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Microparticle enhanced special high temperature wear-resisting brazing bar and manufacturing method thereof

A micro-particle, high-temperature wear-resistant technology, used in welding equipment, welding media, manufacturing tools, etc., can solve the problems of thermal stress, high heating temperature, and low brazing strength in coatings and titanium alloy substrates. Efficiency and activity, enhanced microstructure, effect of large sustainable loads

Inactive Publication Date: 2019-05-03
HENAN ZHILIAN HUANYU INTPROP OPERATION CO LTD
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

Among them, the thickness of the ultra-high temperature wear-resistant coating formed by physical vapor deposition and chemical vapor deposition is usually relatively thin; the ultra-high temperature wear-resistant coating formed by plasma spraying and flame spraying can generally only reach a thickness of about 0.5 mm; and Although the surfacing welding method can form a thicker wear-resistant coating, the heating temperature is higher, and the coating and the titanium alloy substrate are prone to thermal stress; although the brazing method can obtain a relatively large thickness range at a lower welding temperature Coating, but because titanium is a highly chemically active metal, brazing is more difficult, it needs to be brazed under the protection of vacuum or inert gas, and the silver-based, palladium-based, titanium-based or aluminum-based solder used for brazing Among them, due to the high price of palladium and silver, and the titanium-based brazing material itself is relatively brittle, the processing performance is poor, and the aluminum-based brazing material has low brazing strength, so it can only be used in working conditions that do not require high strength.

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0021] This embodiment provides a micron-particle reinforced ultra-high temperature wear-resistant brazing rod, which includes a micron-particle reinforced hollow copper solder core and Co-coated Cr filled inside the micron-particle reinforced hollow copper solder core. 2 o 3 Composite particles and the copper flux coating adhering to the outer surface of the micron particle reinforced hollow copper solder inner core, the Co coated Cr 2 o 3 The mass ratio of the composite particles to the ultra-high temperature wear-resistant brazing rod reinforced with micron particles is 31%.

[0022] Wherein, the micron-particle-reinforced hollow copper solder inner core includes a metal phase and SiC with an average particle size of 9.5 μm, and the metal phase is composed of the following elements by mass percentage: Ag 1.4%, Mn 0.9%, La 0.5%, Sn 2.93%, Nd 1.8%, and the rest is Cu, and the SiC accounts for 5.75% by mass of the micron-particle reinforced hollow copper solder inner core. ...

Embodiment 2

[0033] This embodiment provides a micron-particle reinforced ultra-high temperature wear-resistant brazing rod, which includes a micron-particle reinforced hollow copper solder core and Co-coated Cr filled inside the micron-particle reinforced hollow copper solder core. 2 o 3 Composite particles and copper flux coating adhered to the outer surface of the micron particle reinforced hollow copper solder inner core;

[0034] Wherein, the micron-particle reinforced hollow copper solder inner core has a microstructure composition comprising a metal phase and SiC with an average particle size of 5 µm, and the SiC accounts for 0.5% by mass of the micron particle-reinforced hollow copper solder inner core; The metal phase is composed of the following elements by mass percentage: Ag 1.1%, Mn 0.7%, La 0.4%, Sn 2.93%, Nd 1.6%, and the rest is Cu.

[0035] The Co coated Cr 2 o 3 The mass ratio of the composite particles to the micron particle reinforced ultra-high temperature wear-resi...

Embodiment 3

[0040] This embodiment provides a micron-particle reinforced ultra-high temperature wear-resistant brazing rod, which includes a micron-particle reinforced hollow copper solder core and Co-coated Cr filled inside the micron-particle reinforced hollow copper solder core. 2 o 3 Composite particles and copper flux coating adhered to the outer surface of the micron particle reinforced hollow copper solder inner core;

[0041] Wherein, the micron-particle-reinforced hollow copper solder inner core includes a metal phase and SiC with an average particle size of 7.5 μm, and the metal phase is composed of the following elements by mass percentage: Ag 1.3%, Mn 0.72%, La 0.5%, Sn 2.05%, Nd 1.8%, and the rest is Cu, and the mass percentage of SiC in the micron-particle reinforced hollow copper solder inner core is 3.75%.

[0042] The Co coated Cr 2 o 3 The composite particles account for 40% of the mass ratio of the micron particle reinforced ultra-high temperature wear-resistant braz...

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Abstract

The invention provides a microparticle enhanced special high temperature wear-resisting brazing bar. The brazing bar comprises a microparticle enhanced hollow copper brazing filler metal inner core, Co-coated Cr2O3 composite particles filled into the microparticle enhanced hollow copper brazing filler metal inner core, and a copper brazing flux coating adhering to the outer surface of the microparticle enhanced hollow copper brazing filler metal inner core. The microparticle enhanced hollow copper brazing filler metal inner core comprises a metal phase and micrometer SiC particles. The metal phase is composed of metal elements including, by mass percent, 1.1-1.4% of Ag, 0.6-0.9% of Mn, 0.4-0.5% of La, 1.3-2.93% of Sn, 1.6-1.8% of Nd and the balance Cu. The invention further provides a method for manufacturing the microparticle enhanced special high temperature wear-resisting brazing bar. The microparticle enhanced special high temperature wear-resisting brazing bar can improve wear-resisting performance and tensile strength of the brazing layer.

Description

technical field [0001] The invention relates to the technical field of brazing materials, in particular to a micron particle reinforced ultra-high temperature wear-resistant brazing rod and a preparation method thereof. Background technique [0002] At present, titanium and titanium alloys are widely used in industrial production and social life. Due to their small specific gravity, high strength, good corrosion resistance and biocompatibility, titanium and titanium alloys are widely used in aerospace, chemical industry, biomedicine and civil life. The important roles in other fields are different and replaced. Especially in the application in the field of aerospace, in order to improve the high temperature and wear resistance of the spacecraft surface, it is necessary to install a layer of ultra high temperature wear resistant coating on the surface of titanium and titanium alloy. [0003] Common methods for forming ultra-high temperature wear-resistant coatings on the sur...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): B23K35/14B23K35/40
Inventor 计富宝田文举
Owner HENAN ZHILIAN HUANYU INTPROP OPERATION CO LTD
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