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Oxidation coloring method of titanium product

A technology of titanium material and anodic oxidation, applied in the direction of electrolytic coating, surface reaction electrolytic coating, coating, etc., can solve the problems of uglifying objects, failing to achieve decoration and beautification, and messy colors, etc., and achieve the effect of reducing resistance and simple method

Active Publication Date: 2019-04-05
西安庄信新材料科技有限公司
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0004] At present, there are many researches on the oxidation and coloring process of titanium materials, such as atmospheric oxidation method, anodic oxidation method, chemical treatment method, etc., but in the oxidation process of titanium materials, the control of process parameters is not ideal or the ratio of oxidation reaction solution is different. , the thickness of the oxide film will be uneven, and the color will be messy after lighting, which will not only fail to achieve the effect of decoration and beautification, but will uglify the object to be decorated

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0028] In this embodiment, a method for oxidative coloring of titanium materials for construction, the building can appear brown under light, comprising the following steps:

[0029] Step 1: Cut out a titanium material with a thickness of 2.5cm, perform surface mechanical polishing and degrease the titanium material with acetone and alcohol;

[0030] Step 2: Process connection holes on the titanium material, bend the titanium material into a circular open and close dome shape of the stadium, and use acid etching or carving out the shape;

[0031] Step 3: Degreasing the titanium material for the second time with acetone solution;

[0032] Step 4: Put the titanium material in the electrolytic tank for anodic oxidation treatment, generate an oxide film on the surface of the titanium material, take out the titanium material and clean the electrolyte on the surface, the electrolyte is a mixed solution of 2.0% hydrofluoric acid and 3.0% phosphoric acid ,Specifically

[0033] a. Co...

Embodiment 2

[0038] In this embodiment, a method for oxidizing and coloring titanium materials of ornaments, which can appear rose red under light, comprises the following steps:

[0039] Step 1: Cut the titanium material with a thickness of 0.5cm, and perform surface mechanical polishing and degrease the titanium material for the first time with acetone and alcohol;

[0040] Step 2: Put the titanium material in the electrolytic tank for anodic oxidation treatment, generate an oxide film on the surface of the titanium material, take out the titanium material and clean the electrolyte on the surface, the electrolyte is 0.5% hydrofluoric acid, 1.5% phosphoric acid, 0.1% A mixed solution of sulfuric acid, specifically

[0041] a. Apply a layer of electrolyte on the surface of the titanium material to prevent the bubbles attached to the surface of the titanium material and the electrolyte from affecting the electrolytic reaction, and put the titanium material into the electrolyte of the electr...

Embodiment 3

[0046] In this embodiment, a method for oxidative coloring of titanium materials used in historical buildings, the building can appear green under light, comprising the following steps:

[0047] Step 1: Cut out a titanium material with a thickness of 3.0cm, perform surface mechanical polishing and degrease the titanium material with acetone and alcohol;

[0048] Step 2: Process connection holes on the titanium material, bend the titanium material into a circular open and close dome shape of the stadium, and use acid etching or carving out the shape;

[0049] Step 3: Degreasing the titanium material for the second time with acetone solution;

[0050] Step 4: Put the titanium material in the electrolytic tank for anodic oxidation treatment, generate an oxide film on the surface of the titanium material, take out the titanium material and clean the electrolyte on the surface, the electrolyte is a mixed solution of 2.0% oxalic acid and 4.0% phosphoric acid, specifically for

[005...

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PUM

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Abstract

The invention provides an oxidation coloring method of a titanium product. The method comprises the following steps that the titanium product surface is mechanically polished and degreased; secondly,the titanium product is placed in an electrolytic cell to be subjected to anodic oxidation treatment, an oxide thin film is generated on the titanium product surface, the titanium product is taken out, and an electrolyte on the surface is cleaned; thirdly, the titanium product is placed in a hydrogen peroxide solution to be boiled out to be subjected to oxide thin film hole sealing; secondly, anodic oxidation specially comprises the steps that a, the surface of the electrolyte is coated with a layer of electrolyte, and the titanium product is placed into the electrolyte of the electrolytic cell; b, a power source is switched on, the electrochemical reaction is carried out to generate the oxide thin film, the power source is switched off, the chemical reaction is carried out to enable smallholes to be formed in the oxide thin film, and a heating device and a stirring device are connected while the power source is switched off; c, switching on and off of the power source in the step b are repeated, and the titanium product surface is subjected to the electrochemical reaction to generate the stable oxide thin film. Method has the advantages of being simple in method, and good in titanium product surface oxide thin film uniformity.

Description

technical field [0001] The invention relates to the technical field of oxidation coloring of metal materials, in particular to a method for oxidation coloring of titanium materials. Background technique [0002] The abundance of titanium in the bottom shell is 0.56%, and the abundance of ammonia ranks ninth. my country's titanium resource reserves are quite rich. Metal titanium has two allotropic crystal forms, low temperature (<882.5 ℃) is stable as α type, close-packed hexagonal system; high temperature (>882.5 ℃) is stable as β type, body centered cubic system. [0003] Due to its excellent corrosion resistance, heat resistance and portability, titanium has been widely used in aerospace, chemical and pharmaceutical, military industry, shipbuilding and papermaking, medical equipment and other fields. After the titanium material is oxidized, a layer of oxide film will be formed on the surface of the titanium material, and the oxide film can make the titanium material...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C25D11/26
CPCC25D11/26
Inventor 郭磊侯军涛鲁毅王尧张卫刚
Owner 西安庄信新材料科技有限公司
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