Wear-resistant coating synthesized from basalt flakes and graphene and preparing method thereof

A wear-resistant coating and graphene technology, applied in the field of coatings, can solve the problems of reducing the use time of the coating, prone to overlapping aggregation, weak bonding, etc., and achieves a reduction in corrosion rate, better adsorption effect, and outstanding anti-corrosion performance. Effect

Inactive Publication Date: 2019-01-01
TIANJIN SHANGDIAN TECH DEV
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0003] At present, the most widely used anti-corrosion coating system is the epoxy solvent-based system, and the defects of epoxy-based systems that are not resistant to ultraviolet rays and abrasion have always been a fatal point of it, which greatly reduces the service life of the coating.
Especially in conductive coatings, epoxy zinc-rich coatings, and water-based anti-corrosion coatings, it has outstanding performance. It can be seen that in the prior art, due to the agglomeration of graphene itself, the uniformity and compactness of its dispersion are prone to crossover. Overlapping and aggregation, while graphene is carried on a general carrier, there are problems such as weak bonding, easy falling off, low loading rate, etc.

Method used

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Examples

Experimental program
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Effect test

preparation example Construction

[0026] The preparation method of the corrosion-resistant and wear-resistant coating synthesized by basalt flakes fused with graphene of the present invention comprises the following steps:

[0027] 1) Disperse 3-14 parts by weight of basalt flakes, 5 parts by weight of graphene and 10-24.5 parts by weight of resin monomer in 40-58 parts by weight of epoxy resin, and stir at a high speed. In the high-speed stirring, the stirring speed is 500-5000 rpm, stirring time is 20-50 minutes, so that graphene and epoxy resin are evenly loaded on the surface of basalt scales, and an emulsion with composite sub-nanometer sheet diameters is obtained;

[0028] 2) Add 2-10 parts by weight modifier to the emulsion of composite sub-nano sheet diameter, stir at high speed to polymerize, that is, epoxy resin monomer polymerizes on the surface of basalt scales to form epoxy resin with a thickness of 5-100 μm. After the resin ultra-thin film, add 1.5 parts by weight of advective film aid and 1-5 pa...

example 1

[0031] Disperse 3 parts by weight of basalt flakes, 5 parts by weight of graphene and 24.5 parts by weight of phenolic resin monomer in 55 parts by weight of H228 epoxy resin, and stir at a high speed of 4000 rpm for 25 minutes, so that the surface of basalt scales is evenly loaded with graphene and H228 Epoxy resin to obtain an emulsion with a composite subnano sheet diameter; 10 parts by weight of benzoyl was added to the emulsion with a composite subnano sheet diameter, stirred at a high speed of 4000 rpm for 30 minutes, and the temperature was controlled at 70-80°C. Polymerization occurs, that is, epoxy resin monomers are polymerized on the surface of basalt scales to form an epoxy resin ultra-thin film, then add 1.5 parts by weight of advective membrane aid and 1 part by weight of stearic acid amide, stir to make graphene evenly dispersed, and obtain Basalt graphene coating.

example 2

[0033] Disperse 8.5 parts by weight of basalt flakes, 5 parts by weight of graphene and 24.5 parts by weight of phenolic resin monomer in 48 parts by weight of H228 epoxy resin, and stir at a high speed of 5000 rpm for 20 minutes, so that the surface of basalt scales is evenly loaded with graphene and H228 rings Oxygen resin to obtain the emulsion of composite subnano sheet diameter; 10 parts by weight dicumyl peroxide is added in the emulsion of described composite subnano sheet diameter, 3000 rev / min high-speed stirring 35 minutes, temperature is controlled at 70-80 ℃, polymerization occurs, that is, epoxy resin monomers are polymerized on the surface of basalt scales to form an epoxy resin ultra-thin film, then add 1.5 parts by weight of advective membrane aid and 2.5 parts by weight of stearic acid amide, stir to make graphene evenly dispersed, Prepared basalt graphene coating.

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Abstract

Wear-resistant coating synthesized from basalt flakes and graphene and preparing method thereof are disclosed. The method includes dispersing 3-14 parts by weight of basalt flakes, 5 parts by weight of graphene and 10-24.5 parts by weight of a resin monomer into 40-58 parts by weight of epoxy resin; stirring the mixture at a high speed to evenly loading the surfaces of the basalt flakes with the graphene and epoxy resin so as to obtain a composite emulsion having sub-nanometer flake diameter; adding 2-10 parts by weight of a modifier into the composite emulsion; polymerizing the mixture underhigh-speed stirring, namely performing epoxy resin monomer polymerization on the surface of the basalt flakes to form an epoxy resin ultrathin film having thickness of 5-100 [mu]m; then adding 1.5 parts by weight of a leveling and film formation auxiliary agent and 1-5 parts by weight of stearamide; and stirring the mixture to uniformly disperse the graphene to obtain the coating. The coating overcomes a disadvantage that graphene is difficult to disperse when applied in corrosion inhibiting coating and a disadvantage that graphene layers are liable to overlap and aggregate, has excellent low-temperature flexibility and heat resistance and is suitable for use in severe environments.

Description

technical field [0001] The present invention relates to a coating. In particular, it relates to a corrosion-resistant and wear-resistant coating synthesized by basalt flakes fused with graphene and a preparation method thereof. Background technique [0002] Wear-resistant and anti-corrosion coatings are widely used in steel structures such as traffic road maintenance, petrochemical, construction, marine engineering, and bridge engineering. [0003] At present, the most widely used anti-corrosion coating system is the epoxy solvent-based system, and the defects of epoxy-based systems that are not resistant to ultraviolet rays and abrasion have always been a fatal point of it, which greatly reduces the service life of the coating. . Thick-coated epoxy-based systems not only increase the cost of materials, but also have the disadvantages of easy cracking and low adhesion. The application of basalt flakes will greatly improve the UV resistance of the coating and fill in the s...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C09D163/00C09D163/10C09D4/06C09D4/02C09D5/08C09D7/61C09D7/65
CPCC08L2201/08C08L2205/03C09D4/06C09D5/084C09D5/18C09D7/61C09D7/65C09D7/70C09D163/00C09D163/10C08L61/06C08K7/00C08K3/042C08K5/20
Inventor 吕军李玥杨金桥王林
Owner TIANJIN SHANGDIAN TECH DEV
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