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Micro-interpenetrating network cross-linked low-smoke halogen-free flame-retardant cable material and preparation method thereof

A technology of flame-retardant cable material and interpenetrating network, which is applied in the direction of circuits, electrical components, plastic/resin/wax insulators, etc., can solve problems such as inability to meet requirements, and achieve non-flammable spread, good dielectric properties and insulation , easy processing effect

Inactive Publication Date: 2019-04-19
WUXI JAKE PLASTIC
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0003] Wires and cables are used in all aspects of human life. With the development of social life and new technologies and industries, the requirements for wires and cables are becoming more diverse and their performance is improving. Therefore, the requirements for cable materials are also constantly increasing, especially in the current In key industries such as big data, robotics, new energy, optical communications, rail transit, and aerospace, the application scenarios of cables are rich and diverse, with different requirements. The original thermoplastic materials, cross-linked materials (including radiation cross-linked, silane Cross-linking and chemical cross-linking, etc.) have been unable to meet the requirements in some application scenarios

Method used

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  • Micro-interpenetrating network cross-linked low-smoke halogen-free flame-retardant cable material and preparation method thereof

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0025] Micro-interpenetrating network cross-linked low-smoke halogen-free flame-retardant cable material, in parts by weight, the cable material includes 25 parts of ethylene-vinyl acetate copolymer, 20 parts of silane-grafted linear low-density polyethylene, polyolefin thermoplastic elastic 25 parts of body, 15 parts of ultra-low density polyethylene, 15 parts of functional polyolefin resin, 2.5 parts of high molecular weight polysiloxane, 1.5 parts of cross-linking sensitizer, 2 parts of auxiliary cross-linking agent, 0.5 parts of chain extender, 180 parts of high-efficiency composite flame retardant, 2.5 parts of tubular microcrystalline nano-char forming agent, 2 parts of organosilane, 2 parts of antioxidant, and 1.5 parts of processing aid.

[0026] The ethylene-vinyl acetate copolymer is Dow 265, its vinyl acetate content is 28%, and its melt index is 3.0 g / 10 min.

[0027] Further, the grafting rate of silane-grafted linear low-density polyethylene is 1.5%, the unsatura...

Embodiment 2

[0040] The difference from Example 1 is to adjust the consumption of each component of the cable material, as follows:

[0041] Micro-interpenetrating network cross-linked low-smoke halogen-free flame-retardant cable material, in parts by weight, the cable material includes 10 parts of ethylene-vinyl acetate copolymer, 40 parts of silane-grafted linear low-density polyethylene, polyolefin thermoplastic elastic 15 parts of body, 25 parts of ultra-low density polyethylene, 10 parts of functional polyolefin resin, 0.5 parts of high molecular weight polysiloxane, 0.5 parts of crosslinking sensitizer, 0.5 parts of auxiliary crosslinking agent, 0.1 part of chain extender, 120 parts of high-efficiency composite flame retardant, 2.5 parts of tubular microcrystalline nano-char forming agent, 1 part of organosilane, 0.5 part of antioxidant, and 0.5 part of processing aid.

Embodiment 3

[0043] The difference from Example 1 is to adjust the consumption of each component of the cable material, as follows:

[0044] Micro-interpenetrating network cross-linked low-smoke halogen-free flame-retardant cable material, in parts by weight, the cable material includes 20 parts of ethylene-vinyl acetate copolymer, 30 parts of silane-grafted linear low-density polyethylene, polyolefin thermoplastic elastic 15 parts of body, 20 parts of ultra-low density polyethylene, 15 parts of functional polyolefin resin, 1 part of high molecular weight polysiloxane, 1 part of cross-linking sensitizer, 2 parts of auxiliary cross-linking agent, 0.25 parts of chain extender, 150 parts of high-efficiency composite flame retardant, 0.5 parts of tubular microcrystalline nano-char forming agent, 1 part of organosilane, 1.5 parts of antioxidant, and 1 part of processing aid.

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Abstract

The invention discloses a micro-interpenetrating network cross-linked low-smoke halogen-free flame-retardant cable material and a preparation method thereof. The cable material includes, by weight, 10-25 parts of ethylene-vinyl acetate copolymer, 20-40 parts of silane-grafted linear low-density polyethylene, 15-25 parts of a polyolefin thermoplastic elastomer, 10-25 parts of ultra-low-density polyethylene, 10-15 parts of functionalized polyolefin resin, 0.5-2.5 parts of high molecular weight polysiloxane, 0.5-1.5 parts of a crosslinking sensitizer, 0.5-2 parts of an auxiliary crosslinking agent, 0.1-0.5 part of a chain extender, 120-180 parts of a high efficiency composite flame retardant, 0.5-2.5 parts of a tubular microcrystalline nano-carbon forming agent, 1-2 parts of organosilane, 0.5-2 parts of an anti-oxidant, and 0.5-1.5 parts of a processing auxiliary agent. The cable material has excellent comprehensive performance and service life, good mechanical property, good dielectric and insulating properties and small creep poles, and is high and low temperature resistant, water resistant, acid and alkali resistant, solvent resistant, wear resistant, creep resistant, ozone resistant and bending resistant; and the cable material can meet different application scene demands of cables, and has the comprehensive performance of dealing with complex and changeable environments.

Description

technical field [0001] The invention belongs to the technical field of polymer materials, and relates to a functional plastic, in particular to a micro-interpenetrating network cross-linked low-smoke halogen-free flame-retardant cable material and a preparation method thereof. Background technique [0002] Interpenetrating network polymer (IPN) is a unique polymer blend, which is formed by the cross-linked networks of cross-linked polymer I and cross-linked polymer II, which are continuously interpenetrated with each other. Due to its forced mutual compatibility, it has good mechanical properties, high tensile strength and tear strength, extremely low oxygen and water vapor transmission rates, excellent dielectric and insulating properties, and has certain Chemical inertness, excellent water resistance, acid and alkali resistance, solvent resistance, excellent high temperature stability and low temperature toughness, low surface wear, creep resistance, good biocompatibility ...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C08L23/08C08L51/06C08L83/04C08L23/06C08K13/06C08K7/00C08K3/34C08K3/26C08K3/22C08K5/14H01B3/44
CPCC08K2003/2296C08K2201/011C08L23/0815C08L23/0853C08L51/06C08L2201/02C08L2201/08C08L2201/22C08L2203/202C08L2205/025C08L2205/035C08L2205/04C08L2207/04C08L2312/08H01B3/441C08L83/04C08L23/06C08K13/06C08K7/00C08K3/34C08K3/26C08K3/22C08K5/14
Inventor 祁建强翟银枫潘晓旻邵明元徐颖楠
Owner WUXI JAKE PLASTIC
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