Anionic polyurethane-modified polyacrylate emulsion with crosslinked core-shell structure and preparation method thereof
A polyacrylate emulsion, polyurethane modification technology, applied in the direction of dyeing, textile and paper making, etc., can solve the problems of poor structural compatibility of polyacrylate, lack of structural hierarchy, poor acid resistance, etc., and achieve emulsion stability. Excellent, moderate film forming speed, good water resistance and acid resistance
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[0017]The preparation method of the anionic polyurethane modified polyacrylate emulsion with crosslinked core-shell structure of the present invention includes the following steps:
[0018](1) In the presence of a polyurethane catalyst, the PU active pre-polymerization monomers (ie polyester diol, polybutadiene diol, isophorone diisocyanate, dimethylol propionic acid, trimethylol Propane monoallyl ether, 1,4-butanediol, polyethylene glycol methyl ether and hydroxyethyl methacrylate) are reacted to obtain PU active prepolymer;
[0019](2) Mixing the PU active prepolymer, part of the polyacrylate monomer raw materials, part of the emulsifier, triethylamine and water to prepare a PUm active prepolymer emulsion;
[0020](3) Mix the remaining part of the polyacrylate monomer raw material, the remaining part of the emulsifier and water, stir and emulsify to prepare the PA pre-emulsion; in the presence of the initiator, the PA pre-emulsion is pre-polymerized and then added The PUm active prepolymer...
Embodiment 1
[0049](1) Preparation of PU active prepolymer
[0050]56.465g polyester diol (PE2348, molecular weight 2300), 0.987g polybutadiene diol (HTPB, molecular weight 2700), vacuum dehydration at 110 ℃ for 90 minutes, then cooling to 75 ℃ or less, adding 37.011g iso Phosphonone diisocyanate (IPDI); after the temperature stabilizes, add 5.365 g of dimethylolpropionic acid (DMPA), increase the temperature to 90℃ and keep the temperature for 60 minutes, add 0.0245g of dibutyltin dilauric acid (DBTDL), keep the temperature for 60 minutes; Cool down to below 60℃, add 13.068g trimethylolpropane monoallyl ether (TMPME), 0.36g 1,4-butanediol (BDO) and 5g polyethylene glycol methyl ether (N120, molecular weight is 1000) and react for 30min; add 0.0245g of dibutyltin dilauric acid (DBTDL), increase the temperature to 75℃ and keep for 120min, add 40g of ethylpyrrolidone (NEP) to reduce the viscosity; then add 4.555g of methacrylic acid hydroxy Ethyl ester (HEMA), react at 75°C for 90 minutes to obtain P...
Embodiment 2
[0057](1) Preparation of PU active prepolymer
[0058]52.75g polyester diol (PE2348, molecular weight 2300), 0.95g polybutadiene diol (HTPB, molecular weight 2700), vacuum dehydration at 100 ℃ for 90 minutes, then cooling to 75 ℃ or less, add 37.011g iso Phosphonone diisocyanate (IPDI); after the temperature stabilizes, add 5.3g dimethylolpropionic acid (DMPA), increase the temperature to 85°C and keep for 30min, add 0.024g dibutyltin dilauric acid (DBTDL), keep for 30min; Cool down to below 60℃, add 12.57g trimethylolpropane monoallyl ether (TMPME), 0.36g 1,4-butanediol (BDO) and 5.55g polyethylene glycol methyl ether (N120, molecular weight) dropwise 1000) and react for 20 minutes; add 0.036g of dibutyltin dilauric acid (DBTDL), increase the temperature to 70℃ and keep for 90 minutes, add 40g of ethylpyrrolidone (NEP) to reduce the viscosity; then add 5.85g of methacrylic acid hydroxy Ethyl ester (HEMA), react at 70°C for 60 minutes to obtain PU active prepolymer;
[0059](2) Preparatio...
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