Normal temperature heat conducting and high temperature insulation porcelainized high molecular material and preparation method of material

A technology of polymer materials and heat insulating fillers, which is applied in the field of porcelainizable polymer materials and their preparation, can solve the problem of difficulty in ensuring low temperature heat conduction and high temperature heat insulation at the same time, poor compatibility between heat conductive fillers and silicone rubber matrix, and composite materials. Mechanical properties have a great impact on problems such as easy mass production, excellent mechanical properties, and good consistency.

Active Publication Date: 2018-12-25
上海陛升新材料科技有限公司 +1
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0005] Due to the poor compatibility between the thermally conductive filler and the silicone rubber matrix, the amount added has a great influence on the mechanical properties of the composite material
When the amount of thermally conductive filler added is large, the thermal conductivity is better, but in order to ensure the overall performance of the silicone rubber composite material, only the amount of high temperature resistant filler can be controlled, so it is difficult to ensure the simultaneous realization of the two functions of low temperature heat conduction and high temperature heat insulation , so that the current invention can only be aimed at one of the two functions of heat conduction or fire resistance and heat insulation
For example: the invention patent CN201510354977 provides a high thermal conductivity polyvinyl chloride sheath material for c

Method used

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  • Normal temperature heat conducting and high temperature insulation porcelainized high molecular material and preparation method of material
  • Normal temperature heat conducting and high temperature insulation porcelainized high molecular material and preparation method of material
  • Normal temperature heat conducting and high temperature insulation porcelainized high molecular material and preparation method of material

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0043] See attached Figure 1-2 , a normal temperature heat conduction-high temperature heat insulation ceramicizable polymer material provided by the present invention, which is prepared from the following raw material components (by mass fraction):

[0044]

[0045] The preparation method of the above normal temperature heat conduction-high temperature heat insulation ceramicizable polymer material comprises the following steps:

[0046] (1) Get aluminum hydroxide 1500g and deionized water 5000g, adopt zirconia ball milling beads 5000g as the grinding medium, import in the vertical sand mill and grind, the grinding time is 1 hour, and the grinding speed is 60 rpm;

[0047] (2) filter after grinding, use 300 mesh filter screens for filtration, get the solid gained from the filtration, dry and pulverize to obtain the aluminum hydroxide that has been pretreated;

[0048] (3) Base rubber mixing: use an internal mixer, add methyl vinyl silicone rubber, linear low-density poly...

Embodiment 2

[0053] A normal temperature heat conduction-high temperature heat insulation ceramicizable polymer material, which is prepared from the following raw material components (by mass fraction):

[0054]

[0055] The preparation method of the above normal temperature heat conduction-high temperature heat insulation ceramicizable polymer material comprises the following steps:

[0056] (1) Get each 1500g of magnesium hydroxide, sepiolite fiber and mix with deionized water 5000g respectively, respectively adopt 5000g of zirconia ball milling beads as the grinding medium, import in the vertical sand mill and grind, the grinding time is 1 hour, The grinding speed is 60 rpm;

[0057] (2) Filtrate after grinding, use a 300-mesh filter screen for filtration, take the solid obtained from the filtration, dry and pulverize, and obtain pretreated magnesium hydroxide and sepiolite fibers;

[0058] (3) Base rubber mixing: use an internal mixer, add methyl vinyl silicone rubber, linear low-d...

Embodiment 3

[0063] A normal temperature heat conduction-high temperature heat insulation ceramicizable polymer material, which is prepared from the following raw material components (by mass fraction):

[0064]

[0065]

[0066] A method for preparing a normal temperature heat conduction-high temperature heat insulation ceramicizable polymer material, comprising the following steps:

[0067] (1) get aluminum hydroxide, sepiolite fiber each 1500g and mix with deionized water 5000g respectively, respectively adopt zirconia ball milling beads 5000g as grinding medium, import in the vertical sand mill and grind, the grinding time is 1 hour, The grinding speed is 60 rpm;

[0068] (2) Filter after grinding, use a 300-mesh filter screen to filter, take the solid obtained from the filter, dry and pulverize, and obtain pretreated aluminum hydroxide and sepiolite fibers;

[0069] (3) Base rubber mixing: use an internal mixer, add methyl vinyl silicone rubber, linear low density polyethylene,...

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Abstract

The invention discloses a normal temperature heat conducting and high temperature insulation porcelainized high molecular material which comprises 100 parts of base gum, 20-30 parts of reinforcing agents, 10-30 parts of halogen-free flame retardants, 20-40 parts of porcelain sintering additives, 1-4 parts of heat conducting functional fillers, 4-16 parts of high temperature insulation fillers, 0.01-10 parts of platinum complexes or platinum compounds (calculated in terms of platinum, 1-5 parts of structured control agents and 1.5 parts of crosslinking agents. The invention further discloses apreparation method of the material. The preparation method includes the steps of base gum mixing, milling, discharging and vulcanizing. The highest heat conducting coefficient of the normal temperature heat conducting and high temperature insulation porcelainized high molecular material reaches 0.4W/(m*K) and is far higher than that of a common porcelainized high molecular composite material by 0.2W/(m*K), the heat conducting coefficient of the high temperature porcelainized material is reduced to be 0.08W/(m*K), and the material has the unique advantages of normal temperature heat conductingand high temperature insulation porcelainized properties by unique combination and matching of the heat conducting functional fillers, the high temperature insulation fillers and the porcelain sintering additives, and can be widely applied to cable production.

Description

technical field [0001] The invention relates to a porcelainizable polymer material and a preparation method thereof, in particular to a normal temperature heat conduction-high temperature heat insulation porcelainizable polymer material and a preparation method thereof. Background technique [0002] Porcelainable polymer material is a new type of thermal protection material that has polymer properties at room temperature and can be transformed into a self-supporting ceramic material at high temperature. In many industrial fields such as energy, chemical industry and metallurgy, the application prospect of porcelainable polymers is broad. For example: in the field of power transmission, the wire core itself has resistance when transmitting electric energy. The greater the current, the more heat the wire core generates, and the temperature rise of the wire core will increase its own resistance, further expanding the power transmission process. The loss due to the temperature ...

Claims

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Application Information

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IPC IPC(8): C08L83/07C08L23/08C08L83/04C08K13/02C08K3/36C08K3/22C08K3/34C08K3/38C08K7/28C08K7/22C08K7/10
CPCC08K2003/2227C08K2003/387C08K2201/014C08L83/04C08L2201/02C08L2201/08C08L2205/025C08L2205/035C08L23/0815C08L23/0853C08K13/02C08K3/34C08K3/22C08K7/28C08K7/24C08K3/38C08K7/26C08K3/40
Inventor 王金合施利毅邹雄韩景勃毛琳
Owner 上海陛升新材料科技有限公司
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