Preparation method for microcapsule-coated insecticide controlled release textile
A technology of microcapsules and insecticides is applied in the field of preparation of microcapsule-coated insecticide controllable release textiles. Research and other issues to achieve the effect of good anti-mosquito and anti-mosquito effect, long-term anti-mosquito and anti-mosquito effect, simple and convenient operation
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Embodiment 1
[0041] The production raw materials include polyethylene, insecticide microcapsules (containing deltamethrin) and synergist microcapsules (containing butyronyl ether), and the content percentage of each raw material is:
[0042] Polyethylene: 99%; the content ratio of HDPE to LDPE is 3:1.
[0043] Insecticide microcapsules (containing deltamethrin): 0.5%; prepared by interfacial polymerization with deltamethrin as the core material and polyurea as the wall material, with an average particle size of 4 μm and a core-to-wall ratio of 1:4 - Microencapsulated particles between 4:1. The specific preparation method of insecticide microcapsules is as follows:
[0044] a) Oil phase preparation: fully dissolve 0.1%-0.4% deltamethrin in cyclohexanone, add toluene-2,4-diisocyanate and mix evenly;
[0045] b) Water phase preparation: disperse 3%-7% compound emulsifier into deionized water, and make emulsifier / water system under high shear rate;
[0046] c) emulsification: adding the oil...
Embodiment 2
[0062] The production raw materials include polyethylene, insecticide microcapsules (containing deltamethrin) and synergist microcapsules (containing butyronyl ether), and the content percentage of each raw material is:
[0063] Polyethylene: 95.3%; the content ratio of HDPE to LDPE is 30:1.
[0064] Insecticide microcapsules (containing deltamethrin): 1.5%; adopt the interfacial polymerization method described in Example 1 to prepare respectively with deltamethrin as the core material, polyurea as the wall material, and the ratio of core to wall is 1:2 , microcapsule particles with an average particle size between 1-8 μm.
[0065] Synergist microcapsules (containing synergistic ether): 3.2%; adopt the interfacial polymerization method described in Example 1 to prepare respectively with synergistic ether as the core material, polyurea as the wall material, and the core-to-wall ratio is 1:2, the average Microcapsule particles with a particle size between 1-8 μm.
[0066] The ...
Embodiment 3
[0076] The production raw materials include polyethylene, insecticide microcapsules (containing deltamethrin) and synergist microcapsules (containing butyronyl ether), and the content percentage of each raw material is:
[0077] Polyethylene: 96.8%; the content ratio of HDPE to LLDPE is 30:1.
[0078] Insecticide microcapsules (containing deltamethrin): 1.1%; the interfacial polymerization method described in Example 1 is used to prepare polyurethane as the wall material, and deltamethrin is the microcapsule of the core material, and its average particle diameter is 4.8 μm, the core-to-wall ratio is 2:1. The specific preparation method is:
[0079] a) Oil phase preparation: fully dissolve 0.73% deltamethrin in cyclohexanone, add toluene-2,4-diisocyanate and mix evenly;
[0080]b) Water phase preparation: disperse 5% of the compound emulsifier into deionized water, and make an emulsifier / water system at a high shear rate;
[0081] c) emulsification: adding the oil phase of s...
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