Method for repairing cadmium and halogenated hydrocarbon contaminated soil

A technology for contaminated soil and halogenated hydrocarbons, which is applied in the field of remediation of cadmium and halogenated hydrocarbons contaminated soil, can solve the problems of high treatment cost, inability to effectively remove soil heavy metal pollution sources, and low repair efficiency, and achieve less heat energy consumption and benefit Industrial promotion and application, the effect of simple method

Inactive Publication Date: 2018-12-18
CHANGSHA HUIJU ENVIRONMENTAL TECH CO LTD
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Problems solved by technology

[0007] For the treatment of cadmium and halogenated hydrocarbon contaminated soil, the existing technology has problems such as low repair efficiency, high treatment cost, and inability to effectively remove soil heavy metal pollution sources, etc.

Method used

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  • Method for repairing cadmium and halogenated hydrocarbon contaminated soil

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Embodiment Construction

[0024] Biomass carbon obtained by vacuum pyrolysis of walnut shells and calcium oxide with a mass ratio of 4:1 at a system pressure of 0.5Kpa and a pyrolysis temperature of 500°C for 30 minutes.

[0025] Excavate the soil of the cadmium and 1,2-dichloroethane-contaminated plot, and process it into 2-5mm soil particles through a crusher; prepare dilute nitric acid solution, and prepare 0.1mol / L Add dilute nitric acid solution to 1kg of soil particles, mix and stir for 30min, filter, then add 500g of activated alumina to obtain a soil mixture; send the soil mixture to a vacuum pyrolysis stirring device, heat to 150-200°C, and the system pressure is 1kpa, continuously Stir and keep warm for 30 minutes, the cadmium nitrate and halogenated hydrocarbons in the soil will volatilize from the soil to realize the separation from the soil; add 200g of biomass carbon to the soil, mix evenly, adjust the soil to be weakly alkaline, and obtain the repaired soil.

[0026] Experimental result...

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Abstract

The invention provides a method for repairing cadmium and halogenated hydrocarbon contaminated soil. The method for repairing the cadmium and halogenated hydrocarbon contaminated soil comprises the steps of firstly, excavating soil from a cadmium and halogenated hydrocarbon contaminated land parcel; treating the soil into 2-5 mm soil particles by using a crusher; preparing a dilute nitric acid solution; adding the dilute nitric acid solution, which is prepared according to a ratio of 1L / kg, to the soil particles; mixing and stirring an obtained mixture for 30 min; filtering the mixture; addingactivated aluminium oxide to the filtered mixture according to a certain ratio so as to obtain a soil mixture; feeding the soil mixture into a vacuum pyrolysis stirring device; heating the soil mixture to 150-200 degrees centigrade; continuously stirring the soil mixture; preserving the heat of the soil mixture for 30 min; enabling cadmium nitrate and halogenated hydrocarbon in the soil to volatilize so as to separate the cadmium nitrate and the halogenated hydrocarbon from the soil; adding biomass carbon to the soil according to a certain ratio; uniformly mixing the biomass carbon and the soil; and regulating the soil to be alkalescent so as to obtain repaired soil. The method for repairing the cadmium and halogenated hydrocarbon contaminated soil has the advantages that the heat energyconsumption in use is less, the cadmium and the halogenated hydrocarbon in the soil can be effectively separated, the method is simple, the operation is easy, the treatment effect is good, and a purpose of long-acting treatment is achieved.

Description

Technical field: [0001] The invention relates to the technical field of soil pollution remediation, in particular to a method for remediating cadmium and halogenated hydrocarbon contaminated soil. technical background: [0002] There are 1.8 to 2 million cancer cases and 1.4 to 1.5 million deaths in the country every year, which is related to the excessive pollution of agricultural products to a certain extent. Soil heavy metal pollution has gradually become the focus of public attention. [0003] Cadmium (Cd) pollution is the most harmful. Soil cadmium pollution mainly comes from the deposition of cadmium in the atmosphere, the use of pesticides, fertilizers and plastic films, sewage irrigation, sludge fertilization, accumulation of heavy metal-containing waste, and acid wastewater pollution from metal mines. Cd element has been listed by the United Nations Environment Program as the first globally significant hazardous chemical substance. Cd pollution will not only caus...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): B09C1/08B09C1/06
CPCB09C1/08B09C1/065
Inventor 不公告发明人
Owner CHANGSHA HUIJU ENVIRONMENTAL TECH CO LTD
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