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A kind of heterogeneous gradient composite material and its preparation method

A technology of composite materials and aluminum-based composite materials, which is applied in the field of heterogeneous gradient composite materials and their preparation, can solve the problems affecting the thermal and mechanical properties and process performance of electronic packaging materials, difficult to control thickness, etc., and achieve good sintering performance and easy Control and reduce the effect of forming process

Active Publication Date: 2021-01-08
CENT SOUTH UNIV
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

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Problems solved by technology

When using aluminum-based heterogeneous materials (such as aluminum-silicon alloy and aluminum-silicon carbide) to make graded functional materials, the applicant has previously tried to combine aluminum-silicon alloy and aluminum-silicon carbide composite materials or aluminum-silicon alloy and aluminum-diamond composite materials. The powders are cold-pressed into plates and then alternately laid up and hot-pressed into gradient materials. However, after such treatment, due to the mutual penetration and extrusion of the aluminum-silicon alloy layer and the aluminum-silicon carbide layer or the aluminum diamond layer, it is difficult to control the final The thickness of the aluminum silicon carbide or aluminum diamond layer in the gradient material, because the aluminum silicon carbide or aluminum diamond layer needs to play the role of heat conduction and mechanical shock resistance in electronic packaging materials, if its thickness is uncontrollable, it will seriously affect the electronic packaging material. Thermal and mechanical properties and process properties

Method used

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  • A kind of heterogeneous gradient composite material and its preparation method
  • A kind of heterogeneous gradient composite material and its preparation method
  • A kind of heterogeneous gradient composite material and its preparation method

Examples

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Embodiment 1

[0028] In this embodiment 1, Al-42%Si / Al-50%diamond twins are made of silicon-aluminum alloy Al-42%Si with a silicon weight percentage of 42% and an aluminum-based composite material Al-50% diamond with a weight percentage of 50%. layer heterogeneous gradient composite material, the specific steps are as follows:

[0029] (1) Preparation of silicon-aluminum alloy powder

[0030] The invention adopts a gas atomization method to prepare aluminum-silicon alloy powder. Select pure aluminum ingots and monocrystalline silicon blocks as raw materials, and mix the pure aluminum ingots and monocrystalline silicon blocks with a proportion of silicon content of 42% and the balance as aluminum in terms of weight percentages, and then mix the weighted Pure aluminum ingots are sent to an intermediate frequency induction melting furnace for melting. The tundish crucible of the intermediate frequency induction melting furnace is heated by resistance. The preheating temperature is between 700...

Embodiment 2

[0038] In the present invention, the Al-27% aluminum alloy Al-27% Si, Al-50% Si and SiC with a weight percentage of 60% SiC are used to make Al-27% Si / Al-50%Si / Al-60%SiC three-layer heterogeneous gradient composite material, the specific steps are as follows:

[0039] (1) Preparation of silicon-aluminum alloy powder

[0040] In Example 2, the method for preparing silicon-aluminum alloys Al-27%Si and Al-50%Si powders with silicon weight percentages of 27% and 50% respectively is the same as step (1) in Example 1.

[0041] (2) Synthesize aluminum matrix composites and make them into slabs

[0042] The SiC preform and the Al-(3-12)%Si-(0.3-1.0)%Mg alloy matrix are prepared according to the SiC weight percentage of 60%. Put the SiC preform in the graphite mold, then put the Al-(3~12)%Si-(0.3~1.0)%Mg alloy matrix on the SiC preform, put them all into the infiltration furnace; vacuum to 10 -3 Pa, heated to 780-860°C, kept warm for 10-30min, filled with argon to 2.5-3.0MPa, kept war...

Embodiment 3

[0050] The preparation of heterogeneous gradient functional materials is mainly to make the adjacent materials tightly bonded. The bonding force between materials mainly comes from external pressure and heat. If the external pressure is too large, the thickness of the composite material layer will be difficult to control. If the pressure is too small, the bond may not be firm and cracks may appear. Therefore, the applicant tries to adjust the internal structure of the aluminum matrix composite material or the aluminum silicon alloy, and increases the bonding force from the inside to the aluminum matrix composite material and the aluminum silicon alloy, hoping to make the aluminum matrix composite material and the aluminum silicon alloy under lower pressure. The alloy is closely combined, which not only ensures the controllable thickness of the aluminum matrix composite material layer, but also does not appear cracks.

[0051] Taking the preparation of the Al-42%Si / Al-50%diamon...

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Abstract

The invention provides a heterogeneous gradient composite material and a preparation method thereof. The preparation method comprises the steps that an aluminum base composite material is manufacturedinto a slab, then the aluminum base composite material slab and aluminum-silicon alloy powder are laid in sequence, and finally, the aluminum base alloy composite material and aluminum-silicon alloyare tightly combined to obtain the heterogeneous gradient composite material by pressure sintering. By preparing the aluminum base composite slab in advance without cold pressing and molding, high volume fraction can be obtained, thermal expansion coefficient can be reduced, the thickness and shape of an aluminum base composite layer are controlled easily, and the repeatability of the process is ensured; and the sintering performance of the aluminium-silicon alloy is good, pressure sintering with powder direct laying can reduce the forming process and reduce the cost, the using requirements can be better met, and the stability of the process is ensured.

Description

technical field [0001] The invention relates to the technical field of material engineering, in particular to a heterogeneous gradient composite material and a preparation method thereof. Background technique [0002] Electronic packaging materials are base materials used to carry electronic devices and their interconnections, and play the roles of mechanical support, sealing environment protection, signal transmission, heat dissipation and shielding. [0003] Metal matrix composites organically combine a metal matrix with good thermal conductivity and plastic deformation properties and a reinforcement with a low thermal expansion coefficient and high strength. It is a kind of thermal conductivity and thermal expansion coefficient. Wide range of controllable electronic packaging materials, capable of packaging various chips and substrate materials. Among them, the aluminum-based composite material has excellent thermophysical properties, low density and high strength, and i...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): B22F7/04C22C21/02
Inventor 蔡志勇王日初彭超群冯艳王小锋
Owner CENT SOUTH UNIV
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