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A kind of oxidation coloring method of titanium material

A titanium material and anodizing technology, applied in the direction of coating, surface reaction electrolytic coating, electrolytic coating, etc., can solve the problems of ugly objects, failure to achieve decoration and beautification, disordered colors, etc., and achieve the effect of reducing resistance and simple method.

Active Publication Date: 2021-01-26
西安庄信新材料科技有限公司
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0004] At present, there are many researches on the oxidation and coloring process of titanium materials, such as atmospheric oxidation method, anodic oxidation method, chemical treatment method, etc., but in the oxidation process of titanium materials, the control of process parameters is not ideal or the ratio of oxidation reaction solution is different. , the thickness of the oxide film will be uneven, and the color will be messy after lighting, which will not only fail to achieve the effect of decoration and beautification, but will uglify the object to be decorated

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0028] In this embodiment, a method for oxidative coloring of titanium materials for construction, the building can appear brown under light, comprising the following steps:

[0029] Step 1: Cut out a titanium material with a thickness of 2.5cm, perform surface mechanical polishing and degrease the titanium material with acetone and alcohol;

[0030] Step 2: Process connection holes on the titanium material, bend the titanium material into a circular open and close dome shape of the stadium, and use acid etching or carving out the shape;

[0031] Step 3: Degreasing the titanium material for the second time with acetone solution;

[0032] Step 4: Put the titanium material in the electrolytic tank for anodic oxidation treatment, generate an oxide film on the surface of the titanium material, take out the titanium material and clean the electrolyte on the surface, the electrolyte is a mixed solution of 2.0% hydrofluoric acid and 3.0% phosphoric acid ,Specifically

[0033] a. Co...

Embodiment 2

[0038] In this embodiment, a method for oxidizing and coloring titanium materials of ornaments, which can appear rose red under light, comprises the following steps:

[0039] Step 1: Cut the titanium material with a thickness of 0.5cm, and perform surface mechanical polishing and degrease the titanium material for the first time with acetone and alcohol;

[0040] Step 2: Put the titanium material in the electrolytic tank for anodic oxidation treatment, generate an oxide film on the surface of the titanium material, take out the titanium material and clean the electrolyte on the surface, the electrolyte is 0.5% hydrofluoric acid, 1.5% phosphoric acid, 0.1% A mixed solution of sulfuric acid, specifically

[0041] a. Apply a layer of electrolyte on the surface of the titanium material to prevent the bubbles attached to the surface of the titanium material and the electrolyte from affecting the electrolytic reaction, and put the titanium material into the electrolyte of the electr...

Embodiment 3

[0046] In this embodiment, a method for oxidative coloring of titanium materials used in historical buildings, the building can appear green under light, comprising the following steps:

[0047] Step 1: Cut out a titanium material with a thickness of 3.0cm, perform surface mechanical polishing and degrease the titanium material with acetone and alcohol;

[0048] Step 2: Process connection holes on the titanium material, bend the titanium material into a circular open and close dome shape of the stadium, and use acid etching or carving out the shape;

[0049] Step 3: Degreasing the titanium material for the second time with acetone solution;

[0050] Step 4: Put the titanium material in the electrolytic tank for anodic oxidation treatment, generate an oxide film on the surface of the titanium material, take out the titanium material and clean the electrolyte on the surface, the electrolyte is a mixed solution of 2.0% oxalic acid and 4.0% phosphoric acid, specifically for

[005...

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PUM

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Abstract

The invention provides a method for oxidation and coloring of titanium materials, comprising step 1: mechanical polishing and degreasing treatment on the surface of titanium materials; step 2: placing titanium materials in an electrolytic cell for anodic oxidation treatment, and generating oxides on the surface of titanium materials Thin film, take out the titanium material and clean the electrolyte on the surface; step 3: put the titanium material in the hydrogen peroxide solution and decoct to seal the pores of the oxide film. The specific steps of anodic oxidation in step 2 are: a. Coating a layer of electrolyte on the surface of the titanium material, placing the titanium material obliquely into the electrolyte of the electrolytic cell; b. Connecting the power supply to perform an electrochemical reaction to produce oxides Thin film; turn off the power supply, carry out chemical reaction to form small holes on the oxide film, turn on the heating device and the stirring device while turning off the power supply; c, repeat step b to turn on the power supply and disconnect the power supply, so that the surface of the titanium material is electrochemically The reaction produces stable oxide film formation. The invention has the characteristics of simple method and good uniformity of the oxide film on the surface of the titanium material.

Description

technical field [0001] The invention relates to the technical field of oxidation coloring of metal materials, in particular to a method for oxidation coloring of titanium materials. Background technique [0002] The abundance of titanium in the bottom shell is 0.56%, and the abundance of ammonia ranks ninth. my country's titanium resource reserves are quite rich. Metal titanium has two allotropic crystal forms, low temperature (<882.5 ℃) is stable as α type, close-packed hexagonal system; high temperature (>882.5 ℃) is stable as β type, body centered cubic system. [0003] Due to its excellent corrosion resistance, heat resistance and portability, titanium has been widely used in aerospace, chemical and pharmaceutical, military industry, shipbuilding and papermaking, medical equipment and other fields. After the titanium material is oxidized, a layer of oxide film will be formed on the surface of the titanium material, and the oxide film can make the titanium material...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): C25D11/26
CPCC25D11/26
Inventor 郭磊侯军涛鲁毅王尧张卫刚
Owner 西安庄信新材料科技有限公司
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