content of free electrons in the large current is large, and the free electrons move in a direction. By colliding with the atoms in the amorphous, the kinetic energy is transferred to the atoms, so that the atoms Increased irregular thermal motion

Method used

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  • Amorphous alloy polishing solution and amorphous alloy polishing method
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Examples

Experimental program
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Effect test

Embodiment 1

[0019] A method for polishing an amorphous alloy, comprising the steps of:

[0020] (1) Sample cleaning: use an ultrasonic machine to clean and dry the surface of the amorphous alloy sample, wherein the composition of the amorphous alloy sample is Zr-Cu-Al-Ni-Ti, and its ratio is Zr30 .1:: Cu11.19: Ni10.77: Ti2.22: Al4.81;

[0021] (2) Preparation of polishing liquid: Prepare 1L of polishing liquid with deionized water as solvent. In the polishing liquid, the content of each component is: ammonium sulfate 60g / L, ammonium bifluoride 0.5g / L, sodium sulfite 1.5g / L, molybdenum Ammonium acid 0.5g / L, sodium dodecylsulfobenzenesulfonate 0.5g / L;

[0022] (3) Take the zirconium-based amorphous alloy sample as the anode and connect it to the positive pole of the DC power supply and immerse it in the tank containing the electrolyte polishing solution prepared in step (2);

[0023] (4) Take the stainless steel sheet as the cathode and connect it to the negative pole of the DC power supp...

Embodiment 2

[0028] A method for polishing an amorphous alloy, comprising the steps of:

[0029] (1) Sample cleaning: use an ultrasonic machine to clean and dry the surface of the amorphous alloy sample, wherein the composition of the amorphous alloy sample is Zr-Cu-Al-Ni-Ti, and its ratio is Zr30 .1:: Cu11.19: Ni10.77: Ti2.22: Al4.81;

[0030] (2) Preparation of polishing liquid: prepare 1L of polishing liquid with deionized water as solvent. In the polishing liquid, the content of each component is: ammonium sulfate 30g / L, ammonium bifluoride 1.5g / L, sodium sulfite 1.8g / L, molybdenum Ammonium acid 1g / L, sodium dodecyl sulfobenzene sulfonate 1g / L;

[0031] (3) Take the zirconium-based amorphous alloy sample as the anode and connect it to the positive pole of the DC power supply and immerse it in the tank containing the electrolyte polishing solution prepared in step (2);

[0032] (4) Take the copper sheet as the cathode and connect it to the negative pole of the DC stabilized power supp...

Embodiment 3

[0037] A method for polishing an amorphous alloy, comprising the steps of:

[0038] (1) Sample cleaning: use an ultrasonic machine to clean and dry the surface of the amorphous alloy sample, wherein the composition of the amorphous alloy sample is Zr-Cu-Al-Ni-Ti, and its ratio is Zr30 .1:: Cu11.19: Ni10.77: Ti2.22: Al4.81;

[0039] (2) Preparation of polishing liquid: Prepare 1L of polishing liquid with deionized water as solvent. In the polishing liquid, the content of each component is: ammonium chloride 50g / L, ammonium bifluoride 2g / L, sodium sulfite 3g / L, molybdic acid Ammonium 1.2g / L, sodium dodecasulfobenzenesulfonate 1g / L;

[0040] (3) Take the zirconium-based amorphous alloy sample as the anode and connect it to the positive pole of the DC power supply and immerse it in the tank containing the electrolyte polishing solution prepared in step (2);

[0041] (4) The graphite sheet is used as the cathode to be connected to the negative pole of the DC stabilized power supp...

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Abstract

The invention relates to an amorphous alloy polishing method. The method is characterized in that the amorphous alloy is used as an anode and is connected to the positive electrode of a direct-currentstabilized voltage power source and is immersed into a polishing groove containing the polishing solution, and a conductive material is used as a cathode and is connected to the direct-current stabilized voltage power source and is immersed into the polishing groove; and the direct-current stabilized voltage power source is connected to carry out plasma polishing on the amorphous alloy, wherein the temperature of the polishing solution is 50-100 DEG C, the voltage of the direct-current voltage stabilized power source ranges from 100V to 380V, and the current density of the direct-current voltage stabilized power source ranges from 0.2 A / cm<2> to 1 A / cm<2>. According to the method, the amorphous alloy is polished by adopting the direct-current voltage, the current density is small, the impact force on atoms in the amorphous alloy is small, the crystallization phenomenon of the amorphous alloy cannot be caused, the polishing quality is ensured, and the quality of the amorphous alloy isnot influenced.

Description

technical field [0001] The invention relates to the technical field of amorphous alloy polishing, in particular to a polishing liquid for amorphous alloys and a polishing method for amorphous alloys. Background technique [0002] Medical amorphous alloy materials, such as tensile strength 2-3 times that of similar polycrystalline metals (>2GPa), low elastic modulus (70-90GPa) closer to natural bone, high elastic limit (~2%, basically before yielding Fully elastic), high specific strength (3.2×105N m / kg), high hardness (480-550HV), corrosion resistance, wear resistance and good biocompatibility, are widely used in high-end medical surgical instruments precision Parts manufacturing. Medical parts have extremely high requirements on the surface quality and processing accuracy. The appearance is required to be clean and smooth, without burrs and cracks, so as to ensure the high corrosion resistance and high biological safety of medical surgical instruments to meet the insp...

Claims

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Application Information

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IPC IPC(8): C25F3/16
CPCC25F3/16
Inventor 王成勇何小琳李乃涛高宽张涛郑李娟
Owner GUANGDONG UNIV OF TECH
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