Preparation method of injection-molded polyurethane tire
A technology of polyurethane tires and polyurethane elastomers is applied in the field of preparation of injection polyurethane tires, which can solve the problems of tediousness and difficult positioning of bead rings, and achieve the effects of simplifying the preparation process, high uniformity of tire quality, and strong operability.
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Embodiment 1
[0047] The mass ratio of tetrahydrofuran polyether diol to 1,4-phenylene diisocyanate is 100:40 to prepare a prepolymer, heat to 80°C, add 1% of the mass of the prepolymer to give the tire white color, and place in the mold The skeleton material is fixed in the tire mold by three-point positioning, the positioning deviation is 0.01mm, the electromagnetic force is adjusted to 1T, and a layer of 0.1mm thick polyvinyl alcohol release agent is sprayed on the inner wall. The skeleton material is composed of steel wire and laminated mesh. Weave the structure, start the injection machine to inject into the tire mold, fill the mold to maintain a pressure of 0.1MPa, keep warm at 80°C, release the mold after 5 minutes, cool and mold and demould to obtain the tire matrix; the fatty acid memory composite glue is used as the anti-puncture protective layer for precision Spray on the inner wall of the tire with a thickness of 1.7mm; apply 0.01mm thick trichloroisocyanuric acid on the surface ...
Embodiment 2
[0049] The mass ratio of polyadipate-1,4-butanediol to diphenylmethane-4,4-diisocyanate is 100:40 to prepare a prepolymer, heat to 150°C, and add 1% of the mass of the prepolymer The red pigment gives the tire a red color, and the frame material is fixed in the tire mold by two-point positioning in the mold. The positioning deviation is 0.05mm, the electromagnetic force is adjusted to 0.1T, and a layer of 0.5mm thick paraffin release agent is sprayed on the inner wall. The frame material Adopt a single-layer mesh cylinder structure, start the injection machine to inject into the tire mold, fill the mold to maintain a pressure of 30MPa, keep warm at 170°C, release the mold after 10 minutes, cool down, mold and demould to obtain the tire matrix; compound a layer of polyvinyl alcohol gas inside the tire Barrier film with a thickness of 1.8mm; on the surface of the tire base pattern, apply a 0.05mm thick solution of trichloroisocyanuric acid with methyl ethyl ketone as a solvent fo...
Embodiment 3
[0051] The caprolactone-modified polyrotaxane and hydrogenated xylylene diisocyanate are prepared into a prepolymer at a mass ratio of 100:48, heated to 120°C, and 1% of the weight of the prepolymer is added to give the tire a yellow color. In the mold, the skeleton material is fixed in the tire mold by surface matching positioning method, the positioning deviation is 0.04mm, the permanent magnetic force is 0.4T, and a layer of 0.02mm thick silicone oil release agent is sprayed on the inner wall. The skeleton material adopts a single-layer mesh cylinder structure. Start the injection machine to inject into the tire mold, fill the mold to maintain a pressure of 0.3MPa, keep warm at 120°C, release the mold after 60 minutes, and spray the fatty acid memory composite glue on the inner wall of the tire as an anti-puncture protective layer, with a thickness of 1.5mm , place the injected tire matrix in a 120°C oven for post-treatment for 1 hour, cool and solidify, mold and demould to ...
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