Environment-friendly type adhesive for coating printing and dyeing as well as preparation method and application thereof

An environmentally friendly adhesive technology, applied in dyeing, textiles and papermaking, etc., can solve the problems of environmental pollution, stickiness, easy yellowing, etc., achieve natural color, improve easy yellowing, and small investment in equipment

Inactive Publication Date: 2019-03-01
ANYANG NORMAL UNIV
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0003] At present, the main products of paint printing and dyeing adhesives are low-temperature self-crosslinking adhesives. This type of adhesive is easy

Method used

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  • Environment-friendly type adhesive for coating printing and dyeing as well as preparation method and application thereof
  • Environment-friendly type adhesive for coating printing and dyeing as well as preparation method and application thereof
  • Environment-friendly type adhesive for coating printing and dyeing as well as preparation method and application thereof

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0027] An environment-friendly adhesive for paint printing and dyeing, characterized in that it is formed by reacting the following components by weight: 55 parts of soft monomer, 15 parts of hard monomer, 7 parts of crosslinking monomer, 7 parts of cationic monomer, copolymerized monomer 8 parts of body, 2 parts of emulsifier, 0.4 part of initiator, 0.2 part of formaldehyde scavenger, 100 parts of soft water.

[0028] (1) Soft monomer: butyl acrylate, glycidyl acrylate and glycidyl acrylate are mixed with butadienoic acid;

[0029] (2) Hard monomer: mixed use of methyl methacrylate and acrylonitrile and styrene;

[0030] (3) Cross-linking monomer: mixed use of methacrylic acid and ethylene glycol glycerol dimethacrylate;

[0031] (4) comonomer: the reactant of selenous acid and 4-(2-ethylamino)benzene-1,2-diphenol and xanthan gum;

[0032] (5) Emulsifier: a compound of cationic surfactant, zwitterionic surfactant and nonionic emulsifier; the cationic surfactant is didodecan...

Embodiment 2

[0040] An environmentally friendly adhesive for paint printing and dyeing, characterized in that it is produced by the following components by weight: 50 parts of soft monomer, 10 parts of hard monomer, 8 parts of crosslinking monomer, 8 parts of cationic monomer, copolymerized monomer 7 parts of body, 1 part of emulsifier, 0.3 part of initiator, 0.1 part of formaldehyde scavenger, 80 parts of soft water.

[0041] (1) Soft monomer: Glycidyl acrylate and glycidyl acrylate are mixed with butadienoic acid;

[0042] (2) Hard monomer: mixed use of methyl methacrylate and acrylonitrile and styrene;

[0043] (3) Cross-linking monomer: mixed use of methacrylic acid and ethylene glycol glycerol dimethacrylate;

[0044] (4) comonomer: the reactant of selenous acid and 4-(2-ethylamino)benzene-1,2-diphenol and xanthan gum;

[0045] (5) Emulsifier: a compound of cationic surfactant, zwitterionic surfactant and nonionic emulsifier; the cationic surfactant is triethanolamine monooleate, 3-...

Embodiment 3

[0053] An environmentally friendly adhesive for paint printing and dyeing, characterized in that it is produced by the following components by weight: 60 parts of soft monomer, 20 parts of hard monomer, 8 parts of crosslinking monomer, 7 parts of cationic monomer, copolymerized monomer 8 parts of body, 3 parts of emulsifier, 0.5 part of initiator, 0.3 part of formaldehyde scavenger, 120 parts of soft water.

[0054] (1) Soft monomer: mixed use of glycidyl acrylate and butadienoic acid;

[0055] (2) Hard monomer: mixed use of methyl methacrylate and acrylonitrile and styrene;

[0056] (3) Cross-linking monomer: mixed use of methacrylic acid and ethylene glycol glycerol dimethacrylate;

[0057] (4) comonomer: the reactant of selenous acid and 4-(2-ethylamino)benzene-1,2-diphenol and xanthan gum;

[0058] (5) Emulsifier: a compound of cationic surfactant, zwitterionic surfactant and nonionic emulsifier; the cationic surfactant is polyepichlorohydrin-dimethylamine; the zwitterio...

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Abstract

The invention discloses an environment-friendly type adhesive for coating printing and dyeing as well as a preparation method and application thereof. The adhesive is prepared from the following components through reacting: a soft monomer, a hard monomer, a cross-linking monomer, a comonomer, an emulsifier, an initiator and a formaldehyde catching agent. A preparation process comprises the following steps: adding xanthan gum and 1/3 of soft water in sequence and stirring for dissolving; then adding selenious acid; dropwise adding 4-(2-ethylamino)benzene-1,2-diphenol; carrying out thermal insulation reaction; regulating the pH (Potential of Hydrogen) to be neutral; then adding 2/3 of soft water and 1/2 of the emulsifier and dissolving; then dropwise adding mixed liquid of the soft monomer,the hard monomer, the cross-linking monomer, 1/2 of the initiator and 1/2 of the emulsifier; carrying out thermal insulation reaction and rapidly raising the temperature; rapidly adding the comonomerand 1/2 of the initiator and stirring; then adding the formaldehyde catching agent; rapidly cooling and regulating the pH; cooling and carrying out thermal insulation reaction; naturally cooling, andfiltering and discharging to obtain the environment-friendly type adhesive. When the adhesive disclosed by the invention is used for carrying out coating printing, no formaldehyde is released and environmental protection is realized.

Description

technical field [0001] The invention relates to the technical field of textile printing and dyeing adhesives, in particular to an environment-friendly adhesive for paint printing and dyeing, its preparation method and application. Background technique [0002] Pigment printing and dyeing (pigment printing and dyeing) has excellent characteristics such as simple process, less water consumption, and less pollution, and is suitable for printing and dyeing of various fibers. Therefore, the application prospect of pigment printing and dyeing in textile processing procedures is very broad. The structure and properties of the binder have a decisive influence on the quality of the pigment printing and dyeing products. [0003] At present, the main products of paint printing and dyeing adhesives are low-temperature self-crosslinking adhesives. This type of adhesive is easy to release free formaldehyde which is harmful to the human body during production, transportation and use, and p...

Claims

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Application Information

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IPC IPC(8): D06P1/52C08F220/18C08F220/32C08F222/02C08F220/14C08F220/44C08F212/08
CPCC08F220/18C08F220/1804D06P1/5257C08F220/325C08F220/32C08F222/02C08F220/14C08F220/44C08F212/08
Inventor 王薪孙凯
Owner ANYANG NORMAL UNIV
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