Method for producing graphene functionalized nitrile flocked gloves

A flocked glove, ene-functional technology, applied in the field of gloves, can solve the problems of poor dispersion and compatibility, low performance of glove products, achieve strong tensile properties and wear resistance, wide use value, resistance to cutting and puncture The effect of performance improvement

Inactive Publication Date: 2018-12-07
NANTONG QIANGSHENG SAFETY PROTECTION TECHNOLOGY CO LTD
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

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Problems solved by technology

[0008] The object of the present invention is to provide a kind of preparation method of the graphene functionalized nitrile flocking glove that has functions such as strengthening wear resistance, sterilizing, deodorizing and absorbing sweat for the above-mentioned deficiencies in the prior art and the low performance of glove products; To solve the problem of poor dispersion and compatibility of graphene in nitrile latex, thereby endowing gloves with functionality and improving the ISO-13997 performance indicators of gloves

Method used

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  • Method for producing graphene functionalized nitrile flocked gloves
  • Method for producing graphene functionalized nitrile flocked gloves
  • Method for producing graphene functionalized nitrile flocked gloves

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Experimental program
Comparison scheme
Effect test

Embodiment 1～3

[0054] Embodiments 1 to 3 respectively provide a technical solution for the preparation of nitrile flocked gloves functionalized with graphene as shown in Table 1, wherein on the premise that other raw materials remain the same, with the amount of graphene added as a variable, the graphene The effect of the ratio on glove performance. Specific steps are as follows:

[0055] Step 1: Prepare a coagulation bath (agent) according to the ratio of the coagulant in Table 1, stir well and set aside;

[0056] Step 2: pickling, water washing, alkali washing, scrubbing and drying the hand model in turn for later use;

[0057] Step 3: According to the parts by weight of the auxiliary materials described in Table 1, prepare auxiliary materials with a solid content of 50%, and grind for 48 to 72 hours, so that the particle size of each component is below 5um;

[0058] Step 4: the alkali is added in the nitrile latex, and the pH value is adjusted to two parts of nitrile latex; in this step...

Embodiment 4～6

[0071] Embodiments 4 to 6 respectively provide a technical solution for the preparation of nitrile flocked gloves functionalized with graphene as shown in Table 2, wherein under the premise that other raw materials are kept the same, the addition amount of graphene reducing agent is used as a variable. Effect of reducing agent proportion on glove performance. Specific steps are as follows:

[0072] Step 1: prepare materials according to the parts by weight described in Table 2;

[0073] Step 2: adding the alkali into the nitrile latex, and adjusting the pH value of two parts of nitrile latex; in this step, the pH of the nitrile latex after the alkali (potassium hydroxide) treatment is above 9;

[0074] Step 3: Add the ground auxiliary components to the alkalized nitrile latex. In this step, the grinding time is 48-72 hours, and the particle size of each component is below 5um;

[0075] Step 4: adding the grinding auxiliary material into the alkalized nitrile latex;

[0076]...

Embodiment 7～9

[0089] Embodiment 7~9 provides a kind of preparation technology scheme of the nitrile flocking glove functionalized with graphene shown in table 3 respectively, wherein under the premise that other raw materials keep the same, the kind of graphene (oxidation-reduction method, mechanical exfoliation method and electrochemical stripping method) as variables, the effects of three types of graphene on glove performance were studied. Specific steps are as follows:

[0090] Step 1: prepare materials according to the parts by weight described in Table 3;

[0091] Step 2: adding the alkali into the nitrile latex, and adjusting the pH value of two parts of nitrile latex; in this step, the pH of the nitrile latex after the alkali (potassium hydroxide) treatment is above 9;

[0092] Step 3: Add the ground auxiliary material components to the alkalized nitrile latex. In this step, the grinding time is 48 to 72 hours, and the particle size of each component is below 5um;

[0093] Step 4: a...

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Abstract

The invention discloses a method for producing graphene functionalized nitrile flocked gloves. Highly-water-soluble graphene oxide is adopted, and is organically modified, the specially treated graphene oxide is uniformly dispersed in nitrile butadiene latex, a graphene oxide reducing agent is added into the latex, and the co-action of heat reduction of the graphene oxide and reduction of the reducing agent in the high-temperature vulcanization molding of the nitrile butadiene latex makes the performances of reduced graphene maximally shown in the latex gloves. Test data of the graphene functionalized nitrile flocked gloves show that the mechanical property tensile strength is improved by 65%, and reaches 43 MPa; the elongation at break is increased by 38% or above, and reaches 360% or above; the antibacterial performance reaches 100%, and the chemical resistance is grade 5; and the wear resistance, the cutting resistance and the puncture performance of the gloves are greatly improved.

Description

technical field [0001] The invention relates to a glove, in particular to a preparation method of a graphene functionalized nitrile flocked glove. Background technique [0002] Gloves are necessary protective products for people's daily life and industrial production. Among them, the long tube gloves produced with rubber and plastic as raw materials have good protective effects such as waterproof, anti-stain and anti-corrosion. However, gloves made of this material may suffer from skin allergies, bacterial infections, sweating, sticking, and odors during use, and the tear resistance and chemical resistance are not high, which cannot meet the requirements in chemical, petroleum, etc. industry use. In order to meet the needs of various industries for glove performance, it is urgent to develop a glove that can improve the above deficiencies and impart new properties such as antibacterial, mite removal, sweat absorption and deodorization. [0003] Investigating the patents of...

Claims

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Application Information

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IPC IPC(8): C08J5/02C08L13/02C08L1/28C08K13/06C08K9/04C08K3/04C08K3/22C08K3/06A41D19/015
CPCA41D19/0006A41D19/015C08J5/02C08J2313/02C08J2401/28C08K3/042C08K2003/2241C08K2003/2296C08K2201/014
Inventor 沙嫣沙晓林兰会林
Owner NANTONG QIANGSHENG SAFETY PROTECTION TECHNOLOGY CO LTD
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