Method for preparing fuel oil by co-processing of solid waste and coal tar

A technology for solid waste and coal tar, which is applied in the treatment of hydrocarbon oil, hydrotreating process, tar processing through distillation, etc. It can solve the problems of poor quality of light fuel oil, lower device economy, lack of effective management, etc. Achieve high hydrogen-carbon ratio, reduce energy consumption, and improve conversion efficiency

Active Publication Date: 2019-02-19
SHAANXI YANCHANG PETROLEUM GRP
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Problems solved by technology

Due to the lack of effective management, a lot of solid waste mostly flows into the hands of local oil refiners, which wastes resources and pollutes the environment
Although many solid waste processing devices have been established at home and abroad, they are mainly thermal cracking, and there are obvious shortcomings in the following technologies: the solid waste cracking oil production process is intermittent or semi-batch. In the operation process, the production scale is small, and the secondary cracking in the thermal cracking process seriously leads to low product yield, which is easy to cause secondary pollution to the environment. The light fuel oil has poor properties and requires secondary processing, which greatly reduces the equipment cost. economy

Method used

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  • Method for preparing fuel oil by co-processing of solid waste and coal tar

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Embodiment Construction

[0034] The present invention will be described in further detail below in conjunction with the accompanying drawings.

[0035] see figure 1 , the coal tar 13 is sent to the distillation unit 1 for separation, and the separated light components enter the tar phenol extraction unit 3 to obtain crude phenol 15 and raffinate oil 16, and the heavy components, heavy oil hydrogenation catalyst 14, and circulating oil slurry 31 enter the mixing tank 2 After being fully stirred, enter the pre-hydrogenation reaction device 4 together with the hydrogen gas 17; the pre-hydrogenation reaction device 4 consists of three plug-flow reactors connected in series with the lower feed and upper discharge, with an operating pressure of 16MPa and a temperature of 437°C. The oil volume ratio is 1100, and the space velocity is 1.42h -1 The gas-liquid product of the pre-hydrogenation reaction unit 4 enters the first gas-liquid separator 6, the second gas-liquid separator 7, and the third gas-liquid se...

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Abstract

A method for preparing fuel oil by co-processing of solid waste and coal tar includes: (1), extracting phenol of light components of coal tar; (2), subjecting heavy distillate of coal tar to prehydrogenation to promote the process of converting gelatine and asphaltene of heavy distillate into partially hydrogenated polycyclic aromatic hydrocarbon so as to improve hydrogen supply performance of theheavy distillate; (3), mixing liquid-phase products with different boiling ranges with the solid waste in a separator after the hydrogenation so as to obtain a mixture, and feeding the mixture in a co-processing reaction device to obtain gasoline, diesel oil and phenolic products, thereby realizing co-processing of the solid waste and coal tar. According to the method, the process of phenol extraction to the coal tar and the co-processing of hydrogenated heavy distillate and the solid waste are combined, a great quantity of solvent oil with good hydrogen supply capacity is provided for liquefying treatment of the solid waste, molecular utilization of the coal tar, and scaled, clean and effective utilization of the solid waste are both achieved, conversion efficiency of the coal tar and the solid waste is increased greatly, and the method has the advantages of needing low hydrogen consumption, having high oil yield and good economic benefit, and facilitating long-cycle scaled running of device, and the like.

Description

technical field [0001] The invention belongs to the technical field of chemical industry, in particular to a method for co-processing solid waste and coal tar to prepare fuel oil. Background technique [0002] Coal tar is a liquid product obtained during high-temperature dry distillation of coal. Compared with petroleum-based distillate oil, coal tar has the characteristics of high heteroatom content, high ash content, high content of polycyclic aromatic hydrocarbons, high content of colloids and asphaltenes, etc. , so that there are problems such as coking deposition in the reaction system and short service life of the catalyst when using conventional petroleum hydrotreating catalysts and processes. At the same time, a large amount of solid waste is produced in daily life, such as waste tires, waste plastics, etc. These solid wastes are difficult to degrade in the natural state, causing more and more harm to the environment, and have always been a headache for governments i...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C10G67/00C10C1/04C10G1/00
CPCC10C1/04C10G1/002C10G67/00C10G2300/1003C10G2300/1007
Inventor 韩磊李大鹏霍鹏举刘树伟程秋香李伟常方圆王焜
Owner SHAANXI YANCHANG PETROLEUM GRP
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